File name: Pandora114s1_BuenosAires_20171125_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022416.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171125_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171125T084140.0Z 6538.362268 348 1 31.99 2 89.76 115.37 130.59 185.22 0.00 1 0.00 1 0 36 1.466e-01 1.338e-01 1.435e-01 1.368e-01 1.194030e+04 1.010267e+04 1.298575e+03 -6.000000e+00 8.113693e+03 285.89 -2.00 20.00 -2.00 505.24 0.00e+00 5.101688e-03 3.754483e-03 1.240888e-04 -6.000000e+00 4.095539e-03 285.89 -2.00 20.00 -2.00 499.91 0.00e+00 -1.665391e-01 2.804720e+00 8.034902e-02 -6.000000e+00 2.879914e+00 229.25 -2.00 3.16 -2.00 501.56 0.00e+00 20.031 0.075 489.00 513.00 1 1.0083e+01 2.1536e-01 3.1584e-02 -6.0000e+00 2.2071e-01 1.7019e-01 5.5742e-02 2.8450e-03 -6.0000e+00 5.7728e-02 4.2595e-06 -1.4013e-02 1.2782e-02 8.6625e-05 -6.0000e+00 1.4447e-02 -4.9238e-02 2.4166e-04 12 9 8 11 8 0 36.84 21.68 5.43 -0.04924 -0.14644 8 2 1 4 0 4000.000 25.79 20.18 21.68 -7988 -3461 15594 1193 12750 22346 6117 -4861 -5942 -1816 -16034 -3457 31844 -5804 25609 16169 -22068 14659 1001 11151 -4119 35413 879 -2293 -9609 -29829 6559 5344 -14515 13035 19050 -11713 11900 7654 -5007 13813 1890 11291 -14762 15733 4683 -2221 -9499 3001 57226 757 1572 -14791 13931 11605 -9496 17765 6268 24892 16575 17975 2461 -6231 1474 -10215 22589 2232 -7080 -1116 1692 11933 -3275 9664 -6376 10208 1665 -5524 -1410 -4993 -3393 3952 -17698 1693 -7551 5392 11821 -17161 15053 -23829 15802 -18171 817 -1989 845 -3019 14183 -10112 15881 -497 9167 22117 12889 26729 37412 -8966 -6281 -3736 -357 1581 -10935 12741 -22485 11393 -11902 15676 -10439 -7562 22521 7332 -1213 4286 13385 2537 15351 18356 3218 14236 -3899 44120 -5402 8737 -2457 9252 -8162 3304 -1195 -9831 2847 4147 12587 -20015 -26484 -7927 -19430 4518 -15266 21040 -267 27734 28388 12901 14128 4651 -7721 -2278 11485 -15432 21576 -8797 -3646 13888 1268 12454 20329 6678 -6005 -7454 -2173 -21803 -4072 25921 -6781 21581 14865 -29797 13898 1112 11426 -4970 28826 1010 -2723 -11508 -43991 6741 5541 -18163 12116 16175 -13191 10530 7183 -5505 12964 2027 11001 -18472 14343 4730 -2402 -11122 3139 35292 832 1728 -19169 13447 11306 -11203 15561 5994 19356 13926 15102 2485 -7073 1581 -12418 19786 2394 -8353 -1247 1845 11732 -3718 9501 -7237 9671 1697 -5974 -1450 -5310 -3578 3920 -21988 1725 -8301 5109 10355 -19940 12647 -29605 13276 -21601 810 -2045 846 -3130 12297 -10422 13484 -470 8521 18187 10800 20307 24744 -8565 -5685 -3225 -293 1271 -10171 9715 -25435 9451 -12566 12479 -10672 -7477 16607 6389 -1169 3951 11328 2402 12863 15073 3101 12287 -3986 27358 -5387 7468 -2347 7908 -8343 3018 -1141 -10215 2600 3718 10231 -22138 -30846 -7639 -21165 3937 -16501 16043 -255 20218 20695 11027 11956 4325 -8087 -2233 9624 -15579 15729 SO 20171125T084544.0Z 6538.365093 352 1 32.01 2 89.00 114.80 130.66 183.99 0.00 1 0.00 1 0 15 9.879e-02 9.528e-02 1.114e-01 1.077e-01 1.019290e+03 6.738657e+03 5.736671e+01 -6.000000e+00 5.467070e+03 285.89 -2.00 20.00 -2.00 505.32 0.00e+00 -2.847266e-03 2.962271e-03 2.123655e-04 -6.000000e+00 2.757287e-03 285.89 -2.00 20.00 -2.00 499.86 0.00e+00 4.774380e+00 2.194378e+00 3.654762e-02 -6.000000e+00 1.930882e+00 229.25 -2.00 3.16 -2.00 501.57 0.00e+00 18.571 0.060 489.00 513.00 1 9.8197e+00 1.6883e-01 2.8465e-02 -6.0000e+00 1.4812e-01 5.8699e-02 4.2861e-02 1.5863e-03 -6.0000e+00 3.8504e-02 5.4702e-06 -1.4507e-03 9.9887e-03 7.8585e-05 -6.0000e+00 9.7101e-03 -6.8179e-03 3.2763e-04 12 8 8 10 0 0 92.37 21.69 10.50 -0.00682 -0.01688 8 2 1 4 0 4000.000 25.79 19.93 21.69 -5754 15601 -5446 -7032 -549 3673 -17315 8086 -2742 8243 2806 -9343 11207 -8304 4871 117 -3121 970 6057 9398 5803 -415 -19843 1253 14867 -1069 6578 -2897 7174 -17307 2309 13286 -910 -6946 10574 -5993 -5272 14988 9358 10343 -4058 -12825 3643 10604 -1218 15863 13201 -4563 5953 -8714 -693 11706 -1757 25280 599 4828 12690 -7778 -414 3284 2186 -4469 -11647 18792 -669 5121 -5380 -5149 -14349 17747 10639 1227 2807 -1365 -8964 2868 -7644 -1849 1415 3288 -1711 6267 3756 -7204 9515 18174 7491 -5832 -26 15536 6873 9735 -4624 5632 -12722 7782 -3825 5694 1818 4086 -2645 4045 647 20318 -13008 555 17605 -15736 15913 3344 -18781 17579 2209 1448 -209 16328 6812 -12027 19441 -2660 22158 16610 -10753 -11918 -9075 9966 -5446 -9138 -9097 3886 4540 -1873 20292 -2611 -13434 12339 -2509 -8245 -2595 17186 -5616 -12173 3590 8576 -3458 15329 -15132 -238 3390 15212 4876 -5987 -1815 -6073 13644 -6076 -8218 -616 4043 -23889 8718 -3287 8762 3110 -11552 11153 -9954 5104 130 -3647 1119 6803 10345 6650 -473 -27506 1410 14645 -1234 6989 -3343 7320 -21920 2356 12154 -980 -8211 10789 -7295 -6344 14554 9482 10262 -4626 -15973 3871 10595 -1380 15180 12911 -5266 6073 -10056 -717 10379 -1743 19033 585 4654 11608 -8867 -440 3350 2245 -4906 -13768 16397 -707 5045 -5792 -5435 -16357 14485 9207 1157 2607 -1335 -9587 2744 -8068 -1808 1314 2962 -1613 5468 3383 -6843 8235 14578 6325 -5655 -24 12196 5894 8156 -4514 5015 -13679 6776 -3684 4883 1583 3396 -2303 3255 542 14341 -13300 513 13936 -17336 12597 2956 -20566 13451 1997 1338 -199 13248 6111 -13090 15518 -2649 17102 13368 -11208 -12422 -9159 8349 -5353 -9343 -9301 3486 4043 -1779 15394 -2463 -13913 9768 -2301 -8104 -2465 13718 -5743 -13491 3434 7864 -3605 13348 -16911 -229 3115 12184 4238 -5724 -1667 SO 20171125T084946.0Z 6538.367894 356 1 32.00 2 88.24 114.23 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