File name: Pandora114s1_BuenosAires_20171209_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022520.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171209_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171209T084008.0Z 6552.361204 254 1 31.99 2 89.79 117.96 46.90 11.01 0.00 1 0.00 1 0 22 1.124e-01 1.068e-01 1.169e-01 1.121e-01 2.085662e+04 9.485984e+03 8.183803e+02 -6.000000e+00 6.241129e+03 286.60 -2.00 20.00 -2.00 505.29 0.00e+00 1.494528e-03 3.145952e-03 1.305796e-04 -6.000000e+00 3.144739e-03 286.60 -2.00 20.00 -2.00 499.83 0.00e+00 -2.432817e-01 2.341171e+00 1.707984e-01 -6.000000e+00 2.199648e+00 229.57 -2.00 3.16 -2.00 501.49 0.00e+00 20.045 0.075 489.00 513.00 1 9.9335e+00 1.7984e-01 3.3601e-02 -6.0000e+00 1.6876e-01 1.5516e-01 4.5357e-02 3.6626e-03 -6.0000e+00 4.3889e-02 5.2139e-06 -1.0916e-02 9.4351e-03 3.4293e-05 -6.0000e+00 1.1060e-02 -9.1856e-02 8.0902e-04 12 9 8 11 8 0 95.65 22.91 1.50 -0.09186 -0.16758 8 2 1 4 0 4000.000 26.83 19.99 22.91 -7191 -693 -9992 -3967 11384 1799 5776 -7732 -11827 -76 7551 9742 -5907 4734 -14569 648 -1941 10426 4722 2355 19382 1785 17119 4070 10177 125 3311 2586 2377 13773 -17306 12601 -14447 -13663 -5967 -10433 3446 -3228 16922 -2313 13575 9071 -842 -15262 2117 -5369 -14547 1538 4416 4754 11287 -2521 -5119 -7981 5565 10228 -1532 5212 10952 18202 1006 27261 -700 2469 3995 94 11025 -6006 -4299 2049 3815 -4450 -5626 14593 -5328 12925 -363 583 -9710 23826 -5156 924 -2088 -15403 17969 -18334 11871 -470 21973 2495 8570 3487 -2748 -15130 17575 4305 12498 -24313 23738 -1952 15070 10627 16388 9312 -7826 6613 -10185 4869 -12617 27815 -4915 14298 6289 22377 1873 -7923 -2734 4678 20279 11189 -11252 -480 -21620 7706 -2839 15946 4541 -17185 -4203 -3365 11053 -19009 7919 -8114 5935 13098 1094 -10710 -10386 26460 1736 12563 10794 10448 14504 -17757 -3387 9083 -3264 -1183 -17390 13915 12448 -7787 -712 -11604 -4483 11344 2018 6345 -9829 -15684 -89 8058 10015 -6999 4978 -18405 702 -2178 10554 5187 2698 18859 2073 17060 4322 10212 139 3564 2784 2525 12710 -21167 11259 -17035 -16411 -6861 -12836 3710 -3688 15615 -2557 12726 8902 -919 -19449 2295 -6331 -18857 1690 4658 4909 10664 -2659 -5399 -8534 5217 9363 -1627 5306 10668 16530 1083 22561 -769 2640 4213 103 10658 -6774 -4691 2070 3744 -4694 -5974 12719 -5736 11738 -378 594 -10738 18497 -5286 886 -2064 -16392 14739 -20518 10607 -448 17862 2296 7355 3136 -2642 -16621 13998 3872 10040 -27043 15646 -1608 10244 7442 10802 6713 -6985 5404 -10350 4379 -13600 19862 -4825 11584 5571 17054 1761 -8214 -2684 4272 16012 9833 -12516 -478 -26126 6773 -2710 12481 3991 -18878 -4069 -3235 9183 -21274 6742 -8022 5013 10162 954 -10590 -10412 18713 1597 10524 9338 9182 12348 -19737 -3261 8169 -3100 -1086 -18430 10611 9572 SO 20171209T084412.0Z 6552.364028 258 1 32.00 2 89.04 117.39 46.74 9.69 0.00 1 0.00 1 0 15 9.438e-02 8.906e-02 8.956e-02 8.681e-02 1.597637e+03 5.446876e+03 2.419411e+02 -6.000000e+00 5.237987e+03 286.60 -2.00 20.00 -2.00 505.22 0.00e+00 1.009160e-03 2.385513e-03 9.371359e-05 -6.000000e+00 2.642503e-03 286.60 -2.00 20.00 -2.00 499.76 0.00e+00 3.092079e+00 1.768024e+00 8.540143e-02 -6.000000e+00 1.856653e+00 229.57 -2.00 3.16 -2.00 501.44 0.00e+00 18.655 0.061 489.00 513.00 1 9.6640e+00 1.3600e-01 2.8775e-02 -6.0000e+00 1.4229e-01 1.1104e-01 3.4850e-02 1.9155e-03 -6.0000e+00 3.7272e-02 6.7972e-06 7.7760e-03 8.2402e-03 5.7383e-05 -6.0000e+00 9.3065e-03 -9.3716e-02 4.1136e-04 12 8 8 10 0 0 93.31 22.90 8.27 -0.09372 -0.03978 8 2 1 4 0 4000.000 26.83 20.00 22.90 13346 9178 -11733 -12605 -7184 -1580 -4617 -5009 10326 -6184 4186 1666 -7507 10755 9034 14494 -12243 260 7364 -7263 -10674 3512 1044 4513 35460 -6448 -660 -1828 -8473 8620 -11296 -5453 2319 2288 10092 11305 6538 -851 8499 -4143 10626 -33 7269 2939 9333 -6576 -501 7389 386 -15429 1312 13916 11102 -15334 -8836 27722 8891 -509 8806 15123 -2078 1128 -5268 -2058 -312 8609 16160 -2540 -1349 -440 3486 -12881 -12950 -3587 -2887 13354 4082 9692 3428 -833 1057 -8118 6606 -4176 20901 2091 8319 -16755 -2061 -7732 5399 8343 -10401 -11128 6032 8138 4390 -4479 21025 -17253 -4113 2371 10511 -3010 8412 528 -3003 651 9558 -1607 -7286 1396 7762 5131 13987 9310 -5290 7469 -3271 12800 11470 -5360 -4823 -7171 -6584 8924 -6703 -9558 8628 -6442 15453 1148 180 9255 12824 4357 4526 11879 2992 -6795 1009 -12939 -3959 3705 -10037 15610 -5047 -10242 -9886 3543 -13307 22249 -1472 11924 8758 -14262 -15935 -8820 -1873 -5724 -6271 11046 -7705 4630 1863 -9079 10720 9114 13919 -14585 300 8101 -8734 -13321 3805 1161 4864 28161 -7791 -749 -2074 -10045 8362 -13072 -5939 2381 2427 10190 11415 6898 -956 8582 -4701 10367 -35 7422 3168 9530 -7908 -565 7628 420 -19255 1347 12236 9824 -17571 -9624 21544 8574 -549 8692 13983 -2275 1196 -5977 -2265 -336 8400 14392 -2680 -1385 -442 3322 -14321 -14399 -3662 -2964 11741 3913 8631 3190 -799 989 -7815 5883 -3909 16362 1868 7034 -18267 -1940 -7689 4709 7099 -10786 -11777 5422 7141 3945 -4311 15318 -17983 -3675 1955 7993 -2673 6890 483 -2891 603 7980 -1479 -7052 1247 6604 4557 11530 8120 -5373 6713 -3288 10960 9882 -5387 -4745 -7132 -6478 7546 -6666 -9810 7387 -6407 12327 1056 166 7727 10162 3707 3827 9413 2642 -6758 945 -13276 -3980 3468 -10199 13117 -4926 -10509 -9996 3068 -13321 15368 -1289 SO 20171209T084814.0Z 6552.366829 262 1 31.99 2 88.30 116.82 46.60 8.37 0.00 1 0.00 1 0 29 6.666e-02 6.526e-02 6.772e-02 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