File name: Pandora114s1_BuenosAires_20170621_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T005525.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170621_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170621T110640.0Z 6381.462963 434 1 32.00 2 89.77 60.94 58.63 39.61 0.00 1 0.00 1 0 43 9.560e-02 9.226e-02 8.947e-02 8.732e-02 8.879940e+02 5.094227e+03 5.941323e+01 -6.000000e+00 5.226820e+03 282.95 -2.00 20.00 -2.00 505.26 0.00e+00 2.294767e-03 2.365191e-03 8.191261e-05 -6.000000e+00 2.650341e-03 282.95 -2.00 20.00 -2.00 500.05 0.00e+00 2.055823e+00 1.715286e+00 3.542370e-02 -6.000000e+00 1.860892e+00 224.32 -2.00 3.16 -2.00 501.69 0.00e+00 20.164 0.077 489.00 513.00 1 9.4396e+00 1.3176e-01 3.1113e-02 -6.0000e+00 1.4267e-01 1.1783e-01 3.3824e-02 1.7909e-03 -6.0000e+00 3.7092e-02 7.2046e-06 1.8030e-02 8.1376e-03 3.2441e-05 -6.0000e+00 9.3967e-03 -3.3979e-02 4.7057e-04 12 8 8 10 0 0 66.22 20.87 -0.57 -0.03398 0.09108 8 2 1 4 0 4000.000 25.07 19.43 20.87 2247 -7045 -2431 -17135 11792 1114 3658 -1271 -3724 5129 3115 -1593 2521 3918 -8721 3558 -6437 5817 21989 12771 2601 -2975 1131 16403 8206 2167 -3840 -10747 -11749 -6469 -7328 -10735 405 -14706 13042 1860 1249 8429 -6410 1982 11202 10494 11728 5420 9208 -4787 4520 -14638 1740 3523 15731 6168 -10500 -10196 333 5869 -5974 -920 8292 3065 20004 -5702 8409 -10781 8100 -2888 340 5830 -70 21607 6255 8933 -7946 -7195 8699 -6931 -3833 -7751 11023 -2301 -14611 19110 -3104 8465 -9128 2059 14767 -4468 3350 -2798 7802 -5723 26468 -3398 2881 -60 2592 -820 -3234 2933 -15115 1907 13253 7982 9500 -629 -183 -5508 8350 -5387 -4345 -6387 4844 -394 648 -9943 -263 2250 13591 -7677 -2494 -6116 11662 -11986 13878 3547 -133 7970 -2387 14562 3587 5956 3990 -21196 20414 -6671 10970 -15020 -1 -15704 6702 8554 18805 15493 -6154 6834 7011 6760 -557 -23101 21202 -13659 11286 2239 -7969 -2705 -22627 11895 1266 4070 -1477 -4371 5425 3314 -1753 2636 4024 -10236 3764 -7199 6294 20434 13039 2746 -3327 1220 15256 8288 2313 -4294 -12571 -13475 -6903 -7903 -12251 428 -18544 12577 1995 1333 8273 -7242 2058 10675 10179 11376 5659 9300 -5545 4720 -18208 1797 3478 13374 5666 -11383 -11228 340 5827 -6784 -997 8185 3183 17578 -6507 8349 -12919 7950 -3115 349 5588 -70 17261 5782 8054 -8569 -7801 8090 -7474 -3937 -8137 9497 -2258 -15242 15266 -2922 7155 -9277 1883 11928 -4374 3028 -2694 6803 -5786 19680 -3436 2728 -58 2385 -764 -3010 2510 -15282 1632 10351 6789 8182 -605 -174 -5450 7102 -5245 -4231 -6457 4457 -388 638 -10957 -265 2214 11924 -8255 -2508 -6282 9920 -12888 11581 3301 -129 7120 -2362 12152 3339 5384 3629 -22944 15289 -6531 9096 -16471 -1 -16920 6202 7824 15592 13344 -6228 6090 6212 5922 -513 -26053 15158 -13891 9092 SO 20170621T111045.0Z 6381.465799 438 1 32.00 2 89.04 60.36 58.12 38.64 0.00 1 0.00 1 0 22 7.654e-02 7.419e-02 6.389e-02 6.268e-02 -1.965237e+03 3.549385e+03 1.838541e+02 -6.000000e+00 4.186620e+03 282.95 -2.00 20.00 -2.00 505.22 0.00e+00 -2.707221e-04 1.701627e-03 7.939488e-05 -6.000000e+00 2.122170e-03 282.95 -2.00 20.00 -2.00 500.10 0.00e+00 2.547786e+00 1.235406e+00 1.520364e-02 -6.000000e+00 1.488291e+00 224.32 -2.00 3.16 -2.00 501.73 0.00e+00 18.750 0.062 489.00 513.00 1 9.3081e+00 9.4866e-02 2.8374e-02 -6.0000e+00 1.1413e-01 9.1311e-02 2.4562e-02 1.5778e-03 -6.0000e+00 2.9616e-02 1.0161e-05 2.0306e-03 5.9859e-03 3.6167e-05 -6.0000e+00 7.5188e-03 -1.0739e-01 1.0164e-03 12 9 8 11 8 0 90.68 20.86 -4.82 -0.10739 -0.09331 8 2 1 4 0 4000.000 25.07 20.44 20.86 -6702 7462 681 -2095 -473 -6730 4448 -12313 10864 -542 6875 -564 -995 10830 -9763 6303 -11036 8089 -1960 477 11796 -8822 15918 276 9911 478 193 6505 -8065 3988 -9006 10516 1594 1439 3182 -8962 -1200 -8770 3150 6304 -529 -2315 -7538 -1829 -3505 12994 -4459 16454 16009 -12620 9905 -3384 5402 1112 1866 -6269 3693 9637 -9671 -3821 536 9241 -2681 -700 7559 -1565 11242 -2046 -6882 4015 -91 -1525 3926 15175 2611 1011 -6289 -10751 6996 -12438 8357 -7467 7727 -1867 5414 -4429 -4848 8432 -7653 7893 -6734 16875 -3486 -564 5823 -4855 14550 -11071 16458 -5378 -3479 -4166 -6247 8537 -9018 19706 13303 -1108 5781 -9076 13131 -13661 3622 -7689 8989 4310 -3038 11073 -6513 1827 -2732 323 1368 5886 7616 -8331 11238 -9888 6211 -1963 -2019 5114 4513 -547 -2623 1023 878 -8524 7686 -7921 12755 -1122 4124 -41 -5628 -1355 -640 9392 -1085 7185 -10433 -1789 -407 -7118 7074 715 -2326 -529 -8182 4900 -15030 11205 -619 7181 -626 -1096 10505 -10838 6015 -12792 7952 -2176 521 11548 -10624 14997 306 9987 528 213 6635 -9283 3953 -9997 9649 1639 1532 3415 -10939 -1346 -10490 3304 6353 -570 -2551 -8830 -2045 -4020 12668 -5151 15232 14623 -14991 9128 -3466 4978 1070 1819 -6830 3737 9316 -11369 -4225 566 8971 -2944 -754 7462 -1673 10407 -2129 -6950 3832 -90 -1511 3699 12929 2397 948 -6279 -11024 5910 -12657 6900 -7255 6498 -1742 4740 -4320 -4785 7318 -7817 6910 -6853 13673 -3508 -559 5456 -5053 12348 -11947 13209 -5246 -3260 -3888 -5997 7245 -9420 15816 11443 -1089 5217 -9376 10841 -14899 3379 -8179 8216 4171 -3185 10120 -7103 1824 -2822 319 1319 5379 6844 -8310 9839 -10078 5387 -1844 -1897 4473 3947 -496 -2389 887 762 -8225 6445 -7930 10557 -1079 3786 -39 -5757 -1336 -629 8316 -1051 6258 -10596 -1649 -372 SO 20170621T111450.0Z 6381.468634 442 1 32.00 2 88.31 59.77 57.63 37.67 0.00 1 0.00 1 0 15 5.149e-02 5.088e-02 4.750e-02 4.685e-02 5.303634e+03 3.065643e+03 4.978202e+02 -6.000000e+00 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