File name: Pandora114s1_BuenosAires_20170719_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T011830.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170719_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170719T110212.0Z 6409.459861 406 1 32.00 2 89.76 64.33 53.32 20.34 0.00 1 0.00 1 0 15 8.704e-02 8.171e-02 8.547e-02 8.340e-02 4.111449e+03 5.379710e+03 2.360602e+02 -6.000000e+00 4.747068e+03 282.25 -2.00 20.00 -2.00 505.28 0.00e+00 -2.540628e-03 2.236187e-03 1.904960e-04 -6.000000e+00 2.410914e-03 282.25 -2.00 20.00 -2.00 499.96 0.00e+00 2.417644e+00 1.662797e+00 5.023887e-02 -6.000000e+00 1.705950e+00 225.24 -2.00 3.16 -2.00 501.63 0.00e+00 20.164 0.077 489.00 513.00 1 9.4301e+00 1.2653e-01 3.1477e-02 -6.0000e+00 1.3060e-01 1.0302e-01 3.2983e-02 1.9145e-03 -6.0000e+00 3.4201e-02 7.5571e-06 -1.1453e-03 7.7907e-03 6.8967e-05 -6.0000e+00 8.5760e-03 -4.2533e-02 1.4245e-04 12 8 8 10 0 0 94.77 20.63 7.15 -0.04253 -0.05048 8 2 1 4 0 4000.000 24.86 19.78 20.63 -1443 -332 -2379 -3478 -2832 -6 -152 -10110 8062 -7372 12850 3150 -6343 5762 -6646 -1843 1167 10275 -4293 3528 1262 -5229 -6978 -3551 5076 6733 8451 -14613 5357 6982 4 3258 -481 -5636 28538 -1269 -1949 4560 11214 4580 9722 9014 -7312 4860 -14552 11720 -4129 1418 -1530 4211 2168 2459 -8202 -8592 4634 1854 -101 -485 -3522 2101 706 -1510 -11897 3211 13248 1996 13677 -10049 14152 -8947 13579 -3858 1938 9119 -3791 -1997 4787 20281 -5029 -3887 -3537 -10063 858 -594 2095 990 6738 -915 5581 1152 585 14949 -9709 12484 12115 2806 5792 -12684 16285 -4901 10896 -9298 -2214 10073 -14184 17130 -2331 312 -884 -14158 -6611 -12168 4308 -8054 19871 14379 8950 12250 -7713 16939 3288 5532 -4964 3371 10276 -9896 -7453 745 15973 -10000 -1618 -10830 1309 -5342 -6315 22268 -5781 19307 -868 -7451 13833 3504 4763 -10686 17737 -5548 -1612 -979 -4459 2008 -1157 -7084 -626 -1441 -334 -2515 -3838 -3191 -7 -173 -12928 8615 -9126 12830 3422 -7482 5955 -7723 -2044 1189 10499 -4867 3769 1390 -6156 -8366 -4121 5421 7081 8705 -18795 5547 6925 4 3231 -501 -6358 23640 -1445 -2241 4871 11062 4767 9537 8892 -8527 5059 -18558 11560 -4770 1537 -1685 4291 2198 2412 -8716 -9037 4293 1808 -103 -510 -3858 2176 739 -1613 -14135 3290 12274 2056 12373 -11336 12340 -9703 11619 -3890 1838 8100 -3884 -2035 4565 16358 -4805 -3615 -3253 -9872 758 -537 1862 900 5852 -865 4961 1071 547 12144 -10169 10588 10399 2637 5208 -13414 12564 -4557 8462 -8694 -1923 7874 -14639 13478 -2299 302 -862 -15552 -6654 -12931 3918 -8395 15838 12195 8048 10702 -8276 14280 3175 5173 -5072 3117 8768 -10314 -7616 704 12975 -10525 -1562 -10780 1224 -5295 -6227 16269 -5553 14501 -811 -7614 11661 3330 4260 -11253 15043 -5629 -1581 -956 -4481 1864 -1085 -6915 -569 SO 20170719T110617.0Z 6409.462697 410 1 32.00 2 89.01 63.74 53.05 19.20 0.00 1 0.00 1 0 15 5.953e-02 5.930e-02 5.887e-02 5.798e-02 6.241341e+03 3.866439e+03 3.909308e+02 -6.000000e+00 3.245764e+03 282.25 -2.00 20.00 -2.00 505.26 0.00e+00 -7.366984e-04 1.572682e-03 9.536776e-05 -6.000000e+00 1.647681e-03 282.25 -2.00 20.00 -2.00 500.10 0.00e+00 1.199362e+00 1.158164e+00 5.900139e-02 -6.000000e+00 1.163982e+00 225.24 -2.00 3.16 -2.00 501.74 0.00e+00 18.689 0.061 489.00 513.00 1 9.3273e+00 8.8513e-02 2.8673e-02 -6.0000e+00 8.9150e-02 1.0050e-01 2.2960e-02 1.9756e-03 -6.0000e+00 2.3282e-02 1.1042e-05 -5.9550e-03 5.4192e-03 4.5204e-05 -6.0000e+00 5.8545e-03 3.6187e-02 -1.7358e-04 12 8 8 10 0 0 -246.81 20.62 1.18 0.03619 -0.00512 8 2 1 4 0 4000.000 24.86 19.55 20.62 667 -5623 5049 -2326 8166 -2406 -546 -2287 2777 3038 -7434 7894 -8429 3480 -5442 6807 -1464 -4438 2063 -5116 2744 5787 -3520 1138 -1211 -5299 -3967 9701 -10679 114 7664 5004 -396 -8333 13472 7139 5268 1265 715 -4214 -5200 -3488 2732 508 -1879 8794 11919 -1373 -1357 -7278 4782 -2941 -4763 6378 -2120 -801 5664 10753 2386 4685 9767 2555 -2410 -3385 2988 -10495 3742 -61 -3728 5919 -627 7829 -6723 4502 -3632 6349 -11814 -7615 11274 -3089 376 -12592 324 3085 -10405 901 -1343 8288 -3208 -1815 5593 6619 9793 3943 -4147 -832 4631 10171 -3930 7364 -3024 -683 -2688 -6128 4490 5949 3466 -5240 -1553 -3209 1152 1504 2506 -5778 -1187 9517 -5875 1439 -9626 -2728 13006 10551 12865 1858 2413 2145 -354 -8257 -8447 7771 -4965 2807 -3587 2109 5183 642 1469 5049 -3579 -4248 -548 1384 -5959 3499 997 6590 -16579 724 -5226 1383 8855 548 9746 650 -5935 4940 -2531 8221 -2754 -625 -2692 3112 3367 -8421 8108 -9389 3402 -5773 6396 -1515 -4843 2166 -5874 2932 6008 -4014 1242 -1358 -6204 -4570 9667 -12827 120 7259 4816 -407 -9535 12812 7385 5569 1380 775 -4742 -5872 -3873 2867 550 -2107 8930 11742 -1535 -1496 -8356 4747 -3064 -4927 5824 -2121 -810 5536 10227 2495 4793 9474 2662 -2648 -3535 3124 -11705 3814 -63 -3721 5651 -593 7179 -6663 4014 -3561 5706 -12758 -7791 9371 -2919 340 -12972 294 2750 -10719 838 -1293 7301 -3179 -1773 5066 5948 8592 3712 -4271 -827 4294 8707 -3769 6147 -2739 -594 -2378 -5703 3891 5304 3275 -5472 -1556 -3226 1097 1427 2377 -6034 -1198 8688 -6282 1436 -10805 -2878 11735 9670 11333 1795 2288 2034 -325 -8254 -8472 6625 -4797 2506 -3406 1875 4402 563 1267 4220 -3314 -4048 -513 1291 -6056 3264 960 6036 -19233 707 -5381 1313 7638 504 8113 SO 20170719T111022.0Z 6409.465532 414 1 32.00 2 88.26 63.16 52.80 18.04 0.00 1 0.00 1 0 15 9.052e-03 8.981e-03 4.901e-03 4.882e-03 6.184044e+03 3.123788e+02 4.037061e+02 -6.000000e+00 4.936731e+02 282.25 -2.00 20.00 -2.00 505.42 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