File name: Pandora114s1_BuenosAires_20170602_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T005541.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170602_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170602 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170602T105847.0Z 6362.457488 461 1 32.00 2 89.77 62.46 150.55 174.55 0.00 1 0.00 1 0 22 1.136e-01 1.047e-01 9.676e-02 9.378e-02 1.226371e+04 6.801059e+03 1.008870e+03 -6.000000e+00 6.228982e+03 283.77 -2.00 20.00 -2.00 505.32 0.00e+00 -4.890842e-04 2.550358e-03 1.186943e-04 -6.000000e+00 3.156539e-03 283.77 -2.00 20.00 -2.00 500.17 0.00e+00 -1.373340e+00 1.855477e+00 3.790079e-02 -6.000000e+00 2.217473e+00 224.37 -2.00 3.16 -2.00 501.80 0.00e+00 20.145 0.077 489.00 513.00 1 9.7909e+00 1.4111e-01 3.1202e-02 -6.0000e+00 1.6995e-01 1.5109e-01 3.6815e-02 2.1688e-03 -6.0000e+00 4.4367e-02 6.6615e-06 3.0178e-03 8.4231e-03 9.4067e-05 -6.0000e+00 1.1175e-02 -1.5775e-02 1.1798e-04 12 9 8 11 8 0 -9.85 20.77 8.24 -0.01578 0.00516 8 2 1 4 0 4000.000 24.96 19.38 20.77 178 -13015 583 10206 -1367 -5640 -4163 3374 -3943 2985 299 8977 -9911 -8165 -308 -2790 7805 3380 16690 21383 4182 24642 1986 16655 914 3220 -11983 2093 6565 7502 -9227 -6456 2760 -16740 -1667 1290 -9320 2829 -8462 -2234 -3656 33097 8924 3896 7955 -10976 4103 -15554 -7362 3144 1101 812 -10219 -2857 -10701 20132 -11337 -2899 11697 -5601 11528 7330 9745 -12944 6894 6694 11046 16976 2501 14608 -9562 21003 16025 -6017 -983 -19430 -447 -4400 10887 9697 12027 5967 -7662 1096 11465 3674 -5854 6610 11155 1367 2408 4025 8798 -457 1471 -5696 7072 11814 -9931 37316 -15972 6241 -1299 12224 21438 -20104 39103 -10538 -2043 -8724 1383 -11482 -2232 3993 -10389 12050 6547 3521 16327 -4582 10761 -6480 11815 494 -13465 11630 -4459 2846 -17368 -15043 8605 10934 14345 -16713 2018 -6887 16527 -11482 3330 -11403 -4402 17362 21267 11414 -1579 2720 5062 16454 583 -6270 771 -13976 21229 173 -14784 597 9784 -1508 -6629 -4893 3700 -4634 3234 328 8901 -11714 -9382 -326 -3041 7789 3618 16000 19797 4305 22167 2093 15208 980 3374 -14541 2181 6397 7034 -10009 -6805 2707 -20620 -1818 1384 -11081 2947 -9750 -2396 -3966 24949 8641 4012 7947 -13319 4274 -19540 -8392 3160 1100 791 -10897 -2819 -11607 16533 -13132 -3144 11039 -6282 10880 7233 9436 -15786 6887 6646 10358 14773 2483 12712 -10489 16861 13553 -6416 -1012 -24292 -461 -4638 9675 8617 10393 5486 -7615 1008 9617 3377 -5987 6001 9678 1304 2269 3746 7885 -454 1436 -5890 6257 9638 -9756 22297 -15967 4948 -1120 9481 15889 -23679 26285 -11745 -2077 -9373 1335 -12666 -2269 3854 -11639 10800 6206 3459 14258 -4976 10015 -7074 10522 482 -14930 10023 -4534 2698 -20156 -17026 7663 9486 11950 -18725 1843 -6806 12914 -12006 3061 -12383 -4527 14563 17351 10361 -1546 2560 4653 13435 552 -6238 700 -14510 15497 SO 20170602T110251.0Z 6362.460313 465 1 32.01 2 89.03 61.88 150.45 172.60 0.00 1 0.00 1 0 15 5.489e-02 5.389e-02 5.397e-02 5.336e-02 7.412013e+03 3.562559e+03 4.080557e+02 -6.000000e+00 3.009426e+03 283.77 -2.00 20.00 -2.00 505.27 0.00e+00 1.107087e-03 1.456074e-03 4.605246e-05 -6.000000e+00 1.525361e-03 283.77 -2.00 20.00 -2.00 500.32 0.00e+00 4.196188e-01 1.045265e+00 6.969961e-02 -6.000000e+00 1.072414e+00 224.37 -2.00 3.16 -2.00 501.92 0.00e+00 18.718 0.061 489.00 513.00 1 9.2662e+00 7.9850e-02 2.8810e-02 -6.0000e+00 8.2169e-02 9.3712e-02 2.0560e-02 2.1015e-03 -6.0000e+00 2.1485e-02 1.2058e-05 3.5276e-03 4.9158e-03 4.1040e-05 -6.0000e+00 5.4025e-03 6.9288e-02 -4.7844e-04 12 8 8 10 0 0 93.99 20.75 6.14 0.06929 0.09376 8 2 1 4 0 4000.000 24.96 20.49 20.75 -1722 -5409 5715 -6856 -12249 7052 1889 -1187 -4178 2843 -2036 4201 1842 4077 -316 -3848 -4058 -3481 423 1601 -5110 8525 2875 5671 -3911 295 3443 -315 4197 608 6374 4112 4696 -5715 -882 9052 -3674 9492 -9195 2304 1145 -3548 -1908 6927 4020 4287 -4633 -10518 1129 727 -3534 3696 2447 -2548 -4323 -1323 -2669 7599 -1052 3814 9202 -3145 6851 -2254 9500 574 -489 1924 -7835 5017 6834 4998 -2562 -501 4405 -819 -10434 -6755 -915 15952 -4208 3295 3172 6192 -5589 -801 -4440 1317 12830 -4806 2072 -2132 950 939 1562 9368 -9162 -2939 1557 -523 -722 4812 -1587 5343 -1491 -454 4067 -6056 -6330 12044 574 7093 -5391 7471 -2288 1816 -900 -913 13149 -6360 5021 -2227 -4019 -4459 -7492 5238 -6430 7621 -6823 9083 -6168 13483 -452 -1043 -699 2538 9839 1172 69 3110 -1660 -581 -2900 -1260 -7706 6102 -2627 6079 -2434 -4602 2974 -10040 6533 -1699 -5679 5552 -7787 -14051 7298 1950 -1271 -4589 2875 -2129 4072 1805 3867 -312 -3958 -4259 -3727 446 1686 -5773 8412 3007 5793 -4419 320 3601 -338 4215 615 5956 3929 4552 -6357 -962 9059 -4163 9333 -10773 2386 1198 -3910 -2089 7029 4247 4544 -5363 -12799 1205 763 -3770 3569 2347 -2559 -4492 -1374 -2894 7578 -1151 3977 9081 -3301 6539 -2365 8851 580 -492 1861 -8247 4592 6076 4493 -2487 -482 4090 -809 -11290 -6934 -871 12671 -4072 2962 2873 5485 -5627 -778 -4514 1270 11031 -4917 1978 -2132 931 933 1552 8544 -9853 -2892 1425 -477 -647 4027 -1421 4576 -1423 -447 3922 -6493 -6746 10551 561 6539 -5710 7058 -2409 1846 -945 -907 12164 -6770 4758 -2240 -4043 -4431 -7606 4690 -6508 6730 -6969 7908 -6244 11201 -430 -985 -647 2249 8082 1060 64 2870 -1634 -574 -2962 -1276 -8369 5801 -2732 5779 -2493 -4729 2772 -10502 5788 SO 20170602T110657.0Z 6362.463160 469 1 32.00 2 88.29 61.29 150.32 170.64 0.00 1 0.00 1 0 15 3.094e-02 3.060e-02 3.290e-02 3.271e-02 5.361432e+03 2.091740e+03 3.880200e+02 -6.000000e+00 1.697054e+03 283.77 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