File name: Pandora114s1_BuenosAires_20170509_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T003651.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170509_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170509T104152.0Z 6338.445741 360 1 32.00 2 89.75 68.44 107.78 246.91 0.00 1 0.00 1 0 22 1.094e-01 1.007e-01 9.585e-02 9.295e-02 1.673633e+03 5.612588e+03 3.923518e+02 -6.000000e+00 6.028375e+03 285.09 -2.00 20.00 -2.00 505.28 0.00e+00 4.500721e-03 2.511447e-03 1.766504e-04 -6.000000e+00 3.049892e-03 285.09 -2.00 20.00 -2.00 500.15 0.00e+00 2.496402e+00 1.842494e+00 4.911826e-02 -6.000000e+00 2.137106e+00 225.02 -2.00 3.16 -2.00 501.77 0.00e+00 20.082 0.076 489.00 513.00 1 9.4611e+00 1.4109e-01 3.1211e-02 -6.0000e+00 1.6382e-01 9.5252e-02 3.6524e-02 1.7441e-03 -6.0000e+00 4.2811e-02 6.6813e-06 7.9051e-03 8.9546e-03 9.1583e-05 -6.0000e+00 1.0773e-02 -1.5738e-02 5.0271e-05 12 8 8 10 0 0 -122.04 21.22 18.11 -0.01574 0.03910 8 2 1 4 0 4000.000 25.39 20.43 21.22 -7969 1877 5980 -4622 -7272 10746 -4091 4170 2822 2506 2085 12851 4270 2009 15106 -11112 27503 -5753 4893 -5712 -3929 7800 1522 12469 -18537 1731 -11603 7652 19080 -20344 8713 1271 6129 12739 1858 -4477 479 -2862 -7735 19731 165 -5155 7023 -7762 366 -10050 16872 -9259 4976 -2940 8146 12840 -2373 15406 5206 -868 -11206 -10116 37445 -6144 3145 -8006 -1145 13831 -6679 -195 -8289 11065 -13442 9033 -5066 -9241 6497 2413 6125 -2446 207 5223 2866 -1886 252 1046 -19512 27127 16288 14165 5930 -8891 23490 5623 18767 26288 4544 -7851 -140 6860 24074 585 -12603 -8883 -180 -8550 13063 18896 -738 -4024 -5309 2959 -7338 8159 -14073 3479 -18667 13248 -11999 -5562 -11030 -805 3072 1286 4501 -2700 -4190 -7997 23549 11554 2258 12661 27699 -7910 -1301 8293 -2930 20617 10599 -14307 7055 -2472 7408 -5941 -13743 -4304 820 13237 33 1115 2510 8550 201 4929 6929 -16264 8652 -8453 1857 5876 -5203 -8612 10839 -4845 4559 3104 2723 2239 12209 4363 2078 13664 -13160 22551 -6289 5253 -6418 -4343 7674 1599 11814 -24093 1840 -14024 7529 16340 -25083 7885 1243 5845 11760 1963 -5085 515 -3146 -8833 17017 174 -5761 7038 -9146 403 -12330 15781 -11134 5108 -3197 7719 11308 -2393 13006 4964 -907 -13340 -12104 27974 -7090 3305 -9434 -1266 13188 -7788 -211 -9566 10350 -15838 8394 -5354 -10103 6077 2375 5878 -2570 210 4949 2733 -1867 243 1003 -21665 20266 12798 11453 5234 -9113 17388 4962 14533 19010 4140 -8226 -137 6250 18231 550 -13204 -8750 -159 -8081 9967 13880 -681 -3941 -5321 2713 -7354 6922 -14905 3130 -21365 11240 -13323 -5859 -12373 -821 3026 1289 4331 -2752 -4271 -8379 17968 10000 2160 10958 20661 -8422 -1296 7508 -2953 16200 9053 -15478 6146 -2393 6622 -6191 -14804 -4534 826 11833 32 1070 2381 7606 191 4385 5904 -17258 7187 SO 20170509T104556.0Z 6338.448565 364 1 32.00 2 88.98 67.86 108.52 246.24 0.00 1 0.00 1 0 15 5.294e-02 5.286e-02 4.985e-02 4.931e-02 6.395174e+03 3.249138e+03 4.388142e+02 -6.000000e+00 2.917704e+03 285.09 -2.00 20.00 -2.00 505.23 0.00e+00 2.719948e-03 1.345472e-03 1.694124e-04 -6.000000e+00 1.475728e-03 285.09 -2.00 20.00 -2.00 500.21 0.00e+00 2.166301e-01 9.722488e-01 4.551177e-02 -6.000000e+00 1.032963e+00 225.02 -2.00 3.16 -2.00 501.82 0.00e+00 18.560 0.060 489.00 513.00 1 9.2133e+00 7.4493e-02 2.8463e-02 -6.0000e+00 7.9206e-02 1.1627e-01 1.9277e-02 1.8118e-03 -6.0000e+00 2.0663e-02 1.2957e-05 3.8280e-03 4.6557e-03 7.4756e-05 -6.0000e+00 5.2069e-03 4.3028e-02 -2.0873e-04 12 9 8 11 8 0 70.39 21.23 5.34 0.04303 0.06958 8 2 1 4 0 4000.000 25.39 19.96 21.23 -165 2199 2172 -1313 -8151 6243 -6874 5318 5927 3225 6790 480 1697 -6821 3545 -9213 -743 4887 -1127 1305 -906 637 3572 136 3030 -1916 6297 -5139 -162 -1897 -1985 -3369 -5389 8641 -6475 -3241 -3708 2242 2645 4120 -778 2035 12841 -9497 4441 -7514 7277 -1735 8555 -421 -6033 4751 -635 6291 -1373 3604 7717 -1615 10976 -5104 5428 -4288 -1193 -2322 7267 5684 -2702 181 -1457 -1088 -6128 2792 -3004 -4350 -1478 -4358 1309 -3775 -2741 10544 286 -1472 2334 3739 -5416 1454 -3924 -14376 6636 -399 502 5218 -3765 6214 -5229 1957 4395 6442 2813 -6687 -2334 -4912 3727 -6145 6869 -2703 7371 1051 -4831 10488 -4816 10106 -5515 4416 4330 -2383 4665 -923 3033 174 1088 2315 2632 5789 -6933 5119 -10461 -1326 -5026 3820 4260 107 8692 -3084 -1129 -6260 2212 6867 -5660 -1988 4105 7219 -9039 737 -822 -1274 4400 1015 7940 -13121 3295 -2083 12427 -164 2202 2249 -1354 -9219 6236 -7929 5449 5996 3305 6608 490 1689 -7319 3416 -10152 -766 4881 -1220 1392 -989 686 3741 148 3221 -2142 6453 -5829 -171 -1974 -2028 -3495 -5834 8409 -7532 -3687 -4217 2377 2761 4209 -835 2137 12247 -11476 4722 -9055 7551 -1951 8545 -451 -6649 4578 -634 5859 -1407 3623 7658 -1790 10787 -5520 5280 -4612 -1251 -2470 7003 5512 -2807 180 -1452 -1068 -6256 2590 -2958 -4389 -1469 -4489 1266 -3774 -2666 8887 266 -1396 2144 3411 -5464 1384 -3971 -16198 6054 -389 485 4839 -3867 5857 -5560 1922 4129 5780 2549 -6505 -2129 -4540 3175 -5922 6038 -2711 6814 1035 -4991 9188 -4902 8945 -5798 4268 4238 -2365 4608 -913 2906 172 1061 2198 2447 5135 -6938 4555 -10945 -1271 -5001 3475 3851 101 7463 -2938 -1037 -5980 1937 5799 -5520 -1905 3758 6485 -9637 716 -815 -1275 4166 990 7134 -14250 2970 -1954 10105 SO 20170509T105003.0Z 6338.451424 368 1 32.00 2 88.19 67.26 109.26 245.56 0.00 1 0.00 1 0 22 2.620e-02 2.630e-02 2.368e-02 2.354e-02 7.282201e+03 1.612831e+03 5.823323e+02 -6.000000e+00 1.444386e+03 285.09 -2.00 20.00 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