File name: Pandora114s1_BuenosAires_20171123_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022313.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171123_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171123T084222.0Z 6536.362755 349 1 32.00 2 89.76 114.87 124.07 158.71 0.00 1 0.00 1 0 10 2.562e-01 2.129e-01 2.186e-01 1.927e-01 -1.382062e+03 1.165096e+04 1.246828e+03 -6.000000e+00 1.416839e+04 285.79 -2.00 20.00 -2.00 505.35 0.00e+00 -7.237016e-03 5.161570e-03 4.489370e-04 -6.000000e+00 7.170203e-03 285.79 -2.00 20.00 -2.00 499.82 0.00e+00 4.654234e+00 3.868257e+00 2.768864e-01 -6.000000e+00 5.062700e+00 229.21 -2.00 3.16 -2.00 501.57 0.00e+00 20.037 0.075 489.00 513.00 1 1.0243e+01 2.9495e-01 3.7792e-02 -6.0000e+00 3.8740e-01 5.0886e-02 7.7201e-02 3.6431e-03 -6.0000e+00 1.0227e-01 2.9600e-06 2.9916e-04 1.8021e-02 1.9793e-04 -6.0000e+00 2.5192e-02 -9.3976e-03 -5.7234e-04 12 8 8 10 0 0 97.49 22.23 12.23 -0.00940 -0.00732 8 2 1 4 0 4000.000 26.21 20.00 22.23 16191 -9834 35083 -2832 -12697 -17531 6316 33944 5317 -2838 -11172 39928 -22184 -14248 44363 36939 6576 51338 28596 9584 -21820 -12989 -28581 -14559 19803 1864 30723 -13418 27382 -13836 28485 9598 28161 24180 -14006 9262 274 7731 13794 3944 9758 11434 11165 -15119 17136 540 20401 14470 -7835 272 -4415 -5103 -4690 32263 24606 -6524 -21439 30 -3158 34869 45196 -1350 -8371 54677 -30856 -3909 -26773 41944 13878 6803 58517 14531 24982 -24575 -13719 -14434 35774 -15052 8088 3454 6476 54891 -4257 58559 38291 45445 46775 10907 17591 461 12816 35237 -13085 19092 20025 4248 6344 23332 -6431 21018 47548 54282 -26868 1976 693 -470 17729 21029 -20161 38534 4145 -19520 -21422 5362 9166 28988 45127 -11953 2965 -51133 -335 22446 11333 30558 15680 -8765 -5027 26552 -6718 4000 110 14362 17267 -26795 9157 -15110 -2472 55996 23434 78948 -5073 -555 57387 24333 14228 -20545 53456 7009 -18568 -27979 22789 13839 39319 13545 -10749 25090 -3058 -15592 -23183 6733 27940 5884 -3409 -14472 30711 -31431 -18457 31728 28412 6922 35330 25468 10605 -33566 -18404 -47438 -21021 20309 2289 28191 -17744 25495 -17774 24984 9973 24320 22187 -18169 9798 321 8373 13898 4321 9955 11376 11109 -19613 16187 605 18756 14033 -9375 295 -4893 -5527 -4903 22755 18594 -6819 -26731 31 -3421 25910 30168 -1429 -9489 33054 -43914 -4233 -36079 27998 12060 6255 31690 12079 18563 -30022 -15205 -16361 24780 -17251 7232 3175 5709 29727 -4182 30976 25077 28045 28866 9753 14844 464 11460 25296 -15326 16351 17150 4280 6232 19100 -6966 16941 28744 30081 -31089 1727 630 -450 14653 17132 -24757 25934 3866 -22817 -25547 4938 8225 21563 28772 -13549 2906 -86335 -340 18022 10036 22009 12959 -9211 -5105 19751 -6980 3731 107 12040 14068 -33852 8001 -16592 -2365 29752 17431 34490 -5271 -563 33201 19824 12936 -26683 33452 7034 -24115 -39642 19104 12418 26926 SO 20171123T084627.0Z 6536.365590 353 1 32.00 2 89.00 114.29 123.77 157.66 0.00 1 0.00 1 0 15 1.876e-01 1.565e-01 1.609e-01 1.489e-01 -1.076812e+03 9.264540e+03 4.716163e+02 -6.000000e+00 1.038093e+04 285.79 -2.00 20.00 -2.00 505.34 0.00e+00 -3.489130e-03 4.214232e-03 1.844854e-04 -6.000000e+00 5.233846e-03 285.79 -2.00 20.00 -2.00 499.78 0.00e+00 4.051509e+00 3.107016e+00 1.110482e-01 -6.000000e+00 3.657826e+00 229.21 -2.00 3.16 -2.00 501.53 0.00e+00 18.564 0.060 489.00 513.00 1 1.0202e+01 2.4185e-01 2.9346e-02 -6.0000e+00 2.8072e-01 9.1746e-02 6.0861e-02 2.0179e-03 -6.0000e+00 7.2733e-02 3.9023e-06 -1.5083e-02 1.4528e-02 8.2638e-05 -6.0000e+00 1.8401e-02 -5.6474e-02 8.0658e-04 12 9 8 11 8 0 4.35 22.23 19.89 -0.05647 -0.16110 8 2 1 4 0 4000.000 26.21 20.00 22.23 -12459 13300 -2603 19439 2470 -2457 34957 -4319 16298 -19231 -2351 776 -459 8838 -13440 24369 -1937 11798 18652 -25911 10729 -18030 4708 -14279 40480 -26223 -1201 23203 -12364 17916 8020 8673 -12040 -1823 27097 -18828 1490 38277 28629 11510 19665 -1728 -4063 12961 2496 16240 22402 -9577 3296 -11512 28025 -8003 37907 -4358 7977 -9389 5686 13063 -7579 308 28312 9153 -7463 738 37110 -46 16844 -3112 9109 -12457 -3682 11866 -18827 14136 -12791 -1398 -2141 -13414 2681 6374 -3876 -1948 610 -17506 11000 2289 -12817 22153 18972 59753 -23539 16252 -869 -5412 17886 -3268 64390 29272 -4655 25031 2757 -1241 -21648 24171 2486 18230 13913 4022 48564 4231 74196 -4366 22433 -16317 3140 -1545 -17195 -12691 -5519 7817 -8499 7195 5665 -17600 -4380 8728 32066 3304 -4442 -13482 12534 4980 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-29286 3647 4156 18100 -6546 SO 20171123T085036.0Z 6536.368472 357 1 31.99 2 88.22 113.71 123.46 156.59 0.00 1 0.00 1 0 43 1.204e-01 1.122e-01 1.250e-01 1.205e-01 2.292749e+03 7.532514e+03 9.925241e+01 -6.000000e+00 6.661524e+03 285.79 -2.00 20.00 -2.00 505.24 0.00e+00 2.381684e-03 3.304541e-03 1.689648e-04 -6.000000e+00 3.360236e-03 285.79 -2.00 20.00 -2.00 500.00 0.00e+00 2.285154e+00 2.422443e+00 5.994810e-02 -6.000000e+00 2.353740e+00 229.21 -2.00 3.16 -2.00 501.66 0.00e+00 16.567 0.043 489.00 513.00 1 1.0324e+01 1.8631e-01 2.5168e-02 -6.0000e+00 1.8055e-01 9.3424e-02 4.8333e-02 1.5851e-03 -6.0000e+00 4.6935e-02 4.8657e-06 -6.4560e-03 1.1575e-02 6.4553e-05 -6.0000e+00 1.1837e-02 -2.1541e-02 4.1781e-04 12 8 8 10 0 0 20.46 22.22 3.66 -0.02154 -0.06632 8 2 1 4 0 4000.000 26.21 20.00 22.22 9905 -9763 8899 6957 -6557 10885 815 14066 11343 2346 1516 30821 -5830 13867 -11959 -10335 -14397 717 -3544 -15427 9469 1148 19632 9987 2124 17300 -2949 26733 -12612 6143 -7141 -22000 -1180 11516 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