File name: Pandora114s1_BuenosAires_20170711_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T011903.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170711_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170711T110546.0Z 6401.462338 362 1 31.99 2 89.75 62.69 74.25 262.36 0.00 1 0.00 1 0 22 1.019e-01 9.977e-02 1.106e-01 1.074e-01 3.955624e+03 6.973349e+03 9.298760e+02 -6.000000e+00 5.563571e+03 282.40 -2.00 20.00 -2.00 505.29 0.00e+00 4.227322e-03 2.898834e-03 2.087713e-04 -6.000000e+00 2.820763e-03 282.40 -2.00 20.00 -2.00 500.07 0.00e+00 2.952372e+00 2.159334e+00 8.015125e-02 -6.000000e+00 1.977653e+00 224.94 -2.00 3.16 -2.00 501.70 0.00e+00 20.136 0.076 489.00 513.00 1 9.5528e+00 1.6497e-01 3.1729e-02 -6.0000e+00 1.5169e-01 9.8721e-02 4.2580e-02 1.7694e-03 -6.0000e+00 3.9236e-02 5.8369e-06 -6.3832e-03 1.0021e-02 1.2113e-04 -6.0000e+00 9.9906e-03 -4.4597e-02 8.2617e-04 12 8 8 10 0 0 -456.69 20.56 10.90 -0.04460 -0.08887 8 2 1 4 0 4000.000 24.75 20.27 20.56 5429 5702 -1951 -2302 10877 2226 -10281 7424 12571 -7711 2353 -8977 -1170 8610 -16134 12610 4501 6187 6134 12875 -14583 3269 -7295 -4919 8083 4874 1804 3929 16114 -2078 -8143 -14382 1326 6051 12428 5109 729 283 8676 403 9449 -8296 -3414 -11015 13217 4880 -7630 16376 20955 -11723 5609 -12312 15605 5168 1821 -19626 -8150 -15710 29301 -10794 3321 15573 -1216 6890 558 11839 1190 -5082 4896 -4642 9707 -16 11152 -4610 664 -6129 -20767 718 -11870 5836 7683 10109 23399 -1820 2448 -4583 9800 3845 -712 10834 -4004 -2107 505 -4836 6375 11910 19211 6492 7881 -7975 -5260 -15856 14412 -1588 -8901 -9762 4866 909 -6570 -17947 14571 2324 -193 1628 1702 -10899 10642 12075 -2591 206 16079 1512 5537 26 -3749 3012 -10229 19600 3673 -1843 24020 3631 15195 -6338 -22543 -7167 5401 23783 -1004 5204 10467 -249 -21349 3779 -9073 2098 24487 1312 8955 -5373 -2380 6985 2284 5104 5490 -2098 -2563 10881 2478 -13146 7985 12764 -9454 2566 -10803 -1284 8483 -20265 11950 4706 6515 6597 13073 -18222 3419 -8501 -5628 8170 5098 1937 4083 14479 -2174 -8861 -16658 1341 6032 11952 5344 793 306 8527 427 9154 -9667 -3834 -13531 12897 5207 -9212 15405 18535 -14072 5513 -14088 13255 4861 1803 -24800 -9440 -19961 23860 -13108 3497 14540 -1349 7061 607 11386 1253 -5601 4812 -4953 8859 -16 9942 -4855 671 -6669 -25949 711 -13082 5326 6850 8799 17904 -1689 2191 -4434 8256 3442 -665 8984 -3847 -1997 472 -4838 5748 10111 14918 5597 6535 -7558 -4743 -15652 10528 -1390 -8670 -9894 4323 837 -6442 -19489 11411 2080 -181 1521 1613 -11835 9385 10569 -2643 205 13545 1453 5029 25 -3676 2775 -10839 15479 3408 -1808 18179 3370 12500 -6382 -26259 -7075 4692 17374 -958 4760 9230 -247 -24861 3656 -9442 1962 19500 1235 7710 -5225 -2197 5797 1995 SO 20170711T110950.0Z 6401.465162 366 1 31.99 2 89.00 62.11 75.06 261.84 0.00 1 0.00 1 0 22 3.455e-02 3.383e-02 3.059e-02 3.042e-02 7.266806e+03 2.000249e+03 5.771552e+02 -6.000000e+00 1.884954e+03 282.40 -2.00 20.00 -2.00 505.39 0.00e+00 6.519897e-03 8.378988e-04 3.216327e-04 -6.000000e+00 9.567648e-04 282.40 -2.00 20.00 -2.00 500.71 0.00e+00 1.596692e+00 5.946528e-01 5.766582e-02 -6.000000e+00 6.755332e-01 224.94 -2.00 3.16 -2.00 502.28 0.00e+00 18.677 0.061 489.00 513.00 1 8.5236e+00 4.5745e-02 2.9647e-02 -6.0000e+00 5.1740e-02 3.0123e-02 1.1459e-02 1.8912e-03 -6.0000e+00 1.3517e-02 2.1689e-05 2.9042e-03 2.8949e-03 1.3233e-04 -6.0000e+00 3.3986e-03 1.4093e-02 -6.7854e-05 12 8 8 10 0 0 15.81 20.56 6.61 0.01409 0.03424 8 2 1 4 0 4000.000 24.75 19.31 20.56 2221 -5899 -2538 -761 2265 -4356 -2750 1786 -954 4240 -3248 -4911 -4245 59 31 -2951 560 -1923 -1195 -918 5315 2033 1225 -1312 -2715 1147 -3921 6492 -2413 -2212 -1538 3665 -458 -4399 5978 -620 4507 3017 -618 7409 -5607 5898 1564 -1015 -2001 -180 2342 -3140 2956 1650 -948 989 -535 4587 -806 11864 2327 2475 1296 -3842 1862 1206 -783 1073 2397 2113 -163 267 -4666 721 -2838 1814 -2691 -1025 1404 -4907 -2765 624 -1106 8158 -778 1399 623 1980 -5236 4935 -1541 3769 422 -1200 5580 -153 1931 -1397 3347 2044 514 2275 651 4071 -2386 -1535 -2781 -3400 12241 -7976 -1212 -2779 4415 2494 -1350 1959 -2325 1657 -322 1678 -1988 1989 381 -674 778 -5231 1432 2877 2856 4442 -2450 654 -5696 6830 -3637 -1708 1061 -5895 -290 -1246 1950 -7545 2597 -2212 2829 2105 -3177 903 2271 279 -1244 429 5391 -790 90 -8343 1982 1885 -5582 -2407 -732 2171 -4555 -2870 1790 -977 4063 -3299 -4999 -4236 56 29 -2880 537 -1934 -1218 -943 5146 2037 1242 -1375 -2909 1188 -4263 6298 -2504 -2226 -1504 3402 -452 -4678 5907 -663 4570 3077 -647 7128 -6164 5839 1642 -1043 -2107 -188 2388 -3359 2937 1630 -939 936 -505 4112 -777 10392 2312 2505 1338 -4181 1915 1254 -836 1130 2489 2182 -170 273 -4940 715 -2883 1744 -2708 -1024 1387 -5203 -2855 613 -1086 7222 -750 1319 595 1875 -5368 4608 -1546 3589 414 -1192 5169 -151 1889 -1437 3319 2046 514 2179 618 3642 -2228 -1399 -2566 -3219 10266 -7989 -1159 -2706 3965 2262 -1272 1807 -2284 1596 -321 1660 -2058 1996 392 -706 801 -5652 1424 2781 2745 4223 -2518 657 -6114 6481 -3834 -1767 1065 -6266 -287 -1231 1860 -7994 2533 -2309 2853 2167 -3483 956 2386 300 -1364 461 5457 -834 93 -9176 1971 SO 20170711T111358.0Z 6401.468032 370 1 32.00 2 88.25 61.52 75.88 261.31 0.00 1 0.00 1 0 15 1.296e-02 1.292e-02 1.275e-02 1.270e-02 9.558620e+03 8.604837e+02 6.514630e+02 -6.000000e+00 7.069829e+02 282.40 -2.00 20.00 -2.00 505.37 0.00e+00 7.199117e-03 3.465812e-04 3.924897e-04 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