File name: Pandora114s1_BuenosAires_20171111_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022128.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171111_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171111T084910.0Z 6524.367477 292 1 32.00 2 89.76 111.25 53.75 29.14 0.00 1 0.00 1 0 22 1.453e-01 1.318e-01 1.118e-01 1.065e-01 1.585713e+04 7.882999e+03 8.707208e+02 -6.000000e+00 8.016103e+03 285.18 -2.00 20.00 -2.00 505.22 0.00e+00 -5.736028e-03 2.899534e-03 3.171219e-04 -6.000000e+00 4.054942e-03 285.18 -2.00 20.00 -2.00 499.87 0.00e+00 -1.347252e+00 2.115957e+00 8.094364e-02 -6.000000e+00 2.864652e+00 228.97 -2.00 3.16 -2.00 501.54 0.00e+00 20.046 0.075 489.00 513.00 1 1.0050e+01 1.6139e-01 3.2245e-02 -6.0000e+00 2.1929e-01 1.6482e-01 4.1976e-02 2.4572e-03 -6.0000e+00 5.7696e-02 5.5445e-06 1.4213e-02 8.8801e-03 1.3026e-04 -6.0000e+00 1.4328e-02 9.5072e-02 -9.6120e-04 12 8 8 10 0 0 97.89 21.72 0.01 0.09507 0.19366 8 2 1 4 0 4000.000 25.79 19.83 21.72 -2189 7935 -19418 -1909 17741 3119 14305 -794 7326 -11326 -1019 9365 -8474 6577 -9481 2626 -7319 21695 -4019 -5289 12094 -1390 14227 -76 18636 -11462 4318 27620 -17277 28328 -17286 11780 -4260 6895 12861 6219 9580 -23761 15394 -86 16710 5979 -8057 5857 -18890 10642 -4274 23001 9038 2436 3694 -13180 39782 -17052 8876 -15144 -1267 2872 -13122 9207 -4567 7004 24388 -2468 8037 -6313 31523 -6126 20767 4700 2320 16723 1733 13751 -14211 2685 -16510 3728 -12240 98 24038 -1408 14752 6554 2299 -8015 -13381 -6658 -5307 27956 -20877 17373 50 -3974 30538 1227 39743 -11914 9064 -18185 9640 -5110 -7661 6310 -6078 6212 -463 -3859 -820 -2143 12151 -7747 28073 -5672 12196 2556 34534 4921 -3632 18024 -17111 14972 -18202 30157 24242 661 30647 -9503 891 -16637 10339 -7010 -19461 24276 1555 -4840 5008 19587 -15540 4089 14711 6602 5147 -9706 -1014 -15967 29555 13885 -18169 23730 -10161 10385 8221 -2268 7630 -25329 -2149 16794 3487 14501 -942 7973 -14690 -1178 9634 -10296 6814 -11519 2857 -8401 20538 -4697 -6329 12200 -1605 14055 -87 17632 -14593 4656 23250 -22237 22467 -21285 10899 -4741 7099 12795 6663 9864 -33722 14565 -94 15345 6115 -9528 6072 -25232 10588 -4906 19842 8803 2474 3598 -14762 25739 -19455 7966 -17805 -1331 2937 -15793 8839 -5020 6870 20190 -2679 7828 -7027 23685 -6606 16903 4447 2227 13845 1675 11958 -16610 2671 -18521 3579 -12693 94 18228 -1295 12418 5685 2114 -8311 -14837 -6947 -5469 20604 -25054 14277 50 -4096 22109 1160 24625 -11889 7094 -18265 7230 -4433 -6945 5185 -5986 5712 -472 -4102 -840 -2194 10699 -8337 21239 -6030 10818 2484 24325 4686 -3813 15400 -20758 12987 -21487 21439 18024 621 21388 -9917 837 -18555 8766 -7041 -20667 17417 1379 -4546 4279 14691 -16927 3734 12282 6071 4868 -10128 -977 -17936 22360 11507 -20522 17334 -10229 8415 6812 SO 20171111T085314.0Z 6524.370301 296 1 32.00 2 88.97 110.67 53.35 28.05 0.00 1 0.00 1 0 15 1.036e-01 9.377e-02 8.021e-02 7.781e-02 -2.939730e+03 4.591558e+03 2.067790e+02 -6.000000e+00 5.716627e+03 285.18 -2.00 20.00 -2.00 505.25 0.00e+00 9.252095e-05 2.123140e-03 2.360645e-05 -6.000000e+00 2.887079e-03 285.18 -2.00 20.00 -2.00 499.95 0.00e+00 4.295445e+00 1.569742e+00 2.599400e-02 -6.000000e+00 2.030416e+00 228.97 -2.00 3.16 -2.00 501.62 0.00e+00 18.522 0.059 489.00 513.00 1 9.4853e+00 1.2021e-01 2.7909e-02 -6.0000e+00 1.5564e-01 6.6775e-02 3.1272e-02 1.6393e-03 -6.0000e+00 4.0600e-02 7.6876e-06 3.1532e-03 7.4610e-03 2.4497e-05 -6.0000e+00 1.0189e-02 -2.1838e-02 2.3425e-04 12 8 8 10 0 0 -235.17 21.71 -1.38 -0.02184 0.00003 8 2 1 4 0 4000.000 25.79 20.00 21.71 -88 8750 -947 569 15354 -5306 2708 -4614 -1852 -733 10933 -9420 -4699 10713 -7841 6814 13110 -2021 705 -2273 -3288 -2280 18118 -8175 -2625 -7775 -2284 46095 -6266 8168 -10303 -5176 3761 -6519 6876 -4030 12957 -1232 2594 5534 -8155 6617 -8670 28342 -13303 3462 -2830 1492 6038 3760 2944 -10068 -6460 -4890 1287 -2855 -6283 -3336 -2485 11131 -3980 5213 6531 12927 8280 3118 11995 -17104 3935 544 832 1021 -15011 14420 -2826 1885 12081 16252 6212 -6078 14911 -7631 -4474 -13956 -6029 8026 2181 10860 -8235 240 9135 2238 6040 2752 13421 -6238 15146 -10123 -10222 1773 15595 5093 4135 18088 -8956 19846 -8881 -5576 4882 -3900 13040 -8913 13188 -7678 1251 -2329 -5688 12113 -13767 5086 -6015 -358 6506 -3946 11659 -13511 17474 -18572 -2465 12011 -8637 28429 -10665 11740 426 1638 -6428 12645 -7254 -3555 19430 -6420 13568 -4724 -10656 17621 -6753 23226 -4476 13132 -8565 7149 650 -88 8198 -1011 617 14721 -6388 3054 -5631 -2189 -846 11078 -11546 -5427 10504 -8611 6978 12855 -2209 767 -2577 -3778 -2597 16857 -9934 -3030 -9448 -2613 32107 -7200 7890 -11733 -5605 3805 -7557 7166 -4733 12780 -1385 2769 5683 -9577 6728 -10359 23632 -16977 3749 -3252 1623 6170 3842 2949 -11160 -6766 -5022 1263 -3005 -7028 -3680 -2729 10640 -4411 5274 6542 12159 8125 3187 11039 -20697 3802 536 808 982 -16943 12243 -2888 1849 10626 13469 5590 -5736 12130 -7311 -4180 -14435 -5805 6772 1965 9007 -8283 222 7751 2049 5384 2571 11387 -6452 12561 -10663 -10573 1589 11893 4249 3489 13536 -9050 15419 -9271 -5581 4328 -3717 10442 -8964 10812 -7905 1198 -2343 -5965 10681 -15749 4800 -6279 -348 5830 -3893 9837 -14747 14076 -21511 -2432 10248 -8524 20597 -10717 9905 396 1483 -6281 10307 -6932 -3349 15744 -6423 11899 -4705 -11329 14229 -6998 17817 -4478 10781 -8530 5997 583 SO 20171111T085716.0Z 6524.373102 300 1 32.00 2 88.19 110.11 52.96 26.96 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