File name: Pandora114s1_BuenosAires_20170718_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T011847.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170718_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170718T110244.0Z 6408.460231 386 1 32.00 2 89.76 64.10 47.50 4.09 0.00 1 0.00 1 0 67 7.555e-02 7.320e-02 8.015e-02 7.823e-02 -2.683567e+03 4.685381e+03 1.918841e+02 -6.000000e+00 4.120020e+03 282.26 -2.00 20.00 -2.00 505.29 0.00e+00 4.720446e-03 2.131939e-03 3.164281e-04 -6.000000e+00 2.091875e-03 282.26 -2.00 20.00 -2.00 499.95 0.00e+00 5.524664e+00 1.593534e+00 1.249047e-01 -6.000000e+00 1.479012e+00 225.19 -2.00 3.16 -2.00 501.60 0.00e+00 20.162 0.077 489.00 513.00 1 9.0458e+00 1.2207e-01 3.3122e-02 -6.0000e+00 1.1325e-01 6.0399e-02 3.1442e-02 2.4499e-03 -6.0000e+00 2.9619e-02 8.0677e-06 4.7185e-03 7.3546e-03 1.1606e-04 -6.0000e+00 7.4397e-03 -1.2778e-02 3.8758e-05 12 8 8 10 0 0 52.09 20.23 4.73 -0.01278 0.01995 8 2 1 4 0 4000.000 24.46 19.44 20.23 10406 -1730 1750 1782 -5888 2407 4315 1379 6742 -6143 -7752 10210 5653 4624 2069 6347 2269 -8671 -571 -4147 11735 5681 5956 6057 -1808 5537 423 -20468 -7507 5366 -1913 -4458 6107 -1553 8646 1535 -8635 4850 1268 -4155 6947 -1609 -894 1394 -4176 -2679 9855 -12608 10879 -3442 3493 -3730 4418 -716 319 -1291 -6015 18350 -5562 5496 -2827 531 -524 -8849 1580 -4171 -7160 -1033 -7830 12262 14341 23218 1366 23733 -12399 1655 -8438 -3950 5817 2375 -3472 23947 -4632 1574 -2253 -3295 4005 6894 3978 -9601 -7622 -4070 -8253 5601 5383 5352 7034 8565 -2822 12385 645 875 8003 -10411 -1774 -11045 6539 -1941 104 -3424 12221 3929 2103 -1350 -4166 -541 -1863 10577 -12772 1204 1251 7129 7496 6204 -1098 -5278 -16228 -2973 -8352 -1580 9936 12930 -5303 -5878 5112 4184 11420 -4525 7777 -11689 -130 -1274 4835 4734 8269 7940 2093 1567 -7322 2185 2244 13120 -4536 9290 -1791 1812 1903 -6966 2677 4773 1579 7275 -7435 -9383 10177 5820 4761 2175 6431 2436 -9929 -616 -4685 11337 5837 6120 6254 -2033 5803 465 -27413 -8634 5266 -1975 -4718 5931 -1683 8706 1679 -10417 5058 1355 -4651 6961 -1768 -987 1524 -4889 -3108 10075 -15984 10733 -3836 3536 -3947 4223 -718 321 -1359 -6826 16603 -6425 5675 -3165 576 -576 -10585 1696 -4690 -8162 -1088 -8686 10969 12390 18159 1327 18562 -14070 1641 -9187 -4038 5293 2209 -3195 17873 -4328 1388 -2073 -3079 3493 5848 3470 -9571 -7452 -3862 -8266 4965 4850 4848 6237 7389 -2678 9853 563 746 6329 -10029 -1607 -11222 5609 -1795 92 -3117 9488 3352 1865 -1268 -4113 -524 -1849 9327 -14261 1166 1199 6355 6574 5470 -1042 -5261 -18198 -2935 -8726 -1545 8666 10968 -5388 -5943 4557 3710 9358 -4381 6783 -11916 -128 -1207 4611 4270 7235 7020 1973 1485 -7497 1991 1994 10297 -4256 SO 20170718T110649.0Z 6408.463067 390 1 32.00 2 89.01 63.51 47.46 2.77 0.00 1 0.00 1 0 22 6.621e-02 6.654e-02 5.797e-02 5.692e-02 3.326458e+03 3.572777e+03 2.202221e+02 -6.000000e+00 3.609989e+03 282.26 -2.00 20.00 -2.00 505.18 0.00e+00 5.123118e-04 1.543092e-03 6.003089e-05 -6.000000e+00 1.832604e-03 282.26 -2.00 20.00 -2.00 500.05 0.00e+00 3.781904e-01 1.134559e+00 2.504639e-02 -6.000000e+00 1.294569e+00 225.19 -2.00 3.16 -2.00 501.67 0.00e+00 18.690 0.061 489.00 513.00 1 9.3528e+00 8.6818e-02 2.8293e-02 -6.0000e+00 9.9150e-02 1.3836e-01 2.2570e-02 1.6371e-03 -6.0000e+00 2.5897e-02 1.1280e-05 4.7605e-03 5.3202e-03 3.2308e-05 -6.0000e+00 6.5114e-03 5.7062e-02 -3.0684e-04 12 8 8 10 0 0 -538.65 20.21 6.54 0.05706 0.09008 8 2 1 4 0 4000.000 24.46 19.87 20.21 -746 -6261 -7189 2072 18145 -2721 5109 -3098 4461 616 -5661 -940 -1198 2154 -10419 392 1244 4500 12529 -5736 9123 6256 6390 10021 -477 8069 -1213 -19043 -5379 3196 2072 -5198 616 -6909 4787 3211 5083 108 -4456 2900 -3455 6132 -2684 10050 -3227 7357 4874 -8751 7118 -8253 3215 5049 2444 3519 -7792 11613 -1387 7363 -7363 -2953 3103 -10582 6685 -4184 178 -4229 3295 7698 -1437 4806 -1190 -373 -3388 3682 -5427 -4071 -217 -491 9908 -2806 3003 1741 -2471 584 1182 7623 -4155 3846 -2638 1569 10953 -7442 8056 -12034 1468 -6687 9129 12483 -11114 2414 -7562 10800 -221 10892 -8220 -11804 13266 -6998 8088 7914 8672 -1785 -10445 73 -5900 1223 -2380 11709 297 2407 254 -4968 9376 -8753 9404 2471 2219 4607 -3337 9293 -4158 8479 5547 5274 -2079 5421 3155 -10016 8062 -1607 -2822 808 -10078 8271 -921 5885 -5581 9375 -2670 -9160 5080 -6173 3452 -764 -6961 -8337 2254 17210 -3242 5701 -3514 4662 660 -6359 -993 -1252 2155 -11781 401 1287 4619 12116 -6720 9230 6516 6654 10101 -535 8314 -1363 -25215 -6062 3210 2065 -5588 639 -7992 5056 3476 5370 119 -5055 3031 -3842 6227 -3005 10018 -3708 7635 5166 -10513 7175 -9485 3205 4807 2345 3338 -8433 10669 -1491 7367 -8572 -3284 3243 -11918 6788 -4449 180 -4438 3160 7416 -1403 4357 -1133 -350 -3284 3364 -5507 -4102 -209 -466 8326 -2652 2670 1572 -2344 542 1100 6725 -4158 3567 -2612 1488 9472 -7785 7303 -13512 1448 -7112 8149 10534 -11588 2146 -7278 8548 -197 8887 -8427 -12965 11518 -7419 7276 7037 7620 -1755 -11364 73 -6296 1224 -2482 10657 305 2418 259 -5249 8435 -8762 8296 2205 1995 4052 -3176 7777 -3971 7123 4770 4483 -1870 4466 2650 -9697 6641 -1488 -2686 751 -10518 7221 -886 5311 -5659 8153 -2585 -9259 4351 -5835 2968 SO 20170718T111438.7Z 6408.468503 398 1 33.38 2 87.57 62.38 47.44 0.23 0.00 1 0.00 1 0 15 5.037e-03 4.995e-03 1.861e-04 1.858e-04 4.849325e+03 1.142882e+01 3.367509e+02 -6.000000e+00 2.746528e+02 282.26 -2.00 20.00 -2.00 505.35 0.00e+00 3.801021e-03 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