File name: Pandora114s1_BuenosAires_20170428_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T003614.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170428_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170428 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170428T103313.0Z 6327.439734 457 1 32.00 2 89.75 72.38 114.89 86.19 0.00 1 0.00 1 0 29 6.580e-02 6.504e-02 7.501e-02 7.345e-02 2.000494e+04 5.731622e+03 7.423768e+02 -6.000000e+00 3.636850e+03 285.83 -2.00 20.00 -2.00 505.20 0.00e+00 -1.314225e-03 1.985566e-03 1.253327e-04 -6.000000e+00 1.837258e-03 285.83 -2.00 20.00 -2.00 500.02 0.00e+00 -1.782218e+00 1.485403e+00 1.458575e-01 -6.000000e+00 1.282658e+00 225.59 -2.00 3.16 -2.00 501.63 0.00e+00 20.049 0.075 489.00 513.00 1 9.6051e+00 1.1295e-01 3.2887e-02 -6.0000e+00 9.8396e-02 1.6590e-01 2.9607e-02 3.2935e-03 -6.0000e+00 2.5629e-02 8.4904e-06 -1.9772e-02 6.1846e-03 3.9538e-05 -6.0000e+00 6.4729e-03 4.3964e-02 -1.2886e-04 12 8 8 10 0 0 33.60 21.44 8.78 0.04396 -0.09318 8 2 1 4 0 4000.000 25.58 20.26 21.44 -11580 -2840 -1158 537 5049 -5053 5282 2211 15003 7357 235 10162 1032 9969 6801 3225 5621 3348 2565 -6027 4506 -3834 -5023 -6207 2542 -9677 -4031 -3725 3021 4624 -5502 9228 -6519 8466 628 2329 -1413 7335 -7146 -3411 5404 -559 -3446 10202 -401 6478 -6026 -245 -5768 -5591 3008 3712 -4781 3067 -1617 -791 -314 -6339 -2565 11 3629 711 1765 -12507 7802 -8115 15534 6689 8568 -2785 11754 -7588 -1967 -11290 -8111 -9184 -13450 7331 8817 7912 7486 4673 5564 957 8481 -3065 11290 -1139 2771 369 3600 -5235 -10352 544 1441 -12532 -675 -111 6290 -10752 678 -3231 -308 452 6414 2898 2142 4607 6603 -6488 843 -4865 -7673 19158 -1371 -4352 -322 12351 1107 -756 -1447 10613 850 -2681 6330 -3234 -3839 -15552 6933 3562 -4953 4094 338 8646 3650 7101 -5838 -2458 8377 626 -2197 732 11568 -2300 6175 2741 -1818 12045 -6293 11032 363 389 -10791 -12983 -2921 -1197 563 5219 -5925 5704 2501 15045 7945 269 10400 1141 9945 6463 3158 5396 3343 2647 -6942 4736 -4398 -5834 -7299 2745 -11844 -4663 -4273 3205 4727 -6048 8549 -7040 8005 663 2493 -1594 7569 -8438 -3832 5499 -601 -3821 9940 -438 6686 -7086 -272 -6700 -6387 3089 3688 -5026 2915 -1599 -786 -319 -7059 -2807 12 3763 757 1864 -15308 7827 -9543 14316 6646 8225 -2954 10663 -7751 -2011 -11888 -8358 -9712 -15010 6631 7736 6871 6434 4101 4833 874 7251 -2979 9652 -1117 2631 359 3370 -5323 -11087 527 1394 -13929 -653 -103 5236 -10209 558 -2719 -249 366 5051 2491 1966 4312 6180 -6919 827 -5013 -8148 15690 -1388 -4543 -322 10838 1091 -769 -1504 9838 861 -2750 5782 -3187 -3783 -16269 6177 3092 -4678 3520 301 7031 3076 6039 -5267 -2144 6635 546 -2009 661 9505 -2202 5492 2542 -1770 10203 -6370 9298 335 352 -10786 SO 20170428T103717.0Z 6327.442558 461 1 32.00 2 88.95 71.80 114.10 85.66 0.00 1 0.00 1 0 15 4.252e-02 4.240e-02 4.571e-02 4.519e-02 2.636388e+03 2.789752e+03 2.842603e+02 -6.000000e+00 2.349980e+03 285.83 -2.00 20.00 -2.00 505.25 0.00e+00 1.686854e-03 1.232006e-03 9.521948e-05 -6.000000e+00 1.187375e-03 285.83 -2.00 20.00 -2.00 500.14 0.00e+00 3.163348e+00 8.881656e-01 1.969727e-02 -6.000000e+00 8.303105e-01 225.59 -2.00 3.16 -2.00 501.76 0.00e+00 18.480 0.059 489.00 513.00 1 8.9453e+00 6.8027e-02 2.7900e-02 -6.0000e+00 6.3671e-02 6.4622e-02 1.7595e-02 1.5669e-03 -6.0000e+00 1.6624e-02 1.4093e-05 1.7780e-04 4.2501e-03 5.0049e-05 -6.0000e+00 4.1830e-03 6.4321e-02 -3.8692e-04 12 8 8 10 0 0 70.41 21.45 3.51 0.06432 0.06555 8 2 1 4 0 4000.000 25.58 19.75 21.45 871 725 -6884 2968 -260 4787 -2006 3643 -2656 -3824 3562 3053 -1680 -5784 2585 -1615 -2480 -3265 720 8261 -5713 2286 4406 6532 2358 1229 -3060 13860 1313 -9535 -1120 -1190 -8157 5245 -814 5515 -316 789 -2280 533 542 2327 1890 3351 6417 -4543 -550 -374 -4718 4825 -2273 9901 -4815 239 -8886 264 4310 -7208 2473 -2446 6954 605 -610 4308 -5963 491 -2316 2361 2587 6378 -3920 -1193 -7792 -541 6723 -4792 3923 -6501 442 3378 5982 3797 886 3077 -4132 -2946 2519 -8345 -5049 4923 3656 6838 -1863 3242 6596 7982 -594 1433 -3509 -5081 1709 -4580 831 -2044 46 -4299 1412 -1298 -1301 -4367 -1635 5523 -2636 796 -7944 -1327 2165 45 8550 -3022 812 408 4482 4611 -1174 -12 1536 -3512 5384 -2200 4175 1922 8442 5348 1 -5260 434 3517 684 -3213 7645 2007 -3597 -1376 -1563 -1697 -2228 330 -1825 -1316 -921 414 -323 858 732 -7238 2919 -271 4849 -2210 3819 -2957 -4258 3630 3084 -1756 -6235 2550 -1669 -2630 -3577 776 8369 -6681 2471 4671 6810 2577 1361 -3524 13344 1404 -11039 -1164 -1233 -9226 5360 -912 5880 -357 871 -2565 577 586 2481 2042 3612 6785 -5394 -626 -422 -5475 4987 -2456 9211 -5076 238 -9815 274 4417 -7923 2485 -2581 6662 618 -634 4270 -6538 500 -2392 2288 2464 5774 -3886 -1140 -7939 -517 6050 -4883 3650 -6606 411 3012 5168 3354 810 2768 -4027 -2863 2336 -8665 -5074 4471 3360 6115 -1836 3079 6118 7293 -583 1353 -3400 -4882 1500 -4210 722 -1862 42 -4285 1357 -1283 -1272 -4341 -1571 4970 -2613 776 -8073 -1276 2025 43 7597 -3024 779 388 4030 4085 -1095 -11 1409 -3404 4784 -2109 3753 1768 7259 4696 1 -4989 387 3061 624 -3114 6773 1909 -3655 -1377 -1576 -1724 -2287 330 -1850 -1303 -888 387 -304 SO 20170428T104125.0Z 6327.445428 465 1 31.99 2 88.14 71.21 113.29 85.11 0.00 1 0.00 1 0 22 7.353e-03 7.235e-03 5.056e-03 5.031e-03 1.459111e+04 3.672080e+02 9.907886e+02 -6.000000e+00 4.064852e+02 285.83 -2.00 20.00 -2.00 505.42 0.00e+00 3.900370e-03 1.381052e-04 2.278476e-04 -6.000000e+00 2.053376e-04 285.83 -2.00 20.00 -2.00 500.78 0.00e+00 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