File name: Pandora114s1_BuenosAires_20171210_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022517.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171210_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171210T084022.0Z 6553.361366 269 1 32.00 2 89.77 118.06 46.24 28.46 0.00 1 0.00 1 0 29 1.241e-01 1.142e-01 1.250e-01 1.204e-01 -5.793691e+03 7.022370e+03 1.227654e+02 -6.000000e+00 6.884600e+03 286.65 -2.00 20.00 -2.00 505.25 0.00e+00 4.048171e-03 3.296763e-03 2.816722e-04 -6.000000e+00 3.476416e-03 286.65 -2.00 20.00 -2.00 500.00 0.00e+00 3.230509e+00 2.411884e+00 1.616478e-01 -6.000000e+00 2.447683e+00 229.59 -2.00 3.16 -2.00 501.67 0.00e+00 20.021 0.075 489.00 513.00 1 9.7583e+00 1.8501e-01 3.3454e-02 -6.0000e+00 1.8743e-01 9.8770e-02 4.8110e-02 2.9144e-03 -6.0000e+00 4.9343e-02 4.8570e-06 2.5331e-02 1.1614e-02 9.2467e-05 -6.0000e+00 1.2238e-02 1.0361e-01 -1.0633e-03 12 8 8 10 0 0 99.05 22.12 4.73 0.10361 0.27932 8 2 1 4 0 4000.000 26.11 20.00 22.12 3232 17524 9771 13203 -7877 26843 591 -4157 14745 2489 -9322 -7142 829 -4423 2994 2900 -14318 -2448 17862 4258 -890 -2861 -951 -7286 5131 -11245 -6942 -2724 20703 13641 10512 595 2233 -20373 6742 -11672 24083 -13885 4251 -448 7806 -14534 10218 14727 -7342 2342 -3403 -2059 -6160 10347 10115 16955 3831 -9620 627 14172 -8871 6329 24997 81 -1271 9748 -6854 -7709 -2359 10771 15033 12621 -16603 -20506 -5629 -2058 1002 12298 -6809 9356 13087 -17483 9167 -12143 15316 5004 -6497 1090 16557 -12832 5865 -2088 29605 24613 23253 -8904 -5025 -11630 6122 6379 21142 -6630 11448 9753 2410 -12378 -5608 14867 4058 -5227 29369 -5816 -14000 -7454 4414 8825 16501 11853 6456 -12156 -1998 -13904 -11206 17751 -9852 10623 1760 3225 -16731 17142 -1844 6750 24220 5944 -12039 -17314 -13703 -5711 -2312 6091 -7912 1919 8921 2022 10426 -1236 19879 18375 21618 -15552 5062 1206 5196 25221 1189 39701 -17350 3161 15369 9558 12805 -9632 23542 678 -4978 14424 2708 -11241 -8311 881 -4923 3106 3057 -17130 -2659 17172 4390 -967 -3175 -1040 -8545 5331 -13719 -8031 -2958 17273 11917 9432 599 2284 -26940 6899 -14332 20472 -17048 4316 -476 7680 -18074 10053 14026 -8784 2544 -3884 -2285 -6982 9691 9235 14146 3619 -10525 637 12939 -10404 6426 21052 87 -1391 9591 -7984 -9041 -2599 10258 13489 11424 -19863 -25179 -5893 -2073 986 10938 -7395 8616 11434 -19093 8081 -12365 12657 4608 -6328 990 12951 -13540 5150 -1987 20534 17980 17330 -9264 -5117 -12873 5737 5978 17004 -6947 9799 8276 2151 -12696 -5421 11958 3713 -5284 20804 -5751 -14772 -7315 3876 7553 13393 10321 6050 -13903 -2079 -16312 -12734 14932 -10759 9328 1675 3022 -19259 14167 -1851 6226 18765 5527 -13414 -19119 -14465 -5816 -2234 5349 -7998 1784 7899 1955 9386 -1259 16429 15457 17706 -17498 4640 1139 4619 17866 1049 23712 -18556 SO 20171210T084427.0Z 6553.364201 273 1 32.00 2 89.03 117.49 45.84 27.19 0.00 1 0.00 1 0 22 1.318e-01 1.244e-01 9.547e-02 9.141e-02 -6.580595e+02 5.460861e+03 5.247377e+02 -6.000000e+00 7.312045e+03 286.65 -2.00 20.00 -2.00 505.21 0.00e+00 3.583049e-03 2.506903e-03 1.932740e-04 -6.000000e+00 3.690867e-03 286.65 -2.00 20.00 -2.00 499.83 0.00e+00 4.794716e+00 1.862585e+00 1.060380e-01 -6.000000e+00 2.597173e+00 229.59 -2.00 3.16 -2.00 501.48 0.00e+00 18.610 0.060 489.00 513.00 1 9.5579e+00 1.4333e-01 2.9300e-02 -6.0000e+00 1.9893e-01 6.5611e-02 3.6866e-02 1.9957e-03 -6.0000e+00 5.2294e-02 6.4221e-06 5.2285e-03 8.8637e-03 1.2203e-04 -6.0000e+00 1.2997e-02 9.3854e-02 -9.1739e-04 12 9 8 11 8 0 -96.99 22.12 -1.41 0.09385 0.13012 8 2 1 4 0 4000.000 26.11 20.01 22.12 3956 3618 2584 -12104 795 4684 -414 -1315 4 30304 -13533 16717 -11891 10970 -8422 -18766 22297 2331 24839 -9828 13478 13563 -10642 11775 -11001 -179 -6570 29173 -1762 4862 -5612 -9999 3138 8625 31672 -9197 12081 2534 -11981 346 -16509 17755 -13696 7202 5592 -3201 19398 -1395 12210 1003 14476 10964 -8423 34742 -2824 30298 5596 7036 -2155 -11803 -5127 -17724 9559 -3036 15732 -2009 15262 8442 1421 8492 -9205 -4296 -16056 -3050 -8107 -3357 8961 -17459 16952 -2877 10552 7042 7359 3270 -26729 15146 -2395 13890 -2751 5629 -713 11787 -4687 -23340 15564 -8011 3321 13417 -2389 5780 -21980 21387 -7206 12431 3937 4861 8431 -4015 6915 -10315 10650 4489 -4352 19141 6312 6623 -17301 30419 4652 7735 7154 572 18167 -850 -157 -12511 8393 -9048 22149 11957 -10754 29137 -12238 14548 4606 2442 19035 -18721 15215 -11370 21447 -14015 4014 6329 -9041 31378 -24936 1895 -6809 3959 6930 754 13454 3848 3612 2695 -15105 895 5186 -491 -1582 5 26182 -17841 16048 -14992 10882 -9408 -23316 19977 2437 21216 -12034 13122 13205 -13222 11745 -13865 -203 -7928 24396 -1968 4937 -6168 -11408 3186 8552 25729 -11427 12123 2770 -14957 379 -21300 16332 -17426 7529 6012 -3786 18307 -1609 12107 1090 13403 10217 -9307 24695 -2951 23346 5682 7187 -2433 -14664 -5941 -23290 9593 -3463 14847 -2244 14130 8219 1460 8014 -10227 -4491 -17622 -3151 -8353 -3327 8350 -19554 14074 -2691 8568 5915 6181 2875 -31882 11959 -2266 11201 -2619 4917 -663 9703 -4593 -27970 12812 -8389 3087 11120 -2274 4952 -24248 14971 -6658 9536 3374 4247 7224 -3889 5924 -10339 8588 3871 -4167 14792 5655 6008 -20151 22145 4402 7104 6570 554 14548 -814 -149 -13452 7379 -9525 17116 10245 -10882 21048 -12577 12057 4152 2216 14496 -19635 12269 -11506 16934 -15068 3639 5637 -9435 21995 -30885 1798 -6998 3589 5954 676 10565 SO 20171210T084829.0Z 6553.367002 277 1 31.99 2 88.29 116.92 45.47 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