File name: Pandora114s1_BuenosAires_20171110_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T021418.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171110_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171110T084956.0Z 6523.368009 280 1 32.00 2 89.75 110.90 52.83 12.76 0.00 1 0.00 1 0 15 1.755e-01 1.554e-01 1.417e-01 1.319e-01 7.228245e+03 9.630640e+03 2.258350e+02 -6.000000e+00 9.680784e+03 285.13 -2.00 20.00 -2.00 505.25 0.00e+00 5.291316e-04 3.684652e-03 1.613375e-04 -6.000000e+00 4.897803e-03 285.13 -2.00 20.00 -2.00 499.59 0.00e+00 -1.192825e+00 2.766111e+00 1.067571e-01 -6.000000e+00 3.460068e+00 228.96 -2.00 3.16 -2.00 501.34 0.00e+00 20.042 0.075 489.00 513.00 1 1.0179e+01 2.1311e-01 3.1914e-02 -6.0000e+00 2.6487e-01 2.2121e-01 5.4016e-02 2.4406e-03 -6.0000e+00 6.9670e-02 4.4351e-06 2.3732e-03 1.2092e-02 5.7510e-05 -6.0000e+00 1.7294e-02 -3.1042e-02 -1.9458e-04 12 8 8 10 0 0 92.40 22.23 12.15 -0.03104 -0.01458 8 2 1 4 0 4000.000 26.21 20.00 22.23 -19501 24217 -16718 8545 11170 -15024 4124 1927 1144 -28797 18808 7406 10214 -8210 -7706 24977 5130 14271 -3977 -24 6026 -5396 11763 -7509 20149 4105 -3080 5279 -9307 5725 -22540 -12121 7285 -17284 13141 1141 -2307 641 17098 449 24844 19832 5126 -7885 19560 33431 -15546 14390 -1058 4313 -1415 4993 36889 -16932 11493 -4130 -3538 -8067 13815 20621 -1539 21271 23584 33519 4832 3463 2257 -6527 17145 -15372 23995 15587 19248 -2774 -8020 33407 -11067 33765 4914 -6252 -16585 -40773 4315 57320 38387 -6917 40504 18390 -7327 54976 -9348 10374 8252 -2670 -2486 -8071 19415 4451 -1084 -8117 7928 32517 17137 30460 -7758 1611 -12179 28304 -1705 24356 2578 36919 5039 -21779 36452 -2248 -2765 6797 2987 -6095 -29884 4405 11626 5000 28890 6437 2082 -1969 -8584 -6355 30557 -7959 -18429 -8579 5634 -12065 -5451 10894 -556 5054 -615 -27609 14966 2409 22315 -11595 31853 3205 -212 2541 -17108 11500 -9200 -25029 20348 -21765 8915 11654 -20809 4798 2313 1383 -46531 18582 8069 10657 -10158 -9392 21909 5542 14363 -4920 -29 6899 -6925 12708 -9189 20093 4493 -3610 5641 -11309 5821 -29525 -14101 7031 -21896 12684 1269 -2664 713 15913 487 20982 17603 5301 -9378 17868 26793 -20364 13889 -1176 4460 -1512 4862 25432 -19699 10103 -4342 -3811 -9315 12977 18126 -1684 18515 20121 25997 4997 3612 2354 -7312 14923 -18281 19024 13298 15759 -2845 -8778 24471 -12684 24442 4659 -6520 -19009 -55672 4016 31614 25804 -7392 27227 15531 -8019 32217 -9743 9477 7752 -2653 -2491 -8542 15372 3992 -998 -7804 6341 19966 12184 19195 -7396 1458 -13087 20580 -1667 18103 2353 23862 4519 -25866 24444 -2234 -2770 6205 2847 -6402 -39838 4128 9957 4484 20073 5564 1884 -1861 -8669 -6264 20738 -7909 -20250 -8456 4734 -11892 -4976 8449 -490 4288 -561 -33459 11971 2199 16767 -12272 21874 2926 -199 2279 -17171 9013 -8255 SO 20171110T085400.0Z 6523.370833 284 1 32.00 2 88.97 110.33 52.65 11.59 0.00 1 0.00 1 0 32 1.010e-01 9.451e-02 9.510e-02 9.154e-02 -1.569394e+03 5.684507e+03 3.332548e+02 -6.000000e+00 5.574989e+03 285.13 -2.00 20.00 -2.00 505.27 0.00e+00 7.031162e-03 2.512813e-03 4.698331e-04 -6.000000e+00 2.815174e-03 285.13 -2.00 20.00 -2.00 499.84 0.00e+00 7.342993e+00 1.895788e+00 8.583744e-02 -6.000000e+00 1.977536e+00 228.96 -2.00 3.16 -2.00 501.49 0.00e+00 18.509 0.059 489.00 513.00 1 9.3288e+00 1.4538e-01 3.0609e-02 -6.0000e+00 1.5162e-01 2.3169e-02 3.7029e-02 1.8615e-03 -6.0000e+00 3.9488e-02 6.4883e-06 1.3035e-03 8.5169e-03 1.7557e-04 -6.0000e+00 9.9374e-03 4.2551e-02 -6.2858e-05 12 9 8 11 8 0 -36.26 22.22 -3.89 0.04255 0.05159 8 2 1 4 0 4000.000 26.21 20.00 22.22 4572 7505 13088 -5699 -6422 5011 5679 -8064 8098 1900 4886 -10464 5747 541 7552 8877 -1420 -4594 2850 3679 23891 598 13866 633 -735 1191 5242 -2566 -14098 817 -7876 177 110 -4247 -5739 -7351 19883 4186 -12066 -6105 -10901 3746 160 1098 -2864 19794 4363 2256 19481 1661 8859 -6506 -15623 -13754 16955 -1087 -3348 -7986 -3038 4868 -6067 4217 -14823 -3014 7428 -14279 3803 3667 8689 6530 17650 -2167 14217 8792 -236 4268 770 14393 3697 7766 11354 -9774 5242 -15548 4338 7989 10204 -10598 -17554 -102 -18114 16071 4207 -4568 -2080 -2963 -8234 -13531 18669 7400 -5770 21815 951 -3694 -1281 25488 -3888 3362 -15355 9638 22948 117 -828 12315 5133 -2942 -7995 -4494 -10677 -3276 7866 19516 -11149 2186 6220 2683 576 -9631 22294 2470 4546 -1745 9666 -1909 12317 20339 -386 -4806 -9019 7189 1656 -3352 -15982 -16508 20387 -2572 14369 20123 10471 -4005 -4666 -4217 16388 4395 7215 12331 -6684 -7779 5524 6297 -10285 8719 2144 5261 -12943 5967 586 7599 8875 -1601 -5477 3215 3873 22049 651 13271 697 -826 1318 5551 -2901 -17456 845 -8716 181 115 -4801 -6763 -8882 18197 4432 -14868 -7048 -13237 3966 178 1229 -3376 18708 4802 2510 17946 1788 8638 -7199 -18597 -16044 14807 -1170 -3785 -9603 -3490 5154 -7149 4490 -19152 -3461 7643 -18023 3936 3729 8264 6250 14887 -2203 12246 8046 -239 4136 764 12226 3428 6829 9576 -9537 4704 -16131 3698 6586 8240 -10520 -18606 -90 -19199 12167 3633 -4381 -1972 -2841 -8266 -14114 13820 5976 -5177 14559 779 -3211 -1113 17295 -3554 2828 -15327 7405 15443 100 -733 9807 4491 -2838 -8205 -4486 -11376 -3233 6881 14994 -11504 1961 5372 2422 536 -9992 16879 2285 4130 -1693 8348 -1831 10085 15170 -353 -4636 -9256 6411 1588 -3421 -17546 -18297 16692 -2512 12651 16702 8898 -3847 -4409 -3918 12456 SO 20171110T085802.0Z 6523.373634 288 1 31.99 2 88.19 109.76 52.49 10.42 0.00 1 0.00 1 0 22 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