File name: Pandora114s1_BuenosAires_20170815_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T013848.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170815_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170815T103912.0Z 6436.443889 345 1 32.00 2 89.73 72.83 50.54 349.31 0.00 1 0.00 1 0 29 1.117e-01 1.071e-01 1.093e-01 1.057e-01 1.116539e+04 7.721877e+03 5.892776e+02 -6.000000e+00 6.087433e+03 282.02 -2.00 20.00 -2.00 505.32 0.00e+00 -2.646746e-03 2.891319e-03 1.303843e-04 -6.000000e+00 3.087570e-03 282.02 -2.00 20.00 -2.00 500.04 0.00e+00 1.559525e+00 2.128864e+00 9.323173e-02 -6.000000e+00 2.178662e+00 226.46 -2.00 3.16 -2.00 501.71 0.00e+00 20.106 0.076 489.00 513.00 1 9.7315e+00 1.6333e-01 3.1912e-02 -6.0000e+00 1.6695e-01 1.0389e-01 4.1275e-02 2.5684e-03 -6.0000e+00 4.3380e-02 5.8896e-06 7.0069e-03 9.3926e-03 6.6586e-05 -6.0000e+00 1.0969e-02 -6.1032e-02 7.0996e-04 12 8 8 10 0 0 18.76 21.23 15.02 -0.06103 -0.01243 8 2 1 4 0 4000.000 25.39 20.31 21.23 -6294 3266 9527 7761 13060 14983 -10924 8341 -6081 -4872 -14541 -264 31750 -4691 2262 -8774 -2503 3471 -4723 23408 -2553 25303 3995 8258 -12725 -8087 1278 9535 9694 -562 -2206 10151 -11127 -7826 -10907 5501 -6412 6655 -15124 -1814 9381 -6975 4525 3477 -2822 4701 14973 3145 10841 13474 5300 9445 -22941 -817 19326 -11574 10460 -10115 15950 8992 -634 13588 14683 -4424 6085 20560 -23500 -2438 -4342 25303 -3740 -11822 -1865 -10924 27518 -3834 14386 14039 -11970 12437 -20898 2587 -5094 5263 5856 -6679 5017 -7555 5091 -5428 14768 4193 4457 2825 5377 -8561 -7954 2167 2470 -14797 26805 4014 16687 3509 -2279 -13570 6157 8062 -14424 23917 -7663 15648 15083 4017 5594 12136 8831 -11585 -121 3533 -15503 -1674 10197 4283 -7561 -1910 4762 12315 -7857 -12995 18237 6331 6810 -3925 -10343 -8679 12439 -4509 4604 -344 -9949 15417 16519 -12329 8025 -10188 11058 -4542 8216 -1713 -1383 2201 13129 -6662 3239 9167 7813 12761 14639 -13989 8829 -7382 -5770 -18729 -292 25147 -5313 2394 -10522 -2890 3879 -5449 22005 -2910 23413 4278 8501 -16177 -9777 1395 9420 9309 -583 -2301 9467 -13222 -9300 -13640 5853 -7619 6850 -19122 -1993 9203 -8096 4720 3699 -3217 4969 14172 3303 10336 12195 5053 8418 -27895 -801 15889 -13354 9901 -11880 14435 8697 -674 12579 13492 -4921 6054 17472 -30523 -2526 -4530 19405 -3798 -12986 -1868 -12151 21103 -4026 12424 11930 -12984 10482 -23011 2413 -4850 4873 5121 -6706 4516 -7732 4583 -5414 12052 3830 4099 2653 4876 -8706 -7779 1852 2048 -14280 16841 3171 11889 2977 -2155 -14941 5662 7258 -16069 17970 -7892 12871 12603 3772 5181 10533 7951 -12906 -121 3432 -18074 -1670 8850 3884 -7688 -1844 4318 10369 -8092 -14056 14411 5618 5954 -3762 -10450 -8601 10071 -4410 4205 -336 -10890 13281 14230 -13453 7641 -10993 9639 -4596 7212 -1629 -1290 1973 10644 SO 20170815T104316.0Z 6436.446713 349 1 32.00 2 88.93 72.25 50.71 348.09 0.00 1 0.00 1 0 15 4.342e-02 4.468e-02 4.080e-02 4.053e-02 1.055520e+04 2.809470e+03 9.662626e+02 -6.000000e+00 2.366655e+03 282.02 -2.00 20.00 -2.00 505.36 0.00e+00 2.218390e-03 1.100098e-03 1.326198e-04 -6.000000e+00 1.201435e-03 282.02 -2.00 20.00 -2.00 500.51 0.00e+00 9.038169e-01 7.895213e-01 2.857028e-02 -6.000000e+00 8.514134e-01 226.46 -2.00 3.16 -2.00 502.10 0.00e+00 18.491 0.059 489.00 513.00 1 8.9593e+00 6.0272e-02 2.8189e-02 -6.0000e+00 6.5183e-02 5.2115e-02 1.5297e-02 1.9272e-03 -6.0000e+00 1.7046e-02 1.5967e-05 1.0302e-02 3.6556e-03 1.1587e-04 -6.0000e+00 4.2763e-03 -5.1396e-02 2.9607e-04 12 8 8 10 0 0 -64.93 21.23 3.42 -0.05140 0.02006 8 2 1 4 0 4000.000 25.39 19.64 21.23 -7093 -1518 1644 680 136 5387 219 3916 1356 -6382 2543 1221 -3974 -1605 4434 -3873 -10525 2973 -4504 4739 -5350 1498 580 2451 9039 986 9348 -17754 -2431 -3966 -5687 1909 -2547 6969 664 6217 4354 -250 3051 2022 3798 5166 7739 -308 3255 -1131 -2134 5417 3545 -5807 -2332 -1219 1913 -3560 3802 -1122 -1410 1819 -4952 942 1722 6461 -172 3752 -3799 1363 2624 2660 -5525 -1701 96 -4424 -3189 -1671 -1314 -2083 8675 3888 -3721 25 4622 260 1444 -837 519 8627 619 6851 3162 -580 7301 -3115 -1830 5379 1044 -1566 1542 4108 7279 -2885 386 2006 -4288 -1479 -4691 -1702 6172 -1012 3541 4194 -3002 -5175 -296 -2573 -4759 1307 1349 4658 -149 6886 -4287 -804 -10918 3985 -1401 1762 -1150 -3075 -286 4065 -2494 -9371 3675 6824 1326 -3028 3635 -70 -4561 -6037 -3989 6939 1837 3077 1644 -2156 -147 -3945 2984 800 -103 5911 -3368 -7205 -1503 1632 656 136 5179 224 3879 1369 -6862 2465 1184 -4010 -1568 4075 -3908 -11596 2937 -4890 4731 -5922 1551 608 2538 8809 1042 9036 -22193 -2543 -4097 -5889 1845 -2644 6810 709 6322 4485 -267 3119 2078 3842 5199 7686 -336 3466 -1264 -2402 5595 3670 -6460 -2439 -1230 1844 -3639 3695 -1182 -1531 1820 -5324 954 1732 6224 -178 3745 -4075 1374 2573 2569 -5720 -1676 92 -4416 -3159 -1652 -1311 -2105 7797 3601 -3658 23 4131 244 1345 -804 497 7711 604 6294 3007 -570 6635 -3164 -1858 5141 1042 -1579 1467 3692 6163 -2643 337 1708 -3939 -1366 -4682 -1716 5869 -1035 3429 3998 -3078 -5486 -303 -2574 -4904 1274 1321 4452 -152 6549 -4538 -809 -11940 3697 -1365 1672 -1131 -3097 -280 3818 -2500 -10051 3435 6092 1233 -2922 3296 -67 -4657 -6376 -4195 6632 1867 3113 1698 -2322 -156 -4305 2998 806 -102 5511 -3471 SO 20170815T104719.0Z 6436.449525 353 1 32.00 2 88.13 71.67 50.89 346.88 0.00 1 0.00 1 0 22 7.935e-03 7.823e-03 3.696e-03 3.684e-03 1.396372e+04 2.588720e+02 9.271108e+02 -6.000000e+00 4.324403e+02 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