File name: Pandora114s1_BuenosAires_20171208_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022534.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171208_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171208T084006.0Z 6551.361181 245 1 32.00 2 89.77 117.82 50.18 353.98 0.00 1 0.00 1 0 39 1.649e-01 1.445e-01 1.407e-01 1.317e-01 3.960125e+03 9.126722e+03 6.529529e+02 -6.000000e+00 9.149416e+03 286.55 -2.00 20.00 -2.00 505.23 0.00e+00 6.609776e-03 3.668858e-03 3.549215e-04 -6.000000e+00 4.616567e-03 286.55 -2.00 20.00 -2.00 499.81 0.00e+00 4.317465e+00 2.715694e+00 6.982640e-02 -6.000000e+00 3.245479e+00 229.55 -2.00 3.16 -2.00 501.48 0.00e+00 20.028 0.075 489.00 513.00 1 9.7054e+00 2.1011e-01 3.2038e-02 -6.0000e+00 2.4869e-01 8.7624e-02 5.2076e-02 1.7734e-03 -6.0000e+00 6.5197e-02 4.4048e-06 2.1580e-02 1.2572e-02 1.3995e-04 -6.0000e+00 1.6258e-02 -4.6799e-02 8.4688e-05 12 9 8 11 8 0 -170.51 22.75 22.78 -0.04680 0.10289 8 2 1 4 0 4000.000 26.62 20.00 22.75 7169 -3741 22905 2202 5173 -10259 796 -6477 -16970 21173 507 21175 -8521 8544 -13588 -18717 41004 -4911 20354 6190 14085 -5454 -318 3612 -5138 -1561 -133 8556 17581 7415 -3614 6431 18902 -22389 20706 -3034 6270 -5926 -7478 6780 -16697 13094 -15966 15978 5889 2122 20901 -9492 7776 -11118 21065 4625 16056 44651 870 -5648 -19557 7513 11758 11555 19786 544 15851 -15125 34596 -21472 1945 3614 -19806 -16344 -17555 -898 4810 24417 16899 37271 13762 15750 15272 -10872 23957 10311 -11502 -6228 -15234 30397 -970 9699 5315 -21281 19106 4223 11417 -12907 852 22826 8508 18314 -16516 -1875 -5800 65559 -6288 5033 -12350 -8021 685 8029 14928 29350 19692 -12117 -11615 22156 -18106 649 -5929 8256 20101 -4362 -10197 -3065 -9258 -9884 22748 -6251 4603 17316 -8187 22711 -14863 -22096 13454 28908 20759 26869 30990 -10664 15056 8225 2550 6934 23656 14299 -7701 -5059 -10369 19902 -18177 13681 -20149 -9917 22346 6877 -4140 20071 2437 5678 -13342 933 -8125 -23322 19529 566 18945 -10139 8511 -16919 -24860 30635 -5935 19338 6794 14291 -6741 -375 4131 -6015 -1760 -146 8471 15438 7022 -3796 6201 16598 -30647 18716 -3474 6477 -6836 -8691 6829 -21417 12625 -20893 15406 6337 2375 19253 -11685 7899 -13305 17772 4499 13823 29214 906 -6467 -26264 7762 11641 11440 18055 604 15147 -19662 27103 -29021 2043 3672 -25065 -19698 -21158 -912 4638 19549 14694 26311 12084 13288 12753 -11700 18149 8965 -12476 -6434 -17312 21981 -960 8600 4896 -23874 15297 3962 10123 -13854 797 18079 7142 13598 -16929 -1619 -5102 29912 -5583 4103 -12360 -7833 613 6610 11325 19187 14304 -12322 -11999 16630 -20604 618 -6077 7396 16061 -4436 -10863 -2993 -9490 -10131 16891 -6256 4160 13836 -8458 17230 -16434 -26214 11076 20065 15414 18649 20760 -11016 12273 7302 2428 6379 18520 12348 -8329 -5349 -11549 16224 -20021 11373 -21733 -9642 16953 SO 20171208T084411.0Z 6551.364016 249 1 32.00 2 89.03 117.25 50.27 352.73 0.00 1 0.00 1 0 22 1.135e-01 1.001e-01 9.510e-02 9.179e-02 7.633163e+03 6.338916e+03 4.233189e+02 -6.000000e+00 6.297215e+03 286.55 -2.00 20.00 -2.00 505.23 0.00e+00 1.610931e-03 2.512030e-03 4.228264e-05 -6.000000e+00 3.173366e-03 286.55 -2.00 20.00 -2.00 499.93 0.00e+00 9.569032e-01 1.853698e+00 6.088097e-02 -6.000000e+00 2.218930e+00 229.55 -2.00 3.16 -2.00 501.57 0.00e+00 18.614 0.060 489.00 513.00 1 9.8625e+00 1.4236e-01 2.8395e-02 -6.0000e+00 1.7025e-01 1.3663e-01 3.6510e-02 1.9958e-03 -6.0000e+00 4.4261e-02 6.4139e-06 2.7375e-03 8.5372e-03 2.8970e-05 -6.0000e+00 1.1159e-02 -8.9618e-03 3.2850e-04 12 9 8 11 8 0 -93.95 22.75 0.84 -0.00896 0.01003 8 2 1 4 0 4000.000 26.62 20.00 22.75 -2483 -7902 21745 -6729 -1139 1868 -8131 -1165 -4069 -5548 -4451 15738 -12489 29404 13821 5032 19407 -5836 6611 7386 -2505 10495 3695 -2408 -5666 19500 -6962 53090 -10019 -1646 1939 -14702 2500 -10424 7675 -11736 3077 -5666 4665 -4955 -11152 8104 -2228 -3708 11873 5742 2511 233 19037 -9166 15251 -190 3056 15214 -5437 9579 -3716 20145 7083 -9552 -11185 4094 -5 -12324 7117 -6344 9861 -12690 4990 6900 10975 6403 -132 29366 -5280 -15464 4713 -13211 17953 1311 18051 -9601 13703 2435 -8466 -7465 -3376 4609 104 -283 4595 -5540 -10942 4975 -2598 22551 5027 4751 -12011 -12699 -364 9251 -1626 -3787 4796 -1598 1260 15176 -4253 4244 -8948 1331 -233 -5261 -2736 18373 7633 20830 -14134 9316 -861 -1333 5742 5457 31602 -11576 12340 -704 -3608 -3808 -5156 32086 2739 4338 -4082 -16346 -9607 -4799 197 11625 4753 -2906 1974 -5359 147 -1763 14584 13979 8649 -8739 -9737 -11318 15964 -2601 -8988 19005 -8043 -1318 2137 -10399 -1393 -4969 -6774 -5292 15070 -15651 23998 13146 5272 17959 -6650 7265 8116 -2840 10449 3945 -2745 -6695 17895 -8268 34072 -11778 -1728 1931 -17372 2549 -12505 7872 -14712 3304 -6559 4813 -5588 -13378 8068 -2486 -4248 11750 6062 2726 255 17013 -10611 13447 -190 2915 12867 -5772 9021 -4101 17762 7137 -11344 -13485 4248 -5 -15154 7172 -7229 9405 -14919 4849 6497 9808 5953 -132 22017 -5669 -18457 4551 -14976 14645 1251 14508 -9556 11589 2177 -8522 -7514 -3284 4147 97 -265 4108 -5514 -11629 4560 -2571 17119 4438 4088 -11887 -12354 -307 7022 -1390 -3407 4126 -1519 1183 12374 -4161 3770 -9057 1228 -221 -5325 -2723 14877 6910 16633 -16134 8434 -857 -1311 5166 4848 21502 -12173 10270 -669 -3530 -3726 -5102 21832 2480 3806 -3833 -17188 -9453 -4560 182 9740 4330 -2893 1887 -5218 144 -1671 12465 11245 7232 -8510 -9379 -10961 11828 SO 20171208T084813.0Z 6551.366817 253 1 32.00 2 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