File name: Pandora114s1_BuenosAires_20170516_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T004422.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170516_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170516 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170516T104719.0Z 6345.449525 344 1 31.99 2 89.74 66.27 39.42 284.56 0.00 1 0.00 1 0 22 7.673e-02 7.240e-02 8.464e-02 8.283e-02 2.933232e+03 5.358801e+03 5.937527e+01 -6.000000e+00 4.222574e+03 284.63 -2.00 20.00 -2.00 505.28 0.00e+00 5.877550e-03 2.276454e-03 3.288709e-04 -6.000000e+00 2.135269e-03 284.63 -2.00 20.00 -2.00 500.14 0.00e+00 1.170937e+00 1.657199e+00 9.217689e-02 -6.000000e+00 1.489148e+00 224.68 -2.00 3.16 -2.00 501.76 0.00e+00 20.079 0.076 489.00 513.00 1 9.4228e+00 1.2701e-01 3.2478e-02 -6.0000e+00 1.1428e-01 1.3569e-01 3.2446e-02 2.1265e-03 -6.0000e+00 2.9615e-02 7.5504e-06 4.9975e-03 7.8038e-03 1.2464e-04 -6.0000e+00 7.5279e-03 -7.6873e-04 4.1933e-04 12 8 8 10 0 0 97.51 21.11 7.47 -0.00077 0.03390 8 2 1 4 0 4000.000 25.28 19.97 21.11 5107 -7863 2370 2889 -11831 -3599 10136 -4122 -429 -1166 4604 1437 -2013 -7564 -244 -777 -6481 -719 7613 2068 7957 -5850 12419 6420 1674 -956 -3715 2573 -4959 654 10623 740 -8712 5821 8829 58 7017 -5921 8282 10926 -9769 3818 1140 2587 -3724 -7565 -72 -1801 5596 2160 -5197 -9968 -4346 5956 12134 -1802 -7251 26124 -9631 9582 -670 9095 -5031 -233 -2851 -745 11450 5976 -5273 1755 93 19204 -336 2443 -8324 -2443 2526 -2570 7764 -4708 4566 -2979 5910 14996 1450 12556 -1957 -15423 3012 -580 -8119 -6116 14927 -1024 -2623 -17577 1034 22325 -6843 21582 767 13699 -11891 -6107 10179 15978 -2734 2690 -4636 2320 -4184 7503 1663 2432 149 1089 4929 -4584 4784 -2221 1106 1548 603 2446 -11556 -5041 -6465 3547 2521 1325 10697 8716 -7622 6568 6076 11724 5909 -9854 -7459 -7292 -1035 3457 3372 11372 6192 -8531 6374 -12338 -8697 -4255 621 4015 6823 4887 -8847 2487 3099 -15026 -4279 10581 -4948 -490 -1318 4832 1533 -2195 -8642 -259 -838 -7051 -755 7459 2149 7796 -6587 11697 6464 1776 -1040 -4123 2633 -5315 644 9373 729 -9714 5797 8698 63 6989 -6634 7980 10232 -11316 3906 1215 2758 -4273 -9049 -79 -1999 5664 2210 -5570 -10953 -4469 5578 10968 -1931 -8399 21918 -11573 9491 -736 9107 -5828 -257 -3210 -811 10846 5887 -5736 1757 93 15904 -340 2433 -9327 -2579 2502 -2630 7060 -4515 3985 -2812 5129 11947 1332 10386 -1877 -16905 2736 -545 -8240 -6145 12347 -1008 -2636 -20337 976 16654 -6668 15442 661 10289 -11646 -5796 8472 12811 -2650 2444 -4470 2072 -4013 6511 1561 2308 147 1072 4702 -4838 4612 -2288 1088 1493 578 2284 -12432 -5117 -6693 3330 2392 1270 9336 7740 -7426 5799 5303 9578 5128 -10151 -7646 -7586 -1024 3298 3044 10099 5471 -8760 5632 -13023 -8681 -3963 540 3356 5605 SO 20170516T105124.0Z 6345.452361 348 1 32.00 2 88.97 65.68 40.23 283.76 0.00 1 0.00 1 0 15 6.803e-02 6.881e-02 5.428e-02 5.341e-02 3.018362e+03 3.343495e+03 1.526913e+02 -6.000000e+00 3.743209e+03 284.63 -2.00 20.00 -2.00 505.27 0.00e+00 1.925994e-03 1.450587e-03 3.993850e-05 -6.000000e+00 1.893752e-03 284.63 -2.00 20.00 -2.00 500.19 0.00e+00 1.310101e+00 1.047648e+00 3.088466e-02 -6.000000e+00 1.323165e+00 224.68 -2.00 3.16 -2.00 501.82 0.00e+00 18.564 0.060 489.00 513.00 1 9.2277e+00 8.0144e-02 2.8063e-02 -6.0000e+00 1.0151e-01 1.0555e-01 2.0634e-02 1.6398e-03 -6.0000e+00 2.6373e-02 1.1944e-05 5.3494e-03 5.0119e-03 2.0349e-05 -6.0000e+00 6.6865e-03 -3.2508e-02 4.7407e-04 12 8 8 10 0 0 -79.76 21.11 5.83 -0.03251 0.00460 8 2 1 4 0 4000.000 25.28 19.55 21.11 6854 -2839 -14475 -1827 -5355 2670 -834 243 -619 -6836 4779 -9448 2480 -11264 793 2557 1912 1705 -7822 7929 -3686 10586 2041 1569 9634 -6209 10550 -3639 7013 -8214 4940 1473 -6694 4788 -3558 6842 2784 1913 11497 -3604 5075 -15928 10822 2553 2841 9085 -1463 9792 -4457 1213 -8676 15798 1754 8536 8610 -8585 4190 2140 8797 885 4474 -1971 367 -2985 -7447 5008 -913 7457 4023 -5604 6057 -7817 3890 -4469 -2242 4853 -6350 7703 -7809 2784 -10024 9809 -3020 5550 8333 -749 3689 763 7778 2611 3216 3348 -1706 8468 -2606 -2522 9091 3210 7379 -10379 2693 -8881 9133 6120 3498 3086 -4652 452 -18170 2107 7601 14918 1027 -2302 172 -7724 7541 -5659 -622 1752 3339 6477 1172 8448 -6746 10369 -2190 -7034 -3276 -13157 11547 -148 5527 -3816 -1434 3519 -2955 8722 -12712 5129 -2319 5969 4952 857 6623 -14895 9549 -1250 -1622 -6429 1839 8816 -11620 6433 -3025 -17915 -2050 -5943 2985 -911 263 -670 -7754 4753 -10684 2458 -12698 792 2535 1948 1785 -9172 7997 -4181 10419 2194 1703 9684 -7303 10420 -4077 6878 -9116 4741 1475 -7476 4930 -4073 7092 2983 2043 11034 -3999 5172 -20179 10613 2754 3084 9290 -1654 9774 -5040 1266 -9720 13508 1702 7775 8023 -9797 4313 2278 8780 954 4653 -2057 376 -3165 -8212 4818 -917 6782 3738 -5666 5390 -7954 3538 -4474 -2222 4493 -6503 6729 -7844 2496 -10200 8216 -2895 4921 7252 -721 3416 729 6922 2443 2999 3144 -1708 7758 -2678 -2566 8090 2962 6374 -10459 2335 -8572 7441 5286 3216 2928 -4810 441 -21046 1972 6740 12446 1001 -2357 174 -8517 7180 -6184 -649 1783 3310 6125 1150 7629 -6668 8685 -2091 -7062 -3168 -14018 9601 -139 4833 -3608 -1303 3012 -2703 7198 -13270 4564 -2257 5404 4560 826 6058 -16971 8527 -1236 -1583 -6434 1659 7357 -11987 SO 20170516T105533.0Z 6345.455243 352 1 32.00 2 88.20 65.09 41.04 282.97 0.00 1 0.00 1 0 22 3.826e-02 3.744e-02 3.814e-02 3.771e-02 6.904388e+03 2.504337e+03 5.049243e+02 -6.000000e+00 2.104792e+03 284.63 -2.00 20.00 -2.00 505.21 0.00e+00 1.030759e-03 1.021371e-03 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