File name: Pandora114s1_BuenosAires_20170613_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T005624.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170613_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170613 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170613T110421.0Z 6373.461354 349 1 32.00 2 89.75 61.18 58.26 270.88 0.00 1 0.00 1 0 15 8.716e-02 8.154e-02 8.761e-02 8.540e-02 -1.979152e+03 5.023773e+03 4.241373e+02 -6.000000e+00 4.769847e+03 283.21 -2.00 20.00 -2.00 505.28 0.00e+00 5.714977e-03 2.332671e-03 3.016987e-04 -6.000000e+00 2.421139e-03 283.21 -2.00 20.00 -2.00 499.98 0.00e+00 5.754049e+00 1.715013e+00 7.222724e-02 -6.000000e+00 1.707260e+00 224.17 -2.00 3.16 -2.00 501.62 0.00e+00 20.131 0.076 489.00 513.00 1 9.1048e+00 1.3196e-01 3.2101e-02 -6.0000e+00 1.3074e-01 4.6808e-02 3.3525e-02 1.8942e-03 -6.0000e+00 3.4278e-02 7.3795e-06 9.4001e-03 8.1001e-03 1.2291e-04 -6.0000e+00 8.5905e-03 -3.4886e-02 -7.0990e-06 12 8 8 10 0 0 96.80 20.97 15.03 -0.03489 0.03032 8 2 1 4 0 4000.000 25.17 19.57 20.97 -2689 -5688 -472 2132 -4478 12586 -2049 -2644 873 -1610 -65 5721 4415 -3301 694 -13401 10014 3705 4669 -7683 -5031 9360 -2097 -1433 16334 -1865 10531 -282 2693 1889 853 8367 6888 262 -10649 -2885 714 -5820 1640 10350 -2525 -691 5856 -4901 269 -12979 -159 -99 344 19024 -6449 11782 -5476 11370 -11783 6939 10846 -7781 13652 954 21791 6709 -6132 -1102 3623 6813 -13337 8440 -5635 4274 6345 -3765 -93 -4857 -11471 -10460 5985 4742 -16935 5886 -9506 24355 -6493 4211 2204 1493 98 18363 -1220 -9177 -3221 5488 -5222 23473 -10373 3292 -6933 -5635 -13193 20524 13098 4522 -9603 -4314 6614 -3580 25117 -10807 2673 167 -6345 12580 -8404 2826 -53 2183 15041 -17715 13029 -6336 20710 800 -2069 1591 16792 5883 5615 5614 7107 11420 9190 8258 -4480 -11506 -785 -2197 -2758 -1979 3255 -73 -405 3509 5332 -6028 7345 1654 168 -2399 -1035 -11433 7319 1365 -10247 -2717 -6088 -496 2256 -5194 12567 -2401 -3130 991 -1848 -72 5917 4566 -3651 735 -15330 9879 3722 4742 -8918 -5699 9192 -2317 -1583 15221 -2092 10401 -307 2780 1908 852 7751 6611 278 -12954 -3284 781 -6723 1739 9992 -2775 -752 6045 -5716 302 -16730 -181 -111 379 16986 -7233 10717 -5806 10152 -13479 6777 10471 -9205 13103 1038 19212 6888 -7186 -1230 3842 6919 -16299 8148 -6163 4174 5984 -3887 -92 -5096 -12995 -11790 5677 4472 -18250 5321 -9350 18212 -6217 3635 1949 1335 89 13930 -1123 -9121 -3016 4738 -5081 17437 -10961 3048 -7073 -5601 -13873 15032 10073 3714 -9043 -3904 5501 -3371 17871 -10912 2321 147 -5942 9872 -8309 2558 -50 2067 12668 -20853 11314 -6663 16468 766 -2013 1481 13441 5294 5111 5139 6432 9918 8174 7431 -4570 -11728 -752 -2103 -2640 -1894 3014 -71 -405 3214 4831 -6144 6582 1580 164 -2398 -1009 -12104 6270 1224 -10344 SO 20170613T110826.0Z 6373.464190 353 1 32.00 2 89.01 60.60 59.08 270.32 0.00 1 0.00 1 0 15 6.506e-02 6.169e-02 5.946e-02 5.838e-02 9.333631e+03 4.115301e+03 5.071187e+02 -6.000000e+00 3.560802e+03 283.21 -2.00 20.00 -2.00 505.23 0.00e+00 2.357665e-03 1.588247e-03 1.978568e-04 -6.000000e+00 1.805933e-03 283.21 -2.00 20.00 -2.00 500.08 0.00e+00 1.830188e+00 1.171997e+00 9.588618e-02 -6.000000e+00 1.270817e+00 224.17 -2.00 3.16 -2.00 501.69 0.00e+00 18.694 0.061 489.00 513.00 1 9.2363e+00 8.9662e-02 2.9561e-02 -6.0000e+00 9.7369e-02 8.3744e-02 2.2970e-02 2.4240e-03 -6.0000e+00 2.5434e-02 1.0959e-05 3.2462e-03 5.3635e-03 7.6931e-05 -6.0000e+00 6.4039e-03 -1.1355e-02 6.7439e-05 12 9 8 11 8 0 -5.40 20.97 7.13 -0.01135 0.01116 8 2 1 4 0 4000.000 25.17 20.49 20.97 -1109 2655 5625 5876 -81 5800 -6697 2241 367 3858 16428 -7735 4607 -5501 1520 -239 725 -127 2109 1472 -5147 -6380 -7162 -1313 -3490 15872 1811 -694 -4621 -2256 -4099 -7806 -6544 9777 4351 5635 2823 3222 -88 9902 8611 -5299 -1856 1509 -6723 -1839 -580 586 -234 9130 -3882 -2683 -1344 2081 12280 -8368 -1682 -12070 -1256 65 5666 9641 1288 -2206 4244 3691 -8462 -3709 956 6233 5045 695 12006 -7499 293 -5033 -4534 -41 -1925 2589 34 8144 -7085 -8563 1213 1848 13251 -1189 128 -3654 10529 -2479 -7853 -3079 -9793 101 3104 -1781 -1214 2807 -8557 -1847 16794 901 -3858 -7436 6815 7784 8176 379 -5215 1476 -5120 5156 14602 -2055 7609 4132 6604 1864 3879 -6376 -14627 8645 -8132 1353 -5872 4050 -10541 -4780 12920 -3211 19737 6318 -4325 16302 -700 -3334 1964 2863 -2667 10925 -6194 -1738 2338 -3634 4434 -6008 -2109 7873 -469 9904 -3838 -1102 2604 5540 5956 -89 6164 -8184 2518 418 4194 15510 -8557 4763 -5812 1490 -240 733 -132 2205 1567 -5870 -7374 -8361 -1453 -3968 14895 1948 -757 -5130 -2376 -4300 -8487 -7164 9398 4548 5890 3026 3404 -95 9594 8442 -6004 -2053 1635 -8001 -2097 -653 646 -257 8916 -4205 -2795 -1354 2017 10915 -9417 -1822 -14780 -1389 71 5835 9563 1395 -2483 4468 3872 -9261 -3807 985 6016 4869 651 10717 -7697 282 -5147 -4589 -39 -1831 2324 31 6873 -6993 -8636 1119 1712 11041 -1148 122 -3593 8962 -2411 -8144 -3084 -10541 98 2842 -1662 -1094 2369 -7926 -1579 11952 770 -3601 -7499 6117 6959 7222 358 -5185 1383 -5200 4794 12481 -2087 7047 3990 6283 1873 3815 -6863 -15804 7729 -8020 1292 -5712 3585 -10821 -4634 10480 -3058 14881 5380 -4033 12236 -622 -3075 1751 2582 -2586 9377 -6379 -1725 2242 -3718 4194 -6290 -2101 6970 -442 8301 -3694 SO 20170613T111236.0Z 6373.467083 357 1 32.00 2 88.27 60.00 59.92 269.75 0.00 1 0.00 1 0 15 4.362e-02 4.345e-02 3.973e-02 3.928e-02 6.711967e+03 2.610308e+03 3.309440e+02 -6.000000e+00 2.386904e+03 283.21 -2.00 20.00 -2.00 505.23 0.00e+00 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