File name: Pandora114s1_BuenosAires_20170630_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T011755.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170630_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170630T110732.0Z 6390.463565 486 1 32.00 2 89.77 61.32 141.18 140.44 0.00 1 0.00 1 0 22 1.288e-01 1.241e-01 1.046e-01 1.007e-01 -3.940581e+03 5.821341e+03 9.695227e+02 -6.000000e+00 7.035631e+03 282.70 -2.00 20.00 -2.00 505.35 0.00e+00 1.213046e-03 2.773526e-03 4.036556e-05 -6.000000e+00 3.571074e-03 282.70 -2.00 20.00 -2.00 500.10 0.00e+00 6.476386e+00 1.988155e+00 6.461182e-02 -6.000000e+00 2.519801e+00 224.60 -2.00 3.16 -2.00 501.79 0.00e+00 20.167 0.077 489.00 513.00 1 9.2747e+00 1.5372e-01 3.1209e-02 -6.0000e+00 1.9298e-01 1.5141e-02 3.8430e-02 1.7761e-03 -6.0000e+00 5.0480e-02 6.2148e-06 2.1844e-02 9.4331e-03 1.2685e-04 -6.0000e+00 1.2685e-02 2.9421e-02 -2.3950e-04 12 9 8 11 8 0 89.79 20.92 1.97 0.02942 0.18094 8 2 1 4 0 4000.000 25.07 19.89 20.92 -9989 -13361 3338 -26696 13121 6353 21332 18729 -3972 14728 -7197 1117 17544 -7075 9738 10966 -7086 -7058 16505 -7101 3143 -10468 -2654 15667 -8133 4269 6325 6733 8582 -2056 10786 -16783 13403 -1010 2558 -1359 3546 14107 -15022 19477 -13189 25404 -471 -4638 8371 -6120 10290 -19309 11135 -10440 780 9803 -8182 16886 -6282 19345 -708 22979 29090 2288 12239 -8660 9917 2979 11164 272 -5224 6926 -14635 31372 4654 3869 -2100 -4763 4481 -12709 4799 -7807 24798 -24156 17674 -6727 -9951 2620 -10455 15910 2900 -4972 1688 -14458 18106 -10296 3885 -3298 21642 7185 4706 937 -20716 27251 -10699 8698 -3272 6430 11006 -3858 10123 -11350 591 22274 2432 32112 -7798 18682 752 12491 6965 2023 2962 -8831 -2428 -11300 22512 11205 -5175 23380 -838 12061 -34981 8855 602 7010 2791 19797 9490 -4987 2982 -744 8858 13625 -13175 -8557 -71 2391 -7484 21691 651 -10184 -5707 -15562 21722 -6449 22827 -10915 -15636 3412 -37829 12765 6719 19551 17562 -4621 14017 -8423 1189 15708 -8081 9474 10746 -8543 -8708 16290 -8317 3330 -12742 -3004 14845 -9793 4523 6492 6734 8188 -2137 9865 -20651 12611 -1129 2794 -1538 3780 13367 -18880 17302 -16316 21563 -524 -5432 8648 -7288 10291 -25538 10624 -12022 780 8773 -8721 14222 -6861 16803 -764 19657 23352 2393 11597 -10143 9658 3097 10579 283 -5637 6517 -16853 22501 4318 3615 -2101 -4951 4276 -14300 4453 -8065 18275 -27121 13956 -6817 -9822 2448 -10513 13191 2576 -4784 1521 -15341 13961 -10671 3547 -3275 16822 6427 4268 867 -23258 18492 -10428 6975 -3008 5514 9234 -3784 8556 -11693 532 16076 2161 21592 -7985 14982 733 10942 6488 1984 2869 -9533 -2427 -12199 17220 9608 -5267 18029 -827 10491 -48769 7975 590 6443 2651 15632 8196 -4953 2760 -729 8087 12103 -15524 -9712 -75 2464 -8082 18733 653 -11294 -5931 -17438 16522 -6515 17494 SO 20170630T111143.0Z 6390.466470 490 1 31.99 2 89.02 60.72 140.64 139.11 0.00 1 0.00 1 0 22 7.461e-02 7.120e-02 7.143e-02 6.993e-02 1.074884e+04 4.940729e+03 8.721403e+02 -6.000000e+00 4.074331e+03 282.70 -2.00 20.00 -2.00 505.23 0.00e+00 2.282854e-03 1.885215e-03 1.797344e-04 -6.000000e+00 2.067604e-03 282.70 -2.00 20.00 -2.00 500.09 0.00e+00 -2.284086e-01 1.404524e+00 3.426387e-02 -6.000000e+00 1.457594e+00 224.60 -2.00 3.16 -2.00 501.69 0.00e+00 18.703 0.061 489.00 513.00 1 9.5706e+00 1.0709e-01 2.8683e-02 -6.0000e+00 1.1166e-01 1.2758e-01 2.7815e-02 1.8884e-03 -6.0000e+00 2.9163e-02 9.0952e-06 3.6081e-03 6.4025e-03 1.1277e-04 -6.0000e+00 7.3386e-03 4.4560e-02 -2.4401e-04 12 8 8 10 0 0 74.97 20.92 6.09 0.04456 0.06959 8 2 1 4 0 4000.000 25.07 19.56 20.92 -3253 3781 6125 566 2985 14006 5836 -7296 7907 -1930 -4372 5782 6344 2424 2924 -2873 -3724 -8770 -5877 515 -10973 11577 7098 6192 -2332 1927 -9886 -4424 3990 -781 -1925 -4066 -7484 -9810 21481 3967 8902 311 -5008 4092 514 -158 10390 7520 -3262 -2287 -3247 -10391 -394 -2075 3216 11168 1950 -575 -4168 4289 429 2202 -5106 7171 -4035 8298 -2792 -4875 -2684 -2794 -1336 2273 -4691 -4998 -3964 17528 -3191 11470 -315 -1739 -4931 -13147 10977 17226 1015 -1697 13548 5698 -11865 8779 -3657 -7977 -4834 11251 4735 7532 -6911 15818 -3252 2899 4006 7165 -12383 2679 -7060 3154 -2840 15774 4646 -9495 -2295 -5977 9228 -8740 11697 -1109 6174 1157 -1869 -191 4942 806 -3986 -13555 8434 2651 5548 -8708 13723 1447 9973 -9408 -12043 2885 -7201 9934 -2575 16490 85 9109 -3323 -9949 3295 -6205 9969 -15 -2360 5634 -10591 15309 3014 10580 -4097 7422 318 -4920 4577 -3329 3702 6057 610 3215 13784 6315 -9038 8362 -2221 -5073 5973 6430 2528 2819 -2955 -3931 -9979 -6634 550 -13188 11110 7136 6311 -2600 2060 -11837 -4953 4011 -799 -1953 -4218 -8208 -11386 18749 4170 8869 334 -5607 4151 540 -168 10066 7595 -3712 -2592 -3709 -12631 -426 -2238 3204 10003 1881 -567 -4343 4233 453 2324 -5834 7242 -4555 8305 -3138 -5614 -3018 -3116 -1447 2337 -5102 -5390 -4185 14819 -3117 10431 -306 -1728 -5028 -14306 9217 13432 926 -1592 10970 5029 -12607 7672 -3650 -8339 -4887 9641 4321 6712 -7195 13283 -3316 2745 3656 6140 -12520 2273 -6472 2581 -2482 11759 4041 -9926 -2290 -6222 8184 -9174 9972 -1083 5687 1135 -1905 -192 4743 811 -4252 -16028 7985 2623 5230 -9289 11582 1382 8801 -9522 -12529 2582 -7114 8251 -2408 12567 75 7272 -3001 -9708 2870 -6054 8401 -14 -2303 5111 -11359 12716 2831 9172 -4064 6434 290 -4662 3949 SO 20170630T111548.0Z 6390.469306 494 1 32.00 2 88.28 60.13 140.10 137.83 0.00 1 0.00 1 0 15 4.603e-02 4.485e-02 4.837e-02 4.787e-02 1.252476e+04 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