File name: Pandora114s1_BuenosAires_20170813_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T013827.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170813_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170813T104124.0Z 6434.445417 321 1 32.00 2 89.73 72.07 53.41 315.32 0.00 1 0.00 1 0 50 7.918e-02 7.704e-02 8.029e-02 7.853e-02 1.161989e+03 4.658795e+03 1.019015e+02 -6.000000e+00 4.314918e+03 282.03 -2.00 20.00 -2.00 505.27 0.00e+00 6.969484e-03 2.092366e-03 4.028684e-04 -6.000000e+00 2.190277e-03 282.03 -2.00 20.00 -2.00 500.12 0.00e+00 3.153657e+00 1.566082e+00 5.894537e-02 -6.000000e+00 1.551102e+00 226.37 -2.00 3.16 -2.00 501.73 0.00e+00 20.115 0.076 489.00 513.00 1 9.1926e+00 1.1942e-01 3.2608e-02 -6.0000e+00 1.1877e-01 9.1621e-02 3.0881e-02 1.7861e-03 -6.0000e+00 3.1034e-02 8.0115e-06 1.4126e-02 7.5273e-03 1.5924e-04 -6.0000e+00 7.7887e-03 9.8679e-03 -2.8584e-05 12 8 8 10 0 0 -807.38 20.79 9.64 0.00987 0.10785 8 2 1 4 0 4000.000 24.96 19.65 20.79 5004 4402 6089 -5901 -1829 -3543 -4717 -5983 7285 8721 -6073 17045 10508 1992 -10425 -3425 -816 5455 2188 6054 -10503 -8560 2268 -3617 225 1108 -10169 10147 -6854 12389 -6621 15796 -2261 12304 10359 -10398 7970 -4410 6047 12952 4639 10 -8448 -695 -14615 10818 -3080 15324 10289 -5395 8404 5649 17427 3136 1205 1287 -5346 -10380 -5967 -1604 -7273 -8100 -1999 4479 -8553 3279 -4587 -2925 10480 1726 10737 -2436 -449 629 -3407 8618 3921 8540 21582 406 -3916 -73 3514 -7371 2295 3297 16569 2704 12364 -8106 -13883 11078 1357 9286 3565 -10879 15231 -3059 -9872 -1799 3135 1523 -1573 9365 11589 -6539 -12268 -9762 6529 8260 -6012 -3121 -861 -1242 8096 13601 1412 8037 -14783 1735 -6998 -5753 10227 2220 15172 6061 -9732 3978 152 -2737 3750 1616 -13190 10132 2080 626 2446 -7992 3811 -7488 4314 4662 -3505 -3625 8963 11479 7851 -1757 -1330 3092 -5294 -8529 1958 4759 4357 6126 -6878 -2091 -4188 -5680 -7269 7651 8871 -7045 15463 10053 2060 -11395 -3533 -838 5374 2257 6027 -12343 -9884 2363 -4028 243 1182 -12054 9633 -7492 10872 -6965 13456 -2378 11554 10100 -12486 7894 -4888 5989 11964 4690 11 -10014 -774 -18900 10880 -3540 14469 10032 -6008 7935 5363 14576 3058 1231 1354 -6145 -12677 -6981 -1795 -8621 -9726 -2267 4758 -10271 3449 -5131 -3167 9788 1736 9752 -2513 -456 639 -3636 8137 3823 7801 17055 369 -3711 -66 3111 -7305 2076 2966 13072 2445 10112 -8112 -14761 9273 1273 8176 3345 -11723 12457 -2943 -9926 -1627 2640 1289 -1385 7569 9423 -6481 -12866 -9862 5528 6835 -5785 -2973 -820 -1213 7322 11778 1393 7462 -17282 1711 -7440 -5951 8905 2083 12555 5540 -10488 3751 149 -2765 3554 1563 -13796 8773 1921 582 2236 -7744 3557 -7493 4130 4222 -3459 -3595 7873 9876 7003 -1710 -1264 2744 -5010 -8303 1738 SO 20170813T104528.0Z 6434.448241 325 1 32.00 2 88.94 71.49 54.00 314.34 0.00 1 0.00 1 0 15 3.026e-02 3.012e-02 3.034e-02 3.015e-02 7.151423e+03 1.980543e+03 3.242568e+02 -6.000000e+00 1.649327e+03 282.03 -2.00 20.00 -2.00 505.29 0.00e+00 1.956924e-03 8.230856e-04 1.236007e-04 -6.000000e+00 8.367896e-04 282.03 -2.00 20.00 -2.00 500.40 0.00e+00 9.706305e-01 5.916957e-01 8.784159e-02 -6.000000e+00 5.910593e-01 226.37 -2.00 3.16 -2.00 502.01 0.00e+00 18.515 0.059 489.00 513.00 1 8.6549e+00 4.5566e-02 2.8904e-02 -6.0000e+00 4.5283e-02 7.7037e-02 1.1460e-02 2.2471e-03 -6.0000e+00 1.1787e-02 2.1706e-05 4.6906e-03 2.8291e-03 4.5968e-05 -6.0000e+00 2.9746e-03 -2.1582e-02 3.7396e-04 12 8 8 10 0 0 92.09 20.77 2.87 -0.02158 0.01095 8 2 1 4 0 4000.000 24.96 19.76 20.77 -934 3133 -4841 -1361 -6059 -1002 3578 -2152 -341 1061 -2494 -1200 4129 3473 -5116 3150 -252 5423 -86 162 3700 482 1341 -1369 3643 2315 -1548 -2651 -4476 538 -3615 372 -1177 -2339 814 -151 3389 -1548 -988 4618 -288 -48 -2786 5211 -3725 2968 4975 2945 -183 4085 1564 2570 1516 -4887 3207 -7 2982 1284 2724 -1866 -2039 -2675 1553 -1255 809 -2059 -550 -5101 3611 -576 -676 2528 -1621 392 -2735 8196 -1858 1243 -162 -632 -854 -4174 -262 2924 3162 -2627 -5516 545 1909 300 -4008 1159 -6532 3125 168 1275 2376 -7214 1147 -4889 -2184 4592 245 2741 -605 -1583 5021 293 4216 -550 251 -3149 1333 -2795 -78 3391 3394 -783 225 -1197 -187 3400 -4346 3043 2905 3602 194 2323 3167 -4059 2974 3576 88 4944 2876 -4247 -5229 4766 -50 4041 -309 -1632 4302 2309 -1365 -265 -5418 3169 -2027 327 -4920 -2302 -3682 -865 2870 -4969 -1389 -6637 -1064 3673 -2345 -362 1095 -2629 -1231 3970 3332 -5342 3059 -259 5395 -92 175 3856 520 1437 -1516 3854 2481 -1714 -2925 -4903 544 -3760 374 -1236 -2571 888 -167 3605 -1711 -1074 4722 -310 -52 -2938 5140 -4059 3036 4971 2970 -188 3916 1497 2373 1394 -4811 2980 -7 2941 1307 2742 -1964 -2150 -2850 1595 -1328 835 -2164 -561 -5361 3435 -565 -656 2367 -1589 382 -2783 7508 -1863 1187 -155 -600 -811 -4109 -250 2722 2967 -2640 -5746 536 1847 294 -4109 1137 -7009 3082 171 1267 2282 -7422 1057 -4678 -1997 3893 220 2470 -553 -1513 4564 279 3811 -516 234 -3071 1262 -2798 -76 3242 3263 -791 227 -1228 -188 3256 -4419 2835 2701 3343 187 2205 2983 -4107 2802 3344 85 4461 2610 -4105 -5118 4283 -48 3808 -309 -1674 4195 2312 -1426 -275 -5924 3162 -2100 324 -5037 -2277 -3718 SO 20170813T104930.0Z 6434.451042 329 1 32.00 2 88.15 70.91 54.60 313.39 0.00 1 0.00 1 0 22 8.360e-03 8.288e-03 7.805e-03 7.778e-03 6.781608e+03 5.109379e+02 4.511883e+02 -6.000000e+00 4.556340e+02 282.03 -2.00 20.00 -2.00 505.35 0.00e+00 2.936184e-03 2.107143e-04 1.707929e-04 -6.000000e+00 2.311901e-04 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