File name: Pandora114s1_BuenosAires_20170501_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T003615.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170501_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170501 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170501T103535.0Z 6330.441377 461 1 32.00 2 89.75 71.25 150.19 114.01 0.00 1 0.00 1 0 29 6.910e-02 6.834e-02 7.020e-02 6.884e-02 3.152782e+03 4.420183e+03 1.462573e+02 -6.000000e+00 3.816778e+03 285.63 -2.00 20.00 -2.00 505.26 0.00e+00 -7.153839e-04 1.875742e-03 3.499002e-05 -6.000000e+00 1.928772e-03 285.63 -2.00 20.00 -2.00 500.01 0.00e+00 3.012960e+00 1.370070e+00 3.669637e-02 -6.000000e+00 1.348426e+00 225.43 -2.00 3.16 -2.00 501.66 0.00e+00 20.058 0.076 489.00 513.00 1 9.1996e+00 1.0503e-01 3.0824e-02 -6.0000e+00 1.0341e-01 8.7160e-02 2.6934e-02 1.8170e-03 -6.0000e+00 2.6973e-02 9.0907e-06 8.0702e-03 6.4324e-03 9.8046e-06 -6.0000e+00 6.7980e-03 6.7379e-02 -3.4841e-04 12 8 8 10 0 0 94.25 21.55 7.91 0.06738 0.12336 8 2 1 4 0 4000.000 25.68 20.16 21.55 3607 1264 -7040 -3783 9300 -4423 -1184 9941 476 -835 -6307 825 -6695 -4549 4317 3240 -4766 -15093 2766 1507 1320 1847 7147 -9879 2357 7620 -6083 6204 7170 -47 -10879 2499 -13837 2924 3531 6123 15162 -1629 6812 7384 -4084 -747 11430 13379 9619 2920 674 -9951 -7266 4416 -1135 1524 4152 -692 3339 1796 -120 1528 -4521 1797 -6973 7571 86 -10578 2532 873 -3728 6124 8098 -1905 -12320 8666 953 17055 2987 1488 1739 296 8257 1971 346 -11693 1898 -9309 2792 4768 -11448 7747 17394 2497 457 -3651 -5019 -1403 3616 14979 2930 -3486 -59 -491 -9271 11736 -1458 2998 9840 9008 -1602 -12718 15163 1819 5371 -14548 13156 -291 744 -726 -1463 -463 -2818 6534 -1232 6411 -9984 -1620 830 4502 -2897 -6023 11421 -8165 -4552 4078 -7317 -9924 -3006 6240 12951 -7 -6358 376 7839 4656 8644 -957 6888 3232 8207 1418 -7476 -5308 -3700 1319 -10035 3477 1286 -8041 -4303 9503 -5286 -1387 10445 546 -958 -7036 907 -7319 -4830 4195 3221 -5253 -18942 2961 1648 1449 2019 7426 -12221 2587 7918 -7196 6391 7128 -49 -12430 2518 -16868 3117 3828 6501 14596 -1832 6956 7440 -4611 -820 11209 13000 9779 3178 746 -12086 -8432 4449 -1174 1495 3903 -685 3244 1826 -127 1616 -5084 1891 -7999 7527 92 -11866 2643 915 -4025 5895 7541 -1937 -12885 7797 872 14347 2746 1393 1606 272 6894 1737 310 -11835 1689 -9343 2508 4242 -12070 6763 13791 2296 430 -3603 -5080 -1384 3400 12444 2693 -3337 -53 -435 -8797 8958 -1285 2605 8299 7902 -1581 -13945 12406 1680 4779 -15951 11097 -285 728 -726 -1480 -467 -2923 6173 -1247 5921 -10694 -1578 788 4139 -2714 -5833 9874 -8070 -4337 3561 -7116 -9768 -2721 5102 9921 -6 -6132 346 6814 4232 7616 -934 6261 3066 7427 1368 -7775 -5288 -3554 1194 -10236 SO 20170501T103939.0Z 6330.444201 465 1 32.00 2 88.96 70.66 149.46 112.92 0.00 1 0.00 1 0 29 4.977e-02 4.879e-02 5.087e-02 5.010e-02 3.446222e+03 3.223892e+03 3.310167e+02 -6.000000e+00 2.748765e+03 285.63 -2.00 20.00 -2.00 505.22 0.00e+00 2.554144e-03 1.375434e-03 1.151748e-04 -6.000000e+00 1.390415e-03 285.63 -2.00 20.00 -2.00 499.95 0.00e+00 3.303612e+00 9.944046e-01 2.452198e-02 -6.000000e+00 9.750857e-01 225.43 -2.00 3.16 -2.00 501.60 0.00e+00 18.503 0.059 489.00 513.00 1 9.0237e+00 7.6352e-02 2.8010e-02 -6.0000e+00 7.4717e-02 7.5591e-02 1.9571e-02 1.6202e-03 -6.0000e+00 1.9594e-02 1.2657e-05 1.4724e-02 4.7144e-03 5.4732e-05 -6.0000e+00 4.9038e-03 6.3768e-02 -6.2923e-04 12 8 8 10 0 0 98.70 21.55 5.22 0.06377 0.16590 8 2 1 4 0 4000.000 25.68 19.72 21.55 -10616 15725 268 5399 1618 -3722 1483 6536 8232 1975 -3180 -1513 -2103 9274 -2056 -637 -4284 -1194 3016 3694 -5779 -3983 375 -5891 2549 1866 -5115 9882 -6820 832 -1165 6810 -3444 14572 2148 -2311 -491 5516 -2790 1397 -4337 4183 502 -8885 -2220 -527 -456 2102 2712 -2970 920 -3859 3701 -7405 5315 3118 604 6499 -928 1514 -3014 3211 -310 2114 4277 272 -2001 -616 7697 -6046 6919 -66 -377 2675 -7956 -2325 -3185 -35 3290 -8956 1389 -5920 794 -7244 226 10343 -3873 1014 -10012 535 -327 -3115 2641 -552 -455 2161 6316 -1678 6763 110 -210 -8711 649 -9690 2702 10092 -3187 3889 3876 -2480 7005 412 1821 -7022 1556 4971 580 1232 2720 -3023 1229 2230 2286 -1329 -176 -1764 8669 3016 11557 6038 -1647 1440 -1999 -9398 -7387 5857 2538 -4769 6695 -9204 -577 -1472 2650 2912 -3866 6528 -3951 -975 5481 802 7717 252 -3100 -12028 14120 290 5719 1701 -4204 1607 6740 8273 2082 -3477 -1605 -2217 8653 -2147 -663 -4726 -1310 3228 3954 -6811 -4616 418 -7020 2804 2064 -6029 9867 -7837 861 -1213 6599 -3799 13882 2370 -2678 -555 5796 -3151 1504 -4955 4423 557 -10966 -2587 -606 -520 2312 2912 -3296 955 -4093 3586 -8048 5203 3215 655 6723 -971 1543 -3209 3223 -323 2154 4240 277 -2051 -612 6945 -6179 6137 -62 -359 2495 -8350 -2312 -3157 -33 2949 -8988 1253 -5760 726 -7225 211 8793 -3816 952 -10478 502 -310 -3060 2480 -543 -449 2056 5660 -1591 5750 98 -183 -8180 559 -9517 2430 8672 -3159 3568 3509 -2367 6084 387 1716 -7349 1514 4714 545 1157 2530 -2978 1150 2036 2054 -1225 -160 -1640 7312 2700 9514 5249 -1546 1310 -1871 -9338 -7084 4872 2185 -4477 5725 -9412 -550 -1433 2496 2750 -3931 6015 -4052 -966 5019 753 6621 231 -2955 SO 20170501T104347.0Z 6330.447072 469 1 32.00 2 88.16 70.07 148.71 111.85 0.00 1 0.00 1 0 15 2.691e-02 2.684e-02 2.275e-02 2.261e-02 5.385563e+03 1.502652e+03 3.296921e+02 -6.000000e+00 1.486373e+03 285.63 -2.00 20.00 -2.00 505.32 0.00e+00 2.959817e-03 6.228739e-04 1.524371e-04 -6.000000e+00 7.512375e-04 285.63 -2.00 20.00 -2.00 500.34 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