File name: Pandora114s1_BuenosAires_20170529_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T005515.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170529_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170529 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170529T105621.0Z 6358.455799 493 1 32.00 2 89.76 63.16 131.88 96.02 0.00 1 0.00 1 0 71 5.962e-01 3.454e-01 5.392e-01 3.843e-01 -3.388609e+03 2.543820e+04 1.168520e+03 -6.000000e+00 3.278975e+04 283.97 -2.00 20.00 -2.00 505.38 0.00e+00 2.072077e-02 1.043144e-02 3.777063e-04 -6.000000e+00 1.670436e-02 283.97 -2.00 20.00 -2.00 499.87 0.00e+00 1.077070e+01 7.613280e+00 5.748386e-01 -6.000000e+00 1.186127e+01 224.44 -2.00 3.16 -2.00 501.59 0.00e+00 20.132 0.076 489.00 513.00 1 9.9504e+00 5.7111e-01 5.3013e-02 -6.0000e+00 9.0641e-01 -4.9426e-02 1.4739e-01 8.1438e-03 -6.0000e+00 2.4160e-01 1.4223e-06 1.0189e-01 3.4168e-02 1.4293e-04 -6.0000e+00 5.9226e-02 2.0137e-01 -1.7025e-03 12 13 8 11 8 0 98.39 21.15 0.55 0.20137 0.90814 8 2 1 4 0 4000.000 25.28 19.57 21.15 -17471 100579 -9790 87351 13231 -5354 6929 16115 43926 -2948 18243 49437 -5850 900000 -8761 60460 -41904 15788 -10120 24277 106200 27775 92831 -17938 -2443 37638 19528 129273 20067 12140 -7174 43252 8698 -35421 78066 -961 33668 -18937 107899 -24300 54113 -4524 -8950 938 -40277 11637 -1485 15673 71617 -7608 142129 -7532 130745 -26885 58356 61991 -24804 107058 27176 90851 6689 42207 -29111 14249 129711 15486 163295 26999 88331 11790 64985 9894 38962 182609 12229 35084 -33093 48330 -15712 78347 19495 -25730 61101 100 31161 30807 -20861 14773 59417 236668 15443 43406 53779 21035 44939 41551 107866 -24357 98835 41713 -23178 4628 -28008 -27482 -7055 120907 -14787 6265 4892 41577 34158 -36453 172537 9393 19171 35802 64518 -11753 11178 900000 16455 7994 -10197 -47757 35108 -42167 56521 -21771 -156 2551 -27611 7586 26635 900000 30263 138764 12045 -36308 79551 67115 49532 -1071 71993 -8821 48935 19556 49251 61842 -19672 900000 47675 62147 97005 -25841 45980 -13427 44631 13876 -6622 7453 15601 31893 -3409 17170 34565 -7237 900000 -11308 39020 -75500 16134 -13607 23502 45694 26142 44934 -25565 -2891 29352 18380 48669 18635 12492 -9003 32567 9169 -57787 44085 -1134 28731 -28043 49327 -39644 40745 -6132 -12579 1177 -74806 12559 -1789 15735 41342 -9929 53509 -10398 49223 -45885 42475 43565 -41711 48366 27283 47885 8059 34959 -48222 15021 48834 15547 61477 23717 42123 12132 39145 10181 29337 68749 11664 26417 -49004 31538 -19323 37362 16636 -34227 33738 100 22681 22423 -25656 12977 34299 89101 14341 30504 33745 17950 29325 27114 40610 -27509 37209 26174 -26178 3920 -32292 -31040 -6475 45519 -15309 5455 4489 27393 24916 -54895 64957 9062 16691 26115 34917 -13551 10258 900000 14713 7900 -12237 -84279 27261 -71438 35908 -30224 -173 2701 -38981 7496 21935 900000 24923 52242 12187 -59804 41181 39480 34964 -1260 40656 -11001 33392 17485 32448 36379 -26847 900000 34776 39482 43368 SO 20170529T110034.0Z 6358.458727 497 1 32.00 2 88.99 62.56 131.06 95.38 0.00 1 0.00 1 0 74 4.883e-01 3.195e-01 4.944e-01 3.701e-01 -3.257922e+03 2.251221e+04 1.813672e+03 -6.000000e+00 2.678647e+04 283.97 -2.00 20.00 -2.00 505.39 0.00e+00 8.785195e-03 1.027082e-02 8.011195e-04 -6.000000e+00 1.356197e-02 283.97 -2.00 20.00 -2.00 500.14 0.00e+00 7.181564e+00 7.501019e+00 2.473005e-01 -6.000000e+00 9.484165e+00 224.44 -2.00 3.16 -2.00 501.75 0.00e+00 18.626 0.060 489.00 513.00 1 1.0570e+01 5.6221e-01 3.7266e-02 -6.0000e+00 7.2747e-01 1.0862e-02 1.5356e-01 2.6935e-03 -6.0000e+00 1.8893e-01 1.5583e-06 -6.3246e-02 2.9937e-02 2.9050e-04 -6.0000e+00 4.7942e-02 1.8017e-01 -7.8366e-04 12 8 8 10 0 0 98.05 21.13 36.35 0.18017 -0.25853 8 2 1 4 0 4000.000 25.28 20.05 21.13 -37217 49893 46819 63288 3227 4304 -21006 12995 49865 19359 6087 -568 37654 24462 -14968 49283 673 51032 109907 26370 66188 56593 26422 -28025 98896 -22897 25078 40106 -725 -17211 4840 927 -6027 32757 7660 -4479 -30258 25111 41108 -15149 60434 45505 62312 16723 22493 53475 -8909 43734 -30359 61632 11488 -28850 22392 -51782 -949 999 4382 -25819 115325 -35742 12922 39748 -15288 135761 62670 34242 7869 3561 102872 95980 124676 50081 121339 22625 -12826 44814 -35709 69024 -13696 61188 68004 10637 37794 10702 77160 27137 8070 43849 37138 55550 -46015 55196 7748 29717 67398 11095 7798 -15968 82786 18885 13132 62811 38318 -19365 -13999 38218 31362 11957 -30920 4856 -32080 -17098 14185 28449 -1121 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27159 24739 17421 -37773 -12529 -29743 30069 -25058 20341 -16289 3211 38904 -6273 38884 -14661 30652 23773 -14656 29089 12402 37654 30980 65952 25900 -36600 26962 -34999 51799 27043 SO 20170529T110440.0Z 6358.461574 501 1 32.00 2 88.25 61.97 130.26 94.77 0.00 1 0.00 1 0 67 4.057e-01 2.843e-01 3.294e-01 2.594e-01 1.859414e+02 1.495022e+04 5.949012e+02 -6.000000e+00 2.228138e+04 283.97 -2.00 20.00 -2.00 505.32 0.00e+00 -3.021093e-03 7.200940e-03 2.313458e-04 -6.000000e+00 1.129185e-02 283.97 -2.00 20.00 -2.00 500.18 0.00e+00 1.111568e+00 5.213648e+00 9.754143e-02 -6.000000e+00 7.929961e+00 224.44 -2.00 3.16 -2.00 501.89 0.00e+00 16.698 0.044 489.00 513.00 1 1.1119e+01 4.0475e-01 2.6258e-02 -6.0000e+00 6.0753e-01 8.9507e-02 1.0230e-01 1.6917e-03 -6.0000e+00 1.5908e-01 2.2550e-06 -5.6201e-03 2.5096e-02 1.5633e-04 -6.0000e+00 3.9973e-02 -3.5049e-02 9.8806e-04 12 9 8 11 8 0 99.40 21.14 6.97 -0.03505 -0.07403 8 2 1 4 0 4000.000 25.28 20.39 21.14 51875 22357 13596 3992 -37481 37110 -15318 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