File name: Pandora114s1_BuenosAires_20171028_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T020122.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171028_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171028T090150.0Z 6510.376273 334 1 32.00 2 89.75 105.96 126.52 201.85 0.00 1 0.00 1 0 36 1.636e-01 1.447e-01 1.469e-01 1.387e-01 9.135843e+03 9.704946e+03 7.617991e+02 -6.000000e+00 9.000492e+03 284.46 -2.00 20.00 -2.00 505.21 0.00e+00 -2.143063e-03 3.845237e-03 2.798249e-04 -6.000000e+00 4.571513e-03 284.46 -2.00 20.00 -2.00 499.81 0.00e+00 1.044367e+00 2.790410e+00 9.932421e-02 -6.000000e+00 3.252307e+00 228.76 -2.00 3.16 -2.00 501.52 0.00e+00 20.056 0.076 489.00 513.00 1 1.0088e+01 2.1497e-01 3.2376e-02 -6.0000e+00 2.4831e-01 1.2154e-01 5.5200e-02 2.6114e-03 -6.0000e+00 6.6301e-02 4.2521e-06 3.4079e-02 1.2803e-02 9.3436e-05 -6.0000e+00 1.6116e-02 4.9153e-02 -1.2420e-03 12 9 8 11 8 0 85.36 21.50 5.42 0.04915 0.28554 8 2 1 4 0 4000.000 25.58 19.85 21.50 900000 -8675 30010 -14972 20142 7247 13800 -4584 -5489 1509 15176 9948 -1291 2576 -9185 9157 -8286 -8794 1630 -17385 10174 4136 17949 -1898 5582 6864 -4002 -9732 -7851 18903 -6263 -7363 20474 10070 -15750 14724 5711 -3859 19074 -822 -9610 -33348 9283 42066 14500 6279 -10579 3984 1120 -12103 33979 10943 3774 3633 -1212 -883 -444 5757 3070 25311 9064 3063 -8172 14517 6284 534 14906 -9310 1546 16294 1336 -11981 7685 19526 1788 -6034 -18503 -17373 22811 -2803 15148 14526 -6950 -25556 4494 -4248 -15634 1187 33822 32379 11503 -12455 11295 -6006 -3389 11006 25479 -8150 289 -8463 -10798 9255 2844 5825 935 30629 15715 -4715 20352 4317 -14287 20074 -14598 23045 13091 17241 -13691 21466 -2669 12574 1753 -19491 21247 -24338 16172 -19318 29278 11950 2349 -16901 -5975 -7111 -16055 13747 -1322 18431 -4808 17518 -4311 -11388 38468 21352 60295 -9775 -5294 -12488 722 -14624 40418 33455 36588 22892 -20547 900000 -9854 23891 -19187 18577 7739 13934 -5564 -6662 1685 14586 9948 -1429 2726 -10968 9246 -10216 -11185 1899 -24642 10964 4738 17948 -2167 5917 7153 -4605 -11640 -8963 16100 -6810 -8207 17810 10037 -20693 14275 6002 -4406 17111 -894 -11408 -50463 9253 30494 13927 6543 -12941 4151 1178 -14148 24324 9618 3522 3424 -1230 -920 -471 5790 3171 20871 8788 3164 -9478 13417 6264 556 13237 -10376 1527 13731 1295 -13245 7033 16101 1783 -6507 -22299 -20307 17569 -2769 12491 12109 -7242 -30394 4276 -4186 -17398 1119 24517 23765 10423 -13543 9787 -6225 -3398 9349 18181 -7893 250 -7836 -10090 7076 2367 4899 865 21856 13216 -4847 16078 3961 -15778 15859 -16493 18011 11343 14353 -15585 17324 -2767 11216 1727 -23346 16606 -29565 13051 -22319 20892 10152 2195 -19095 -6040 -7248 -17731 11094 -1224 13935 -4615 13691 -4285 -12382 25816 17231 33293 -10961 -5711 -13678 736 -16252 27124 23588 24554 17502 -22999 SO 20171028T090555.0Z 6510.379109 338 1 31.99 2 88.94 105.38 126.82 200.74 0.00 1 0.00 1 0 15 9.810e-02 9.309e-02 1.042e-01 1.013e-01 -7.593602e+03 5.904502e+03 6.149552e+01 -6.000000e+00 5.397170e+03 284.47 -2.00 20.00 -2.00 505.24 0.00e+00 3.418214e-03 2.776022e-03 2.368544e-04 -6.000000e+00 2.728440e-03 284.47 -2.00 20.00 -2.00 499.93 0.00e+00 4.134761e+00 2.072722e+00 1.816027e-01 -6.000000e+00 1.921254e+00 228.76 -2.00 3.16 -2.00 501.59 0.00e+00 18.454 0.059 489.00 513.00 1 9.7345e+00 1.5861e-01 3.1379e-02 -6.0000e+00 1.4725e-01 9.4876e-02 4.1543e-02 3.1921e-03 -6.0000e+00 3.8395e-02 5.8947e-06 -3.6006e-03 9.5883e-03 9.9190e-05 -6.0000e+00 9.6494e-03 7.4171e-02 -3.0773e-04 12 8 8 10 0 0 98.44 21.50 -0.15 0.07417 0.04920 8 2 1 4 0 4000.000 25.58 19.82 21.50 -4116 -5795 3554 -1238 4565 7327 5585 -2985 7094 3872 -3331 5958 4565 4766 -7418 -198 -6207 16801 6520 -6817 2338 -19195 16400 -17123 12534 1913 8456 537 -8024 4988 -3347 4645 6923 -1029 -3422 2217 5109 2180 12699 10366 8074 7184 -3096 -81 -12949 -14876 3506 210 -6567 -2783 -6019 -10668 -6246 -8316 2620 3959 -2229 20935 410 10696 3783 -1205 -12936 14426 286 -3702 32080 -9357 9764 -15230 6997 -2421 10707 18404 -11017 -1432 2165 19213 -2636 2334 5513 6378 9140 -9705 11672 3305 -2384 -5361 15485 14778 393 -8673 -4362 3904 6334 -1609 13632 -209 17347 -4780 3128 -3939 -8789 7826 -7968 10840 -5155 25124 1472 -314 -8428 -4418 -3887 -9083 -4792 -2770 -182 11061 -12002 1598 13291 -13324 4777 -7587 6237 -14559 15679 -7031 -6306 5327 -1336 11061 -15623 1036 6191 10934 -4417 -298 -2824 11942 15341 -17696 -5120 8672 24700 10253 15228 6308 1465 26383 -13191 -1602 -10313 -4319 -6326 3653 -1378 4919 7843 6177 -3619 7745 4309 -3920 6294 4822 4966 -8677 -216 -7305 16080 7072 -7984 2506 -25530 15300 -22433 12275 2089 8617 586 -9344 4951 -3521 4487 6642 -1103 -3872 2405 5375 2337 12100 10014 7960 7178 -3463 -89 -16365 -19292 3781 232 -7647 -3056 -6651 -12000 -6571 -8859 2531 3877 -2389 18147 440 10333 3905 -1308 -15835 13459 306 -4090 24411 -10587 8980 -17736 6435 -2419 9351 14978 -12173 -1450 2106 15510 -2599 2162 4925 5655 7922 -9573 9963 2891 -2218 -5155 12103 11643 358 -8716 -4248 3560 5736 -1597 11669 -205 14097 -4744 2794 -3690 -8559 6505 -7908 9078 -5085 18079 1315 -281 -8104 -4111 -3665 -9241 -4785 -2766 -179 9812 -13401 1546 11295 -14547 4297 -7672 5494 -15895 12741 -7196 -6415 4825 -1293 9469 -17444 971 5415 8953 -4165 -269 -2663 9927 12561 -19217 -5241 7746 18846 9096 12942 5524 1334 19475 -13246 -1403 -9815 SO 20171028T090956.0Z 6510.381898 342 1 32.00 2 88.14 104.82 127.10 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