File name: Pandora114s1_BuenosAires_20171031_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T020235.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171031_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171031 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171031T085844.0Z 6513.374120 296 1 31.99 2 89.75 107.17 115.45 241.60 0.00 1 0.00 1 0 15 1.436e-01 1.352e-01 1.357e-01 1.278e-01 2.547423e+04 1.101568e+04 9.144729e+02 -6.000000e+00 7.901554e+03 284.62 -2.00 20.00 -2.00 505.21 0.00e+00 -1.905134e-03 3.581160e-03 2.133708e-04 -6.000000e+00 3.996974e-03 284.62 -2.00 20.00 -2.00 499.64 0.00e+00 1.923237e+00 2.665470e+00 3.000838e-01 -6.000000e+00 2.823800e+00 228.81 -2.00 3.16 -2.00 501.30 0.00e+00 20.058 0.076 489.00 513.00 1 9.9173e+00 2.0487e-01 3.8933e-02 -6.0000e+00 2.1622e-01 1.1365e-01 5.1500e-02 5.6435e-03 -6.0000e+00 5.6726e-02 4.6168e-06 -1.8941e-02 1.0061e-02 5.4272e-05 -6.0000e+00 1.4140e-02 1.4726e-01 -1.0874e-03 12 8 8 10 0 0 94.25 21.58 13.91 0.14726 0.01588 8 2 1 4 0 4000.000 25.68 19.81 21.58 -10125 -12857 -17664 -24087 10063 15444 4136 7582 15291 -13587 2409 5774 534 4805 18569 -9926 3236 4689 2402 14803 19168 8247 11590 -3975 14332 -3431 -8679 -30723 6344 7699 -11122 -1576 3757 1714 29551 16099 -10705 -1794 13201 -7419 12334 12438 11513 5541 319 -937 397 -3878 -3250 31374 2146 5902 -12977 8808 2197 -3003 7724 -5365 27880 3194 -1407 14404 -15172 14509 10536 13071 48313 -5582 -5093 5142 -8824 -18547 12164 10845 36538 -9650 6690 6748 -10580 -10528 -3861 8002 5515 -2427 -5196 -7379 4060 -12199 2745 13387 -19356 8899 -17332 10522 -2755 8379 12040 -2939 -887 -9356 4649 -7534 21383 8232 2106 -7364 4654 12319 2975 6490 6711 26323 1254 -2270 -5592 -2391 5436 -4418 3959 -8600 1274 -2801 -5926 5148 7713 30685 21638 -12501 -4755 -1856 -801 19744 16458 27871 35150 -1477 130 32607 12699 7979 -10812 18723 -40029 -20337 36592 -18778 34086 -1891 18779 982 -21307 13734 332 -11593 -15066 -22121 -33181 10172 15197 4662 8410 15867 -18838 2822 6457 621 5287 17607 -11602 3324 4815 2587 14460 18244 8814 11999 -4812 14478 -4154 -11086 -48736 6886 8099 -13742 -1724 3858 1817 24425 15726 -13942 -2142 13446 -9167 12357 12357 11535 5922 362 -1087 457 -4662 -3853 25932 2329 6012 -15493 8236 2165 -3134 7416 -6046 23044 3413 -1574 13709 -19380 13810 10467 12659 32672 -6385 -5698 5109 -9946 -22762 10866 9779 25625 -10876 6479 6535 -11262 -10960 -3687 6702 4706 -2242 -4962 -7277 3622 -12986 2536 11107 -22119 7592 -19128 8812 -2652 7215 9801 -2668 -750 -8202 3421 -6133 12887 5670 1583 -6398 3825 9932 2724 5791 5936 18956 1158 -2185 -5603 -2321 4851 -4323 3564 -8885 1217 -2828 -6169 4715 6701 20655 15751 -12818 -4540 -1729 -740 14836 12753 19197 22285 -1329 114 20673 9940 6683 -10513 14654 -53964 -22922 25204 -21441 23102 -1839 14802 919 -24644 11028 301 SO 20171031T090249.0Z 6513.376956 300 1 31.99 2 88.95 106.60 116.16 240.87 0.00 1 0.00 1 0 15 1.036e-01 9.717e-02 9.376e-02 9.045e-02 2.770661e+03 5.872282e+03 5.905207e+01 -6.000000e+00 5.705061e+03 284.62 -2.00 20.00 -2.00 505.25 0.00e+00 2.668976e-03 2.450891e-03 1.741193e-04 -6.000000e+00 2.881191e-03 284.62 -2.00 20.00 -2.00 499.88 0.00e+00 4.471401e+00 1.845347e+00 8.041359e-02 -6.000000e+00 2.020327e+00 228.81 -2.00 3.16 -2.00 501.52 0.00e+00 18.474 0.059 489.00 513.00 1 9.5793e+00 1.4162e-01 2.8694e-02 -6.0000e+00 1.5497e-01 7.3075e-02 3.6135e-02 1.9745e-03 -6.0000e+00 4.0185e-02 6.6188e-06 -2.7545e-03 8.4897e-03 6.1380e-05 -6.0000e+00 1.0163e-02 1.0247e-02 3.7414e-04 12 8 8 10 0 0 -409.60 21.58 5.41 0.01025 -0.00886 8 2 1 4 0 4000.000 25.68 19.93 21.58 13641 8878 2818 -11813 10696 -25 -9531 9547 -8342 3470 6555 6340 11878 -14930 24323 -8325 -444 -6497 5230 2814 3559 3650 122 7196 -14955 17851 -1444 -1734 -1529 8085 11842 -6659 6945 -14984 -6142 -6286 11362 118 10170 1406 9978 1448 -9813 -42 12681 -3264 4213 -6754 4097 18804 -6455 -6008 7454 6684 2376 -3259 2106 4703 6159 3624 611 -12525 541 -5196 -433 1659 9333 3361 -3880 14323 -10929 -9650 -7399 -8143 7055 2557 23585 -3895 -18246 -18368 -193 -7311 -6311 4627 12655 1006 28069 -2573 7105 -139 10031 -12681 4602 3450 2868 7193 -1762 -8034 -11076 19400 -9431 15007 -1662 5297 -4733 37 13568 -23037 15900 -12283 -6811 17010 -6886 27266 -4865 -1641 -5960 842 1396 9888 17663 17613 4928 -6231 15449 -16506 21759 4655 -3457 4208 16603 14572 11414 3707 -6192 -8413 -6211 -2062 4897 6982 -1430 5660 -6393 14552 5328 15758 -3755 245 -15427 -13155 6364 -12377 23343 12094 8489 2963 -14812 10974 -29 -12374 10279 -10672 3889 7016 6705 11734 -19098 20949 -10017 -503 -7488 5471 3044 3829 3927 136 7528 -19623 16882 -1647 -1958 -1681 7837 10849 -7361 6855 -19041 -7334 -7580 11416 132 10099 1513 9849 1566 -12007 -48 12667 -3840 4582 -8104 4335 16783 -7211 -6499 6918 6242 2359 -3525 2216 4893 6334 3813 661 -15473 589 -5988 -474 1755 8992 3377 -4128 12529 -12144 -10495 -7872 -8808 6631 2524 18680 -3983 -19816 -19746 -184 -7009 -6015 3974 10098 908 20738 -2424 6063 -127 8282 -13210 4080 3135 2638 6297 -1660 -7879 -10925 13760 -8728 10727 -1409 4286 -4379 34 10901 -26552 12246 -12388 -6491 12913 -6754 19339 -4825 -1592 -6076 807 1338 8712 14290 14054 4396 -6146 12242 -18110 16398 4179 -3372 3801 13248 11870 9551 3307 -6005 -8252 -5954 -1920 4342 6190 -1402 5238 -6335 12499 4751 12738 -3701 231 -16815 -13722 5344 -12394 16435 SO 20171031T090650.0Z 6513.379745 304 1 32.00 2 88.15 106.03 116.86 240.14 0.00 1 0.00 1 0 15 6.897e-02 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