File name: Pandora114s1_BuenosAires_20171112_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022324.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171112_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171112T084826.0Z 6525.366968 302 1 32.00 2 89.76 111.59 56.66 44.36 0.00 1 0.00 1 0 92 1.366e-01 1.219e-01 1.242e-01 1.182e-01 -8.919276e+03 6.996447e+03 4.193814e+02 -6.000000e+00 7.535645e+03 285.23 -2.00 20.00 -2.00 505.22 0.00e+00 7.318475e-03 3.268224e-03 1.324670e-04 -6.000000e+00 3.810520e-03 285.23 -2.00 20.00 -2.00 499.71 0.00e+00 5.148217e+00 2.412654e+00 6.972668e-02 -6.000000e+00 2.689871e+00 228.99 -2.00 3.16 -2.00 501.43 0.00e+00 20.049 0.075 489.00 513.00 1 9.5380e+00 1.8641e-01 3.1204e-02 -6.0000e+00 2.0596e-01 1.0805e-01 4.6872e-02 1.8461e-03 -6.0000e+00 5.4109e-02 4.9726e-06 3.7238e-02 1.0692e-02 8.3767e-05 -6.0000e+00 1.3459e-02 8.2581e-02 -7.9039e-04 12 8 8 10 0 0 83.66 21.66 8.66 0.08258 0.34088 8 2 1 4 0 4000.000 25.68 20.15 21.66 -4439 -10233 3687 -21482 11867 12429 24432 8239 1222 8636 -14231 7470 -3290 -6803 -552 -674 5875 12525 -5468 9596 -559 -1436 -5 1195 -11429 -25580 -8583 -10263 34382 6617 12071 -8259 -2435 31505 -1519 38366 462 7770 -6770 -3398 -11396 -3436 7093 21366 6004 -3613 24643 -845 -4747 11377 -11221 2430 2594 -3788 21436 14965 19179 26182 18068 3250 9540 -5206 -2056 -4339 -11778 -12332 -12754 -8214 2061 -3864 -670 -10625 32274 -1681 26480 1008 660 -751 8720 -3826 15305 10985 6742 21784 -1140 -15834 -5113 12219 6075 18367 3549 2944 -4876 -19218 -4390 -3544 16139 4901 -12729 -5344 22025 4330 583 20641 13156 516 26284 -6747 -16528 2387 28740 25103 -14251 5956 -2993 -10458 3118 -1377 -513 -7273 -8564 -14027 8926 -3834 2412 40788 12288 -4204 7446 10994 -3922 15469 9466 -9748 -10557 648 -22582 -2458 -5782 11970 -11665 9204 30360 -15638 -3419 8242 5829 -3926 -1497 39062 15146 -18402 3551 -5034 -12703 4089 -31291 12572 13167 22850 8933 1396 9006 -18374 7666 -3730 -7996 -617 -770 6418 12957 -6789 10245 -662 -1608 -6 1320 -14302 -36555 -10144 -11971 24965 6286 11003 -9506 -2728 25553 -1713 28747 500 7742 -7792 -3806 -13996 -3955 7451 19640 6446 -4242 21510 -933 -5317 10546 -12742 2384 2564 -4096 18546 14103 17482 22247 16608 3465 9580 -6072 -2319 -4960 -14284 -14765 -15073 -9136 2037 -3999 -667 -11737 23434 -1727 20455 989 637 -725 7612 -3783 12532 9419 6041 16827 -1040 -16742 -4851 10382 5147 14755 3135 2665 -4873 -22545 -4482 -3594 13324 4437 -13366 -5070 15631 3669 520 15247 10480 459 17702 -6205 -16637 2005 18939 17634 -15274 5349 -2992 -11360 2958 -1356 -494 -7374 -8683 -14933 7563 -3720 2219 25698 10323 -4170 6579 9395 -3891 12547 8020 -9813 -10550 578 -25675 -2332 -5778 10142 -12586 8065 21547 -17666 -3442 7401 5319 -3639 -1316 23761 11627 -18814 2977 SO 20171112T085230.0Z 6525.369792 306 1 32.00 2 88.98 111.01 56.08 43.41 0.00 1 0.00 1 0 15 1.028e-01 9.572e-02 8.776e-02 8.507e-02 2.335675e+03 5.409729e+03 2.486226e+02 -6.000000e+00 5.677835e+03 285.23 -2.00 20.00 -2.00 505.25 0.00e+00 1.493122e-03 2.355114e-03 8.545970e-05 -6.000000e+00 2.864585e-03 285.23 -2.00 20.00 -2.00 499.98 0.00e+00 3.155877e+00 1.720542e+00 1.085427e-01 -6.000000e+00 2.003558e+00 228.99 -2.00 3.16 -2.00 501.64 0.00e+00 18.532 0.060 489.00 513.00 1 9.6283e+00 1.3269e-01 2.9043e-02 -6.0000e+00 1.5376e-01 8.5303e-02 3.3460e-02 2.1501e-03 -6.0000e+00 3.9796e-02 7.0237e-06 3.6130e-03 7.9707e-03 5.3285e-05 -6.0000e+00 1.0082e-02 -1.7651e-01 1.5981e-03 12 8 8 10 0 0 -154.92 21.66 6.18 -0.17651 -0.15144 8 2 1 4 0 4000.000 25.79 20.11 21.66 7104 7046 -13517 -4208 -6427 -2555 -463 9241 -13587 1499 -8584 -9945 8648 969 7215 1008 8270 6306 2230 9321 -4442 10117 -2107 2898 1720 -4342 -6975 17979 2152 -5362 -6094 1736 -3382 -6462 -2414 2902 -3866 4467 -1814 9885 5023 -8348 9017 11275 8255 1653 1025 3262 7274 4240 -9071 -2303 -2017 -7352 20396 -10931 4044 8991 15437 -4854 5918 1938 9877 13289 -8418 7253 -6103 9122 -3428 -7833 24874 -16376 8376 -18427 18281 5362 -502 3822 -9392 19477 -15916 26233 7746 -2147 -727 -7983 -5378 173 4608 -5019 -2596 12221 4574 8625 -11360 3194 -18931 9710 -1129 12023 -7113 5518 8784 -4577 -4345 2481 7003 27594 -5512 10286 -6191 -4860 1754 19006 9037 -2816 17682 -3176 793 -9529 -6280 18780 -13192 -189 -13882 8598 548 11699 2416 9193 9784 -3804 35345 -8308 17804 -3084 -3733 -5817 11084 -8832 -8312 16156 -21023 4718 21106 -19351 10885 6236 -3896 -10147 10047 5471 -5925 6685 6840 -16665 -4862 -7771 -3028 -543 9852 -18046 1687 -10532 -12202 8704 1045 7305 1025 7999 6380 2393 9378 -5136 10123 -2390 3142 1893 -5068 -8298 16390 2237 -5842 -6606 1756 -3704 -7543 -2764 3162 -4471 4693 -2007 9671 5166 -9885 9073 11219 8535 1828 1134 3482 7318 4290 -10185 -2356 -2030 -7846 16893 -12760 4158 8896 14330 -5505 6020 2057 9718 12633 -9874 7177 -6785 8569 -3601 -8491 19220 -19025 7636 -20839 15446 5157 -473 3612 -9349 15375 -16755 19395 6499 -2002 -675 -8030 -5298 162 4107 -4918 -2490 10191 4171 7641 -12314 2963 -21507 8096 -1024 9336 -6561 4458 6958 -4269 -4189 2288 6204 19701 -5401 8523 -6065 -4761 1636 15155 8053 -2847 14652 -3261 785 -10429 -6578 15072 -14369 -179 -15120 7528 522 9999 2267 8049 8515 -3564 23578 -7946 13732 -2909 -3560 -5421 9474 -8837 -8398 13724 -24541 4281 16357 -22589 9397 5598 -3803 -10302 8180 4643 -5697 SO 20171112T085632.0Z 6525.372593 310 1 32.00 2 88.20 110.45 55.52 42.45 0.00 1 0.00 1 0 15 6.306e-02 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