File name: Pandora114s1_BuenosAires_20170821_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T013836.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170821_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170821T103201.0Z 6442.438900 442 1 32.00 2 89.75 75.23 88.25 71.66 0.00 1 0.00 1 0 15 8.680e-02 8.325e-02 8.210e-02 8.029e-02 1.911725e+03 4.928003e+03 2.691362e+01 -6.000000e+00 4.732200e+03 282.10 -2.00 20.00 -2.00 505.27 0.00e+00 1.826407e-03 2.175908e-03 6.363830e-05 -6.000000e+00 2.401584e-03 282.10 -2.00 20.00 -2.00 500.02 0.00e+00 4.050272e+00 1.608266e+00 4.017299e-02 -6.000000e+00 1.701792e+00 226.74 -2.00 3.16 -2.00 501.67 0.00e+00 20.132 0.076 489.00 513.00 1 9.2225e+00 1.2334e-01 3.1068e-02 -6.0000e+00 1.3029e-01 6.8345e-02 3.1713e-02 1.8277e-03 -6.0000e+00 3.4064e-02 7.7967e-06 5.5323e-03 7.4773e-03 2.7530e-05 -6.0000e+00 8.5402e-03 1.2533e-02 -7.2978e-05 12 8 8 10 0 0 -175.93 20.77 -4.79 0.01253 0.05091 8 2 1 4 0 4000.000 24.96 19.88 20.77 10696 -11231 -14069 1397 -8062 -2159 12236 7291 2131 11417 5575 -2990 4074 -2633 8985 4748 10600 8736 -4217 7664 -4303 6518 15333 -14724 -3361 -9505 9443 -5944 -5998 -7040 10902 -1871 -9281 3250 -12013 11589 -5445 1357 -5948 7469 10600 -1093 23702 1131 -3900 2122 -5557 3164 7034 1737 -5931 10196 -5707 -5419 -1090 -4668 5053 -10115 489 -3079 7132 -4540 5088 18295 -3021 15628 -6668 4575 -7005 15462 3237 -6982 7523 7334 14425 -75 12976 -629 -13463 -9227 -7108 4433 -6954 -2156 -2985 -5743 -2535 -12610 6317 13736 -394 7304 6225 2183 5618 3069 -8898 -5573 3790 -1428 8010 -12950 9445 6720 -705 -6443 2632 13518 -11215 1190 344 5729 -721 2092 7318 -3976 24403 -4525 8091 -5790 -7878 5557 -11649 -7145 3246 11010 -4673 18657 4035 3516 8364 -11535 6417 -5096 -2647 4718 -17351 25889 -15923 2916 4173 -486 2377 -2309 8698 5785 3234 7528 16008 -10802 1098 -6539 -3314 9441 -12691 -16926 1484 -9654 -2488 12382 7788 2384 11489 5861 -3378 4237 -2901 8789 4885 10488 9036 -4735 7721 -4900 6669 14401 -18773 -3845 -11570 9463 -6861 -6767 -7794 9896 -1934 -10567 3376 -14939 11492 -6371 1467 -6834 7446 10233 -1192 20396 1234 -4523 2327 -6560 3386 7123 1814 -6504 9255 -5959 -5630 -1104 -5046 5091 -12047 526 -3424 7147 -5122 5233 16511 -3361 14268 -7487 4513 -7645 13305 3108 -7364 6868 6773 12564 -76 11438 -624 -13974 -9078 -6818 3794 -6705 -1994 -2804 -5593 -2407 -13274 5500 11081 -367 6324 5512 2040 5112 2853 -9192 -5455 3300 -1278 6383 -12550 7341 5487 -642 -6402 2421 11105 -11640 1077 313 4988 -681 1955 6587 -4048 18846 -4696 7442 -6124 -8448 5139 -12606 -7310 2986 9424 -4712 14959 3751 3286 7447 -11802 5808 -5113 -2552 4177 -17993 18721 -16808 2768 3982 -463 2223 -2277 7732 5330 3070 6831 13192 -11402 1007 -6388 -3145 SO 20170821T103605.0Z 6442.441725 446 1 32.09 2 88.94 74.66 87.48 71.10 0.00 1 0.00 1 0 15 4.911e-02 4.834e-02 4.887e-02 4.819e-02 2.598811e+03 3.002002e+03 1.362998e+02 -6.000000e+00 2.677448e+03 282.10 -2.00 20.00 -2.00 505.27 0.00e+00 -1.642385e-04 1.307629e-03 2.650779e-05 -6.000000e+00 1.358512e-03 282.10 -2.00 20.00 -2.00 500.10 0.00e+00 2.858060e+00 9.560399e-01 2.920023e-02 -6.000000e+00 9.611205e-01 226.74 -2.00 3.16 -2.00 501.75 0.00e+00 18.515 0.059 489.00 513.00 1 9.0396e+00 7.3181e-02 2.7997e-02 -6.0000e+00 7.3612e-02 7.1935e-02 1.8814e-02 1.6313e-03 -6.0000e+00 1.9200e-02 1.3320e-05 3.1622e-03 4.5341e-03 1.6287e-05 -6.0000e+00 4.8309e-03 5.7710e-03 1.0295e-04 12 8 8 10 0 0 59.52 20.78 8.46 0.00577 0.02771 8 2 1 4 0 4000.000 24.96 19.56 20.78 3866 -1835 3164 712 3808 -3385 -1683 -6204 7029 3632 -783 3403 -14248 -277 -7962 2527 3309 1703 -6295 4094 5886 -5335 7112 -3914 2886 6070 -8636 -4071 -795 3217 3250 -3794 -2373 1295 4569 -763 3249 -1589 3204 1156 -2492 2268 -3405 4827 -850 2313 4249 3119 -39 316 9774 3681 -1722 -1907 -1336 12021 -9789 731 -2344 -4252 1258 -1188 -1374 2872 6126 -935 10859 -2381 -1382 787 -2247 5039 -1199 1783 2182 633 -9009 -7932 1681 -12 4643 -11668 7281 -1170 10062 4658 -5094 11612 -1921 8525 907 -2447 1113 -2141 801 -2511 337 -3082 3681 -5108 6461 8933 -3853 14393 -4420 -1419 -2846 7595 1210 -736 8513 -6852 1168 -6105 -1167 1404 -5720 -2080 -4050 8379 -7114 6573 2215 1000 3426 492 2926 -124 -1535 149 1872 -2032 -3076 1051 -3833 -2525 -5345 415 7639 -5604 -2427 2979 4199 4555 -5180 9783 762 1641 -3430 995 -1758 -3001 -2672 3704 -1913 3244 771 4098 -3730 -1849 -7169 7083 3739 -830 3418 -16868 -283 -8749 2522 3345 1797 -7354 4357 6171 -6266 7390 -4560 3153 6422 -10523 -4679 -864 3262 3234 -4061 -2563 1394 4892 -869 3539 -1797 3410 1245 -2777 2420 -3881 5122 -964 2549 4575 3358 -43 337 9202 3581 -1735 -1922 -1363 11053 -11498 785 -2606 -4506 1259 -1220 -1420 2848 5859 -949 9648 -2376 -1346 741 -2156 4462 -1133 1653 2042 605 -9414 -8054 1524 -11 4029 -11952 6211 -1095 8495 4194 -5098 9872 -1871 7474 859 -2413 1071 -2155 787 -2535 326 -3012 3282 -4855 5359 7146 -3525 11259 -4332 -1395 -2881 6905 1158 -709 7439 -7038 1124 -6416 -1182 1397 -5785 -2040 -4073 7915 -7333 5825 2019 911 3037 452 2634 -116 -1450 138 1706 -1926 -2931 949 -3578 -2301 -5005 371 6494 -5559 -2373 2798 3932 4277 -5396 8833 756 1609 -3497 951 -1690 -2885 -2568 SO 20170821T104007.0Z 6442.444525 450 1 32.00 2 88.14 74.08 86.71 70.54 0.00 1 0.00 1 0 22 2.227e-02 2.214e-02 2.080e-02 2.070e-02 4.695216e+03 1.331563e+03 3.592758e+02 -6.000000e+00 1.213719e+03 282.10 -2.00 20.00 -2.00 505.33 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