File name: Pandora114s1_BuenosAires_20170728_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T011858.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170728_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170728T105620.0Z 6418.455787 467 1 31.99 2 89.76 66.69 128.85 123.83 0.00 1 0.00 1 0 80 1.738e-01 1.513e-01 1.655e-01 1.560e-01 -1.049411e+04 8.951872e+03 6.489914e+01 -6.000000e+00 9.473040e+03 282.17 -2.00 20.00 -2.00 505.22 0.00e+00 2.824507e-03 4.297584e-03 4.395303e-05 -6.000000e+00 4.825219e-03 282.17 -2.00 20.00 -2.00 500.18 0.00e+00 3.099415e+00 3.054196e+00 8.793929e-02 -6.000000e+00 3.438907e+00 225.65 -2.00 3.16 -2.00 501.83 0.00e+00 20.154 0.077 489.00 513.00 1 9.9564e+00 2.3688e-01 3.1620e-02 -6.0000e+00 2.6258e-01 8.6870e-02 5.8479e-02 2.1714e-03 -6.0000e+00 6.9888e-02 3.9485e-06 7.2499e-02 1.5319e-02 5.1664e-05 -6.0000e+00 1.7114e-02 6.2498e-02 -1.1355e-03 12 13 8 11 8 0 2.03 21.91 10.45 0.06250 0.56538 8 2 1 4 0 4000.000 25.90 20.02 21.91 900000 -2910 -7560 11750 21266 40518 -466 -1010 19904 3581 -20324 16169 4256 8392 22672 21005 -5344 17405 -19518 -11831 -6921 14368 1090 -6839 4192 -17466 9486 -1981 29167 -11778 -11945 28246 -266 151 953 794 97 19555 -11160 -4662 -10460 -8508 5813 -11700 -11912 16628 16730 12870 4600 -8469 30089 6853 6579 24341 27188 -10785 958 -4841 19102 -14612 -16880 9380 -10788 7844 -13068 3772 -3606 19730 7024 8315 29422 -14352 -17217 -9957 22206 9592 7654 2018 -6827 -15532 8319 37682 9550 2473 1839 -1902 4643 -7681 -6685 -14946 11895 21723 -22365 52305 -967 21584 -6155 13351 24580 3464 -6198 -31230 23381 1979 22155 29024 -6589 68420 -13014 14442 -1694 31935 -10378 -2251 15638 -14112 6830 -3302 -17634 4766 -1344 30147 -18278 22862 -16664 3734 -15026 4732 34662 5614 3461 -11374 -5098 4838 -10244 12552 8315 21081 10048 43020 17954 13983 16900 -288 27793 -23649 26397 -12267 13668 5123 9935 6696 -27676 900000 -3242 -8999 11677 19277 30089 -514 -1103 17390 3637 -25968 14303 4277 8248 19808 19040 -6361 16537 -26857 -15118 -8465 14279 1238 -7807 4532 -21364 8605 -1979 21405 -13326 -14001 22745 -288 162 1000 826 101 16743 -13082 -5180 -12475 -10060 5985 -14310 -14449 14915 14665 11413 4314 -8891 21469 6287 6237 19849 21892 -12752 1006 -5378 16745 -18022 -21335 9083 -12645 7515 -15184 3652 -3712 15887 6372 7458 21592 -16531 -20532 -10961 17428 8408 6787 1893 -7029 -17573 7462 25350 8566 2394 1800 -1938 4448 -7854 -6836 -16853 11155 18820 -28638 34121 -1007 17738 -6529 11355 18321 3178 -6338 -41780 18321 1910 17148 20524 -6548 32037 -13928 12007 -1699 23498 -11900 -2409 14047 -16991 6592 -3470 -21063 4509 -1348 22182 -22008 18351 -19904 3640 -17661 4567 24842 5365 3341 -12500 -5164 4392 -10865 10795 7628 17325 9313 28776 15440 12560 14858 -303 22043 -29139 20432 -12798 11494 4699 8829 5901 -34848 SO 20170728T110025.0Z 6418.458623 471 1 31.99 2 88.99 66.10 128.17 122.93 0.00 1 0.00 1 0 29 1.065e-01 1.036e-01 1.045e-01 1.016e-01 7.256078e+03 6.982434e+03 1.106703e+03 -6.000000e+00 5.807824e+03 282.17 -2.00 20.00 -2.00 505.38 0.00e+00 -2.884426e-03 2.766355e-03 1.543055e-04 -6.000000e+00 2.946751e-03 282.17 -2.00 20.00 -2.00 500.28 0.00e+00 2.437244e+00 2.027118e+00 4.041988e-02 -6.000000e+00 2.078760e+00 225.65 -2.00 3.16 -2.00 501.92 0.00e+00 18.638 0.061 489.00 513.00 1 9.8432e+00 1.5538e-01 2.8448e-02 -6.0000e+00 1.5928e-01 4.7154e-02 3.9687e-02 1.6108e-03 -6.0000e+00 4.1456e-02 6.1626e-06 -5.9532e-03 9.3569e-03 1.4207e-04 -6.0000e+00 1.0472e-02 -5.5381e-02 5.7106e-04 12 9 8 11 8 0 -543.64 21.91 2.88 -0.05538 -0.09668 8 2 1 4 0 4000.000 26.00 20.07 21.91 1528 3517 9056 -5662 -11723 18992 2017 -2030 13778 609 -3156 -3076 -8004 -19534 10199 11363 12273 18765 -178 24102 -1952 3876 -10190 4955 314 -8322 15156 -2637 9018 -11210 13195 -5334 -17404 -3863 -8218 666 -6222 -1295 -3750 562 22224 513 4894 -8803 6698 12627 9157 -599 -843 4191 -14862 16742 1606 -7562 11 4727 12021 22592 5928 -6706 -2152 6917 18790 2307 10330 4853 -2286 -21705 -183 -10238 -17794 -3359 583 -7137 3616 -5072 2073 -7120 -1217 11079 -4638 12824 -3353 15938 7092 -5211 -75 10457 5796 2375 5052 10340 -6101 12235 1846 21190 13005 -3009 5189 -8396 -3657 17729 21554 -9718 15302 -17094 -8094 -6930 -220 9091 55 -1746 4449 -6303 -4835 1141 19299 -11584 263 -16340 10814 11916 17387 11320 7395 -2498 -13727 2971 540 -22166 -5200 -2188 5340 5766 9196 20217 -10418 3216 12986 13194 10337 -3666 -14854 -2994 9363 4515 6251 -19985 -307 22989 15960 19449 -9032 1413 3253 8185 -6124 -13848 16894 2167 -2297 13334 668 -3549 -3415 -9227 -25021 9653 10674 11616 17093 -201 21782 -2152 4042 -12250 5134 342 -9893 14193 -2925 8745 -12954 11656 -5633 -21038 -4208 -9661 730 -7315 -1437 -4209 597 18894 541 4973 -10349 6806 12160 9123 -653 -907 4203 -17571 14010 1526 -7785 11 4458 10859 18756 5867 -7527 -2301 6753 16348 2375 9811 4835 -2414 -27391 -184 -11220 -20800 -3369 561 -7490 3458 -5356 2038 -7566 -1196 9492 -4621 10732 -3318 13126 6453 -5094 -71 8920 5197 2204 4562 8885 -6230 10513 1770 16625 10851 -2867 4426 -7998 -3256 12585 14763 -9319 11910 -19266 -8618 -7379 -218 8095 53 -1717 4155 -6633 -5058 1129 15983 -13127 267 -19738 9965 10759 14616 9939 6677 -2489 -15386 2831 528 -27189 -5375 -2193 4955 5278 8017 15609 -10898 2964 11078 11502 9462 -3926 -16975 -3070 9095 4366 5972 -24829 -311 18188 13281 15387 -9475 SO 20170728T110432.0Z 6418.461481 475 1 32.00 2 88.21 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