File name: Pandora114s1_BuenosAires_20170514_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T004040.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170514_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170514 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170514T104547.0Z 6343.448461 342 1 32.00 2 89.74 66.86 57.75 268.32 0.00 1 0.00 1 0 22 8.269e-02 7.727e-02 8.127e-02 7.947e-02 3.708828e+03 5.161682e+03 1.958586e+02 -6.000000e+00 4.554486e+03 284.76 -2.00 20.00 -2.00 505.25 0.00e+00 -3.550891e-04 2.164918e-03 4.684322e-05 -6.000000e+00 2.306258e-03 284.76 -2.00 20.00 -2.00 500.04 0.00e+00 2.344378e+00 1.594438e+00 4.061942e-02 -6.000000e+00 1.617883e+00 224.77 -2.00 3.16 -2.00 501.68 0.00e+00 20.079 0.076 489.00 513.00 1 9.3809e+00 1.2172e-01 3.0913e-02 -6.0000e+00 1.2395e-01 1.0237e-01 3.1710e-02 1.8584e-03 -6.0000e+00 3.2503e-02 7.8807e-06 1.4414e-03 7.4291e-03 2.0922e-05 -6.0000e+00 8.1503e-03 -2.5868e-02 8.5416e-04 12 9 8 11 8 0 74.25 21.42 5.86 -0.02587 -0.01587 8 2 1 4 0 4000.000 25.47 20.32 21.42 -5159 1797 3918 -5605 1030 -3972 760 1210 7841 -2618 4020 10861 -7815 7998 -14579 2283 1702 290 -2838 -1833 -1699 -2051 9968 4836 -1181 5604 8716 -638 -11273 3533 -6700 8018 -5468 4908 6636 -1929 -2894 501 2803 3278 463 16335 1207 7156 5763 -7279 2901 3867 1844 -12939 5136 -16493 -1486 -11916 3227 6698 -4261 1381 -9416 -1886 -11467 1865 -2671 13022 12228 10280 -4263 2796 10908 18776 1488 6836 -4155 3990 -213 3776 -363 -11701 13948 -2685 14622 -7294 -7026 -9084 3808 -2597 -486 2827 -2941 15152 -46 -2669 -426 920 1635 144 -2070 9091 -8037 421 -1138 24991 -10381 -4795 5371 937 -153 -13882 16145 -10252 19339 -7225 -1363 7634 -284 2252 3782 -73 -1612 10186 -3637 -5295 9648 -5232 -3619 2528 13908 -15925 9389 12022 -3369 13991 5622 27857 -19169 -8604 1338 -4006 5424 -5259 4575 -8672 3827 1010 2608 1598 -8079 7635 -6751 21608 -6975 4275 900000 -5454 1829 4033 -6518 1146 -4729 871 1380 8288 -3029 4294 10695 -9173 7965 -17033 2288 1758 312 -3198 -2056 -1906 -2311 9990 5122 -1331 5878 8780 -693 -13229 3486 -7271 7619 -6133 5123 6926 -2194 -3291 543 2941 3404 495 15013 1304 7358 6045 -8693 3104 4036 1924 -15251 4907 -19098 -1466 -13179 3150 6504 -4713 1456 -11050 -2047 -13694 1956 -2940 12239 11492 9715 -4583 2759 9799 15404 1437 6247 -4272 3833 -216 3666 -339 -12018 11660 -2470 12072 -7066 -6840 -9109 3393 -2491 -459 2587 -2849 12244 -43 -2611 -412 887 1560 137 -1975 7568 -7747 365 -986 16667 -10056 -4552 4785 894 -149 -15273 12968 -10630 14969 -7386 -1334 6912 -281 2182 3627 -73 -1647 9223 -3735 -5438 8407 -5246 -3576 2363 11645 -17986 8227 10242 -3149 11646 5036 19663 -20112 -8081 1218 -3689 4937 -5108 4088 -8940 3507 958 2449 1522 -8476 6786 -6805 16038 -6775 3702 900000 SO 20170514T104952.0Z 6343.451296 346 1 31.99 2 88.97 66.27 58.57 267.78 0.00 1 0.00 1 0 29 6.169e-02 6.049e-02 5.385e-02 5.304e-02 5.714436e+03 3.506580e+03 4.896429e+02 -6.000000e+00 3.397042e+03 284.75 -2.00 20.00 -2.00 505.26 0.00e+00 3.099162e-03 1.438870e-03 1.627081e-04 -6.000000e+00 1.717438e-03 284.75 -2.00 20.00 -2.00 500.21 0.00e+00 1.552536e+00 1.043184e+00 2.384945e-02 -6.000000e+00 1.197135e+00 224.77 -2.00 3.16 -2.00 501.81 0.00e+00 18.560 0.060 489.00 513.00 1 9.1830e+00 7.9870e-02 2.8262e-02 -6.0000e+00 9.1880e-02 9.6536e-02 2.0377e-02 1.6124e-03 -6.0000e+00 2.3801e-02 1.2028e-05 8.5355e-03 4.9834e-03 8.4421e-05 -6.0000e+00 6.0521e-03 -7.3757e-03 4.7761e-04 12 9 8 11 8 0 -158.84 21.43 -0.19 -0.00738 0.05183 8 2 1 4 0 4000.000 25.58 19.80 21.43 -1058 7855 -8388 -3871 6648 -6999 1151 -4532 3881 -4883 2156 782 3485 2855 -5680 -3528 -4073 4118 3079 -774 4489 -4884 12349 -7436 14652 -2676 -846 15779 -8919 -743 -11873 2475 7426 5354 7568 -3125 1844 -1883 -2130 -1359 -201 4121 -5572 10401 996 -198 5059 -214 7379 2779 7397 -6445 -4486 -11784 8751 6399 6715 2558 -9322 -2948 -9316 5669 6023 -7450 -1666 -5532 14753 2216 -703 -2903 7273 -6893 -7987 16094 -4827 1345 1127 5627 -3075 -1250 9343 1613 -1248 1964 5379 2623 -113 -2198 2568 4839 -8452 7707 -3769 2384 8617 3106 1413 -6271 -895 6633 -8584 -1208 11632 -1235 -8178 -3660 3698 -673 4638 -5109 -1084 -2844 4881 1846 8901 8480 439 -1644 -10920 -846 -6372 6735 3462 -9536 4601 -6506 1664 -8284 -1422 14503 1000 7844 -2498 1525 -471 13753 4391 -3986 3337 1996 8070 -10394 8301 -1239 1117 2662 -3737 -4773 -3969 -1834 -161 2455 -4392 -1084 7614 -9876 -4471 7061 -8078 1233 -5122 3982 -5382 2182 791 3394 2781 -6045 -3730 -4433 4225 3234 -848 4668 -5586 11943 -8815 13967 -3024 -930 14385 -10110 -758 -13458 2471 7285 5530 7765 -3563 1982 -2076 -2333 -1474 -217 4300 -6489 10455 1108 -223 5366 -235 7392 2842 7025 -6881 -4664 -13357 8311 6410 6843 2740 -11245 -3331 -10536 5915 5891 -8328 -1744 -5932 13551 2131 -688 -2868 6428 -7011 -8280 13284 -4957 1293 1069 5010 -2947 -1170 7863 1473 -1180 1813 4842 2446 -109 -2157 2395 4403 -8817 6912 -3846 2309 7813 2928 1323 -6175 -814 5475 -8118 -1060 9147 -1144 -8424 -3687 3472 -654 4220 -5097 -1046 -2837 4584 1811 8215 7909 446 -1720 -11857 -880 -6510 6304 3296 -9654 4053 -6447 1527 -8412 -1348 11710 923 6742 -2353 1357 -422 10642 3761 -3780 3001 1850 7133 -11159 7439 -1228 1086 2556 -3817 -4875 -3945 -1744 -149 2200 -4272 SO 20170514T105359.0Z 6343.454155 350 1 32.00 2 88.20 65.68 59.39 267.23 0.00 1 0.00 1 0 15 3.312e-02 3.268e-02 3.738e-02 3.697e-02 8.670618e+03 2.540321e+03 6.971781e+02 -6.000000e+00 1.822561e+03 284.75 -2.00 20.00 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