File name: Pandora114s1_BuenosAires_20170720_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T011843.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170720_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170720T110140.0Z 6410.459491 426 1 32.00 2 89.76 64.56 61.09 34.27 0.00 1 0.00 1 0 15 1.223e-01 1.119e-01 9.830e-02 9.480e-02 5.666039e+03 6.262230e+03 5.228209e+02 -6.000000e+00 6.670611e+03 282.24 -2.00 20.00 -2.00 505.25 0.00e+00 2.089310e-04 2.550165e-03 2.903506e-05 -6.000000e+00 3.384608e-03 282.24 -2.00 20.00 -2.00 500.10 0.00e+00 9.788527e-01 1.889275e+00 1.861478e-02 -6.000000e+00 2.384677e+00 225.28 -2.00 3.16 -2.00 501.71 0.00e+00 20.158 0.077 489.00 513.00 1 9.6197e+00 1.4448e-01 3.0983e-02 -6.0000e+00 1.8275e-01 1.2828e-01 3.7105e-02 1.8339e-03 -6.0000e+00 4.7540e-02 6.6165e-06 1.7875e-03 8.7481e-03 6.3416e-05 -6.0000e+00 1.2021e-02 3.9625e-02 2.0394e-05 12 9 8 11 8 0 84.74 20.73 -0.11 0.03962 0.05202 8 2 1 4 0 4000.000 24.96 20.43 20.73 -13013 14183 -7472 21111 8812 -8640 -12091 -434 2995 4042 4415 7489 -64 9267 -9416 5997 -15030 10647 -2922 -4775 26191 -93 3535 -5017 14081 -11532 19963 -4746 -11003 -6254 6726 29188 -4430 84 8546 -6047 3865 -10968 15916 11805 7232 2878 -3614 -5763 647 20209 -2259 -641 11547 -14878 10409 -11878 26950 -12400 6757 4593 2273 8042 -7851 2668 -7650 -2420 -11669 1052 2407 -1603 2157 -1825 9444 -6080 22364 9307 3649 1022 -16371 9370 -11415 -14314 5626 3331 27711 -13671 17469 -921 5899 11741 -1665 8809 -10007 9246 4755 4117 22504 5177 1748 -14445 14800 -13347 22403 9334 -5482 1551 -12200 -2499 -16454 13748 2417 391 2821 -7322 -9853 -14393 11317 -12208 20489 -7561 7393 24230 -13653 18715 359 13752 15377 -7830 14822 -439 19276 -18850 16598 4384 -9867 22628 3966 32545 -9886 25747 -4416 15472 2008 -4412 24052 -14995 460 -11988 11397 -1329 -15808 25976 -6348 -5708 -8397 6723 796 -14769 12614 -8530 18636 9007 -10724 -15729 -504 3339 4400 4718 7655 -69 9102 -11124 6129 -18063 10883 -3258 -5472 23642 -102 3744 -5811 13520 -14288 17931 -5381 -12950 -6819 6333 22059 -4803 90 8629 -7117 4095 -13317 14592 11189 7168 2995 -4052 -6676 709 18277 -2547 -702 11015 -18064 9543 -13245 20034 -13673 6279 4496 2337 7921 -9094 2776 -8814 -2654 -14096 1121 2520 -1728 2205 -1910 8717 -6479 17733 8360 3481 1013 -19573 8706 -12940 -16404 5193 3116 20256 -14211 14284 -856 5173 9819 -1605 7673 -10519 8001 4308 3778 17382 4811 1686 -16191 12119 -14107 16133 7481 -4998 1306 -11903 -2279 -17965 11498 2302 379 2637 -7484 -10300 -15881 9793 -13541 16540 -8124 6869 19138 -15857 15759 361 11900 12859 -8139 12223 -423 15336 -22004 13591 4048 -10486 17347 3640 22113 -10105 18242 -4231 12310 1866 -4458 18578 -16310 460 -12843 10325 -1293 -17799 20366 -6384 -5585 -8261 5622 709 SO 20170720T110544.0Z 6410.462315 430 1 31.99 2 89.01 63.98 60.64 33.32 0.00 1 0.00 1 0 22 7.364e-02 6.955e-02 6.870e-02 6.739e-02 2.874639e+03 4.273672e+03 3.484667e+02 -6.000000e+00 4.015144e+03 282.24 -2.00 20.00 -2.00 505.27 0.00e+00 8.803770e-04 1.825453e-03 5.987869e-05 -6.000000e+00 2.037702e-03 282.24 -2.00 20.00 -2.00 500.17 0.00e+00 1.871203e+00 1.348336e+00 1.260382e-02 -6.000000e+00 1.437510e+00 225.28 -2.00 3.16 -2.00 501.78 0.00e+00 18.684 0.061 489.00 513.00 1 9.4139e+00 1.0293e-01 2.8225e-02 -6.0000e+00 1.1013e-01 8.6505e-02 2.6607e-02 1.5477e-03 -6.0000e+00 2.8701e-02 9.4559e-06 -5.5615e-04 6.3908e-03 4.7030e-05 -6.0000e+00 7.2418e-03 3.2960e-02 -3.4597e-05 12 8 8 10 0 0 44.63 20.74 5.73 0.03296 0.02910 8 2 1 4 0 4000.000 24.96 19.43 20.74 6437 20426 -8118 -2493 -1682 -4531 -3843 -6010 2545 -4470 -583 10197 10851 -9611 -5517 -2769 -1387 11997 -3560 -1968 8010 6369 4829 5674 -84 7 -13617 -2404 -551 8888 -13193 1640 -3667 6080 3812 -7573 11674 750 11214 -6134 8293 5629 227 3460 3279 6741 1177 -4125 -5306 1914 -9715 -6080 -1247 566 6797 -6498 -2431 1864 1632 1940 3015 3189 -2928 -3442 1999 10232 -4069 -5293 8989 514 8533 -4483 2644 9271 -5380 11014 -3404 13263 992 -150 8941 -6499 -7993 5657 580 703 -7729 3342 -4328 14213 -9221 7613 -3092 5117 -2538 -10 9108 -8084 17508 -2321 4359 12619 -1088 -6936 6538 -6578 -5138 -3585 2365 -4100 15012 1182 10395 -6839 2635 -2215 -4741 2655 1176 6808 -5495 20657 -11473 223 1372 -13759 10377 -5158 -8194 573 -11066 -1272 7424 3996 -4056 10846 707 8011 -6138 9291 -2650 -4059 13783 -4070 4473 5897 -8118 22420 -6425 8189 -3341 -4453 -6808 5893 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