File name: Pandora114s1_BuenosAires_20170427_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T003617.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170427_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170427 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170427T103225.0Z 6326.439178 455 1 31.99 2 89.75 72.77 101.77 81.46 0.00 1 0.00 1 0 15 8.623e-02 8.367e-02 6.951e-02 6.781e-02 6.229187e+02 3.934071e+03 2.966021e+02 -6.000000e+00 4.767159e+03 285.90 -2.00 20.00 -2.00 505.16 0.00e+00 1.942609e-03 1.850458e-03 1.256220e-04 -6.000000e+00 2.410201e-03 285.90 -2.00 20.00 -2.00 499.99 0.00e+00 1.988403e+00 1.351545e+00 7.186471e-02 -6.000000e+00 1.688454e+00 225.64 -2.00 3.16 -2.00 501.61 0.00e+00 20.049 0.075 489.00 513.00 1 9.2298e+00 1.0361e-01 3.1212e-02 -6.0000e+00 1.2941e-01 1.1987e-01 2.7205e-02 1.9142e-03 -6.0000e+00 3.3905e-02 9.1859e-06 -3.0415e-03 6.5409e-03 7.1892e-05 -6.0000e+00 8.4957e-03 2.9595e-02 -3.7028e-04 12 8 8 10 0 0 -6.76 20.92 6.97 0.02959 0.00850 8 2 1 4 0 4000.000 25.07 19.43 20.92 -11832 6210 -4745 2556 4004 3642 5490 -4169 -5627 7506 23884 -5209 -2934 7748 -373 4903 -1147 -1142 15298 10543 -719 -15502 5253 -3431 9025 7225 -1940 531 -11440 20423 -2051 19811 -5209 3426 -5220 -6035 -534 -5185 13366 -11280 13030 -922 -8456 15442 -14820 -5990 7040 12226 5722 -254 -559 -9066 7921 -11563 2098 5272 -5912 7137 -3353 -1944 -130 1015 5993 -7397 2627 1253 13812 -5645 7311 -6987 19070 -2683 -10352 9084 -5090 10994 -10435 6864 -1795 1094 1660 -7826 -4025 2952 9423 -6569 -7375 11214 2046 8508 -2024 17693 -12343 12765 -6875 -6213 -1421 -9248 -8828 -6193 10827 10244 -6204 3846 -5178 9132 -1112 5725 6648 5584 -3641 -11898 127 1444 11903 -928 4702 15405 -9075 6114 -14575 -6357 -10595 13725 4300 695 7996 909 7785 5969 10914 9410 3832 4052 -11617 13789 140 1833 1673 -2010 2554 -6707 2134 654 13949 -891 3371 -9450 -6566 14602 5294 14923 -17550 -13258 5897 -5182 2682 4258 3977 5996 -5067 -6946 8055 21433 -6159 -3343 7836 -379 4715 -1184 -1205 14033 10325 -793 -19853 5470 -3908 9119 7460 -2192 582 -13891 17557 -2145 16417 -5586 3462 -5945 -7087 -596 -6020 12734 -13596 12241 -997 -9930 14439 -18979 -7087 7332 12028 5933 -275 -592 -10165 7301 -12759 2027 5047 -6524 7084 -3744 -2145 -141 1084 6108 -8654 2782 1338 12853 -6279 7030 -7648 15887 -2746 -10666 8252 -5054 9409 -11098 6074 -1700 991 1482 -7673 -3812 2625 7908 -6522 -7445 9457 1895 7387 -1951 14039 -13332 10871 -7227 -6530 -1417 -9836 -9169 -6123 8816 8213 -5799 3276 -4948 7815 -1081 5233 5965 4988 -3524 -12506 120 1368 10335 -929 4493 13312 -10066 5842 -17075 -6787 -11620 11632 3966 664 7142 876 7018 5158 8962 7837 3372 3533 -11674 11228 122 1563 1446 -1839 2277 -6661 1961 614 11508 -857 3124 -9976 -6701 11875 4616 11553 -18597 SO 20170427T103629.0Z 6326.442002 459 1 32.01 2 88.95 72.19 100.98 80.92 0.00 1 0.00 1 0 22 3.419e-02 3.385e-02 3.567e-02 3.542e-02 1.164482e+04 2.491492e+03 7.079507e+02 -6.000000e+00 1.890584e+03 285.90 -2.00 20.00 -2.00 505.31 0.00e+00 2.186012e-04 9.689267e-04 6.047841e-05 -6.000000e+00 9.546969e-04 285.90 -2.00 20.00 -2.00 500.38 0.00e+00 5.052282e-01 6.936650e-01 8.030949e-02 -6.000000e+00 6.657089e-01 225.64 -2.00 3.16 -2.00 501.98 0.00e+00 18.478 0.059 489.00 513.00 1 8.8990e+00 5.3181e-02 2.8602e-02 -6.0000e+00 5.1081e-02 7.9020e-02 1.3525e-02 2.3951e-03 -6.0000e+00 1.3284e-02 1.8100e-05 -1.4869e-03 3.1912e-03 6.5843e-05 -6.0000e+00 3.3617e-03 5.6632e-02 -1.2410e-04 12 8 8 10 0 0 64.41 20.92 2.50 0.05663 0.04632 8 2 1 4 0 4000.000 25.07 20.35 20.92 -6538 -5607 -819 -116 4528 -2877 2599 2086 1265 2996 437 -1112 -4578 3432 -947 -4764 9856 -1558 -4984 -6828 -714 1777 2626 1536 -3662 771 3530 216 -263 -1588 4457 -639 -997 -3453 -547 1513 772 1226 -2689 4712 1855 1446 3727 3588 -3702 7419 984 -1201 849 4957 1852 -1338 873 1273 -3230 -3066 -3586 1874 3819 83 -1509 1941 4870 470 97 -3263 -4462 792 3289 -5521 -3562 2068 -3595 -2704 2784 -7732 1116 -3184 2454 -1736 2438 6430 3141 7662 517 3175 -6063 620 5800 1337 53 242 2607 2179 1305 -1384 3715 -467 -5801 -4330 -4020 1687 1715 4673 983 380 2897 -6366 2790 1450 -3114 -4141 1587 4501 -3468 -1536 -232 4687 -521 -630 1770 3264 -2823 -5533 -2043 5953 -1560 -82 934 -815 1796 2096 280 4968 -2791 238 4399 -6203 -6412 1679 6195 3572 3102 -1864 420 101 3678 1104 -3859 -59 -1404 -4295 -4152 -6325 -5516 -794 -115 4402 -3076 2671 2168 1321 3037 449 -1143 -4810 3296 -947 -4984 9080 -1652 -5595 -7903 -780 1897 2784 1653 -4171 841 3726 233 -278 -1658 4291 -648 -1036 -3804 -602 1653 847 1326 -2987 4821 1950 1533 3900 3804 -4001 7693 1086 -1343 916 5025 1886 -1369 857 1241 -3140 -3067 -3712 1870 3762 85 -1565 1950 4777 483 100 -3448 -4706 780 3119 -5655 -3540 1929 -3557 -2682 2652 -8255 1085 -3178 2274 -1658 2222 5637 2863 6734 493 2990 -6328 608 5399 1297 52 238 2529 2147 1300 -1396 3466 -439 -5589 -4012 -3647 1431 1466 3995 913 372 2848 -6513 2749 1431 -3014 -4076 1494 4164 -3499 -1525 -228 4413 -522 -638 1749 3140 -2831 -5593 -1974 5313 -1510 -79 887 -787 1687 1960 265 4433 -2650 217 3854 -6119 -6469 1594 5719 3436 3035 -1933 429 104 3658 1123 -4082 -59 -1397 -4342 -4197 SO 20170427T104029.0Z 6326.444780 463 1 32.00 2 88.17 71.62 100.21 80.39 0.00 1 0.00 1 0 15 5.722e-03 5.689e-03 2.664e-03 2.655e-03 9.985678e+03 1.807785e+02 6.631675e+02 -6.000000e+00 3.164608e+02 285.90 -2.00 20.00 -2.00 505.40 0.00e+00 3.408948e-03 7.278556e-05 1.922681e-04 -6.000000e+00 1.598349e-04 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