File name: Pandora114s1_BuenosAires_20170805_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T012613.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170805_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170805 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170805T104930.0Z 6426.451042 361 1 32.00 2 89.75 69.21 109.10 229.70 0.00 1 0.00 1 0 22 1.013e-01 9.591e-02 7.833e-02 7.597e-02 7.156069e+03 5.230660e+03 7.634728e+02 -6.000000e+00 5.518590e+03 282.10 -2.00 20.00 -2.00 505.22 0.00e+00 2.722045e-03 2.051706e-03 1.062659e-04 -6.000000e+00 2.800971e-03 282.10 -2.00 20.00 -2.00 500.01 0.00e+00 8.131357e-01 1.533537e+00 2.044495e-02 -6.000000e+00 1.981277e+00 226.01 -2.00 3.16 -2.00 501.62 0.00e+00 20.143 0.077 489.00 513.00 1 9.3730e+00 1.1713e-01 3.1033e-02 -6.0000e+00 1.5173e-01 1.3541e-01 3.0134e-02 1.7490e-03 -6.0000e+00 3.9621e-02 8.2923e-06 4.5600e-03 7.1133e-03 9.1806e-05 -6.0000e+00 9.9588e-03 6.5908e-02 -3.3508e-04 12 9 8 11 8 0 94.76 21.26 9.20 0.06591 0.09754 8 2 1 4 0 4000.000 25.39 20.02 21.26 3050 19830 14792 1792 -16185 3649 -15832 -495 6758 -4526 -4785 -4433 6935 -14286 14852 5830 11953 9650 2256 4028 -3145 10065 -5924 7793 -4973 304 11671 -8618 15715 -8022 8736 -3064 -1656 5544 -9366 10932 -6616 11236 -10571 17374 7444 -1837 2057 -14502 18381 -6517 5552 -1425 -829 -2586 -9308 15500 -638 10979 -3952 -1369 2761 -10666 5254 1835 28069 -2923 -3753 -4399 3788 14682 -7361 12049 -8611 -3482 -345 -4399 5218 -10814 14001 -780 284 6524 -4237 -392 -7593 2922 -6936 3108 9828 10249 -2278 -4902 6151 -1734 1116 4681 -5669 6665 -5752 11796 -7633 10714 4693 1694 15327 -1006 -2534 -19557 20662 -12891 7363 -12800 4152 13713 -12694 11139 -589 22708 -5458 -748 6947 -10967 36324 -11865 8680 3278 -1876 5312 -8160 19180 -11578 1979 4034 3414 9361 -9907 22058 5013 -5044 -13448 15958 1248 -2244 5547 -6223 13499 878 16557 -15600 2313 16412 -19093 6342 -1069 576 309 2105 2985 16877 13690 1945 -21523 4056 -21643 -582 7333 -5416 -5650 -5141 7082 -16667 13825 5586 10978 9294 2386 4219 -3544 9944 -6882 7931 -5777 335 11414 -10183 14199 -8921 8067 -3195 -1743 5614 -11299 10855 -7784 10933 -12647 15612 7392 -2016 2196 -18503 17064 -7797 5871 -1598 -910 -2824 -10582 13390 -637 9757 -4159 -1448 2878 -12920 5451 1968 23132 -3294 -4285 -5067 4005 13776 -8478 11246 -9747 -3699 -351 -4340 5000 -11526 12581 -766 273 5800 -4122 -363 -7527 2611 -6876 2807 8371 8777 -2227 -4928 5525 -1679 1049 4270 -5805 6111 -5997 10212 -7851 8926 4041 1467 11342 -866 -2229 -20935 15386 -13920 6614 -14060 3807 11297 -13589 9488 -573 17755 -5715 -752 6498 -12352 25697 -13640 8079 3173 -1877 4870 -8507 15265 -11868 1888 3552 3021 7791 -9981 17042 4260 -4662 -13372 12552 1083 -2054 4787 -6134 11057 823 13345 -17425 2168 13372 -22080 5612 -997 517 275 1844 SO 20170805T105334.0Z 6426.453866 365 1 32.00 2 88.97 68.63 109.71 228.97 0.00 1 0.00 1 0 15 5.911e-02 5.762e-02 5.675e-02 5.584e-02 2.430303e+03 3.450432e+03 1.291504e+02 -6.000000e+00 3.221505e+03 282.10 -2.00 20.00 -2.00 505.28 0.00e+00 3.534423e-03 1.504349e-03 1.803149e-04 -6.000000e+00 1.635382e-03 282.10 -2.00 20.00 -2.00 500.08 0.00e+00 4.507691e+00 1.100059e+00 3.328608e-02 -6.000000e+00 1.157225e+00 226.01 -2.00 3.16 -2.00 501.71 0.00e+00 18.595 0.060 489.00 513.00 1 9.0010e+00 8.4202e-02 2.8467e-02 -6.0000e+00 8.8615e-02 3.9686e-02 2.1500e-02 1.6332e-03 -6.0000e+00 2.3153e-02 1.1480e-05 1.6595e-02 5.2388e-03 6.8091e-05 -6.0000e+00 5.8141e-03 3.8997e-02 -2.0306e-04 12 8 8 10 0 0 -135.62 21.26 8.78 0.03900 0.15411 8 2 1 4 0 4000.000 25.39 19.58 21.26 -1139 5419 -3982 7446 -3231 747 2131 106 6309 -1611 7089 609 5513 -7934 -4429 3255 -4143 4739 -5408 -7847 -328 5393 2806 -4409 -2151 -3377 3981 -112 2930 -2304 -2364 8534 -5493 8525 4766 266 -2343 -3189 -755 -905 7647 2062 5084 -2574 -4339 77 -3896 11941 -11346 4417 -3642 8461 13837 2908 -758 -8075 10559 -4111 12358 1483 -5579 3315 -11000 7553 -1561 -3388 -104 -1333 470 -4346 4325 -6004 7059 -5503 -1247 1864 574 -2800 -897 1485 -6294 -868 4995 -6911 -1938 3502 -1047 303 3730 -1260 -3385 7683 2720 6810 2758 -4379 10369 -3001 482 -6728 16168 -14241 5489 -6076 85 1953 -3057 826 -4470 465 -6324 -6341 1215 -1657 8251 5817 4746 3642 8635 446 -7001 17240 -691 6069 -5502 2941 6467 3509 489 -8757 312 -10641 11358 -4674 -1837 -5123 4945 7184 -6611 -4739 -6124 3374 7507 2288 6328 8586 7556 -12447 6258 2607 -2080 5888 -7530 -1158 5338 -4452 7626 -3764 849 2407 114 6733 -1710 6803 616 5250 -8598 -4654 3219 -4520 4841 -6196 -9248 -359 5589 3000 -5100 -2441 -3868 4197 -121 2972 -2404 -2458 8096 -6193 8616 5077 296 -2650 -3596 -823 -988 7700 2220 5379 -2977 -5145 87 -4562 11763 -13827 4481 -3893 7841 12066 2865 -796 -9399 10402 -4724 12039 1607 -6493 3544 -12755 7260 -1628 -3547 -104 -1322 451 -4326 3906 -5997 6229 -5572 -1220 1760 540 -2672 -829 1331 -6092 -798 4357 -6832 -1836 3163 -992 283 3356 -1189 -3276 6728 2540 6173 2604 -4389 8796 -2843 430 -6306 11835 -14078 4525 -5798 79 1811 -2980 765 -4312 425 -6230 -6355 1151 -1643 7507 5472 4545 3550 8034 449 -7055 14271 -676 5522 -5314 2632 5622 3152 453 -8909 290 -11031 9361 -4454 -1679 -4816 4235 6129 -6619 -4745 -6309 3194 6864 2217 5929 7906 7030 -14025 5741 2426 -1995 5213 -7734 SO 20170805T105743.0Z 6426.456748 369 1 32.00 2 88.18 68.03 110.33 228.21 0.00 1 0.00 1 0 15 3.998e-02 3.919e-02 3.781e-02 3.740e-02 7.016030e+02 2.110810e+03 6.107709e+01 -6.000000e+00 2.178940e+03 282.10 -2.00 20.00 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