File name: Pandora114s1_BuenosAires_20171211_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022452.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171211_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171211T084034.0Z 6554.361505 279 1 32.00 2 89.76 118.16 48.08 45.02 0.00 1 0.00 1 0 46 1.226e-01 1.122e-01 1.022e-01 9.813e-02 6.516806e+02 5.870429e+03 1.055774e+02 -6.000000e+00 6.801338e+03 286.70 -2.00 20.00 -2.00 505.23 0.00e+00 -9.935781e-05 2.689243e-03 1.320354e-05 -6.000000e+00 3.431123e-03 286.70 -2.00 20.00 -2.00 499.82 0.00e+00 2.488358e+00 1.989033e+00 1.646390e-02 -6.000000e+00 2.411280e+00 229.62 -2.00 3.16 -2.00 501.51 0.00e+00 20.013 0.075 489.00 513.00 1 9.6553e+00 1.5268e-01 3.0524e-02 -6.0000e+00 1.8476e-01 1.3048e-01 3.9864e-02 1.6927e-03 -6.0000e+00 4.8457e-02 5.9759e-06 2.2517e-03 9.4123e-03 1.5757e-05 -6.0000e+00 1.2077e-02 1.0291e-01 -8.2699e-04 12 8 8 10 0 0 91.09 21.47 2.20 0.10291 0.11853 8 2 1 4 0 4000.000 25.58 20.30 21.47 -3852 19157 3468 -9880 8468 -1174 1031 -534 -5236 10363 -11066 16288 -2573 4999 1181 10742 12997 -16386 1863 -5763 7321 -3086 13138 57 -2930 509 -18088 46021 -4703 26720 1730 -14569 16061 -8894 -2508 -15062 12133 -16226 24221 12559 -6195 26484 -9188 22907 -7229 26638 -1888 -8264 2628 -1837 22318 -4486 26620 4321 -8126 10715 -13403 3018 -17907 4918 2713 12380 29695 -7886 2417 -12700 20467 -8692 -3755 1875 -682 29885 -5140 21069 -4367 23385 -14651 -652 -1269 -5895 4180 -20064 14315 11979 -1886 5068 -11719 10704 4621 -2564 -3791 5722 17399 -3028 -3209 -692 18031 -8839 4800 -3576 770 6115 -11256 12617 -815 13756 -3036 -13929 -1021 7362 18219 -14171 18920 6682 13746 -1108 -2841 8387 -6055 -5945 -7070 9075 -9974 -9635 16068 -2406 9435 -4630 9110 -5306 14536 2594 -4016 6812 -15443 -446 -1304 -9849 8324 -10806 6120 1662 12671 76 -662 15038 -4906 8085 -10153 12311 -6300 -5251 22527 -4076 16453 3597 -12083 8844 -1380 1204 -639 -6547 10965 -14294 15779 -2970 5289 1290 10701 12859 -20805 2163 -6837 8199 -3582 12975 65 -3420 575 -24474 32463 -5398 21761 1764 -17377 14316 -10494 -2862 -19800 12138 -21331 20969 12081 -7151 22079 -11018 20125 -8669 22890 -2155 -9963 2797 -2002 18605 -4747 20143 4045 -8702 9757 -15986 3116 -22966 5014 2819 11670 23613 -9153 2526 -15310 17456 -9755 -3949 1840 -678 21656 -5273 16754 -4536 18596 -17006 -649 -1245 -5972 3807 -21833 11842 10217 -1746 4417 -12188 8945 4112 -2451 -3669 5057 13808 -2985 -3202 -674 14417 -9086 4214 -3332 672 4963 -10827 9709 -740 11165 -2975 -15241 -970 6329 13911 -14994 14559 5905 11487 -1085 -2852 7564 -6334 -6219 -7438 8020 -10494 -9963 12751 -2300 8055 -4565 7832 -5263 11798 2371 -3911 5897 -16433 -402 -1176 -9710 6956 -11174 5445 1569 10817 74 -653 12747 -4803 6954 -10398 9891 -5953 -4813 15551 SO 20171211T084438.0Z 6554.364329 283 1 32.00 2 89.02 117.59 47.49 43.93 0.00 1 0.00 1 0 29 8.688e-02 8.703e-02 8.144e-02 7.901e-02 1.152849e+04 5.968496e+03 6.946374e+02 -6.000000e+00 4.822352e+03 286.70 -2.00 20.00 -2.00 505.25 0.00e+00 2.600482e-03 2.178866e-03 1.386944e-04 -6.000000e+00 2.431255e-03 286.70 -2.00 20.00 -2.00 499.82 0.00e+00 -4.750924e-01 1.643891e+00 7.632327e-02 -6.000000e+00 1.705990e+00 229.62 -2.00 3.16 -2.00 501.49 0.00e+00 18.607 0.060 489.00 513.00 1 9.7985e+00 1.2598e-01 2.8800e-02 -6.0000e+00 1.3078e-01 1.6761e-01 3.2210e-02 2.2755e-03 -6.0000e+00 3.4197e-02 7.4922e-06 -7.2453e-04 7.2668e-03 6.7161e-05 -6.0000e+00 8.5565e-03 2.4314e-02 -1.9265e-04 12 8 8 10 0 0 -373.62 21.47 7.04 0.02431 0.01929 8 2 1 4 0 4000.000 25.58 19.83 21.47 -12234 2979 -3187 9805 -11810 -12705 9087 2370 1569 -3850 6994 2869 1887 621 -1669 4572 -5078 -3785 -14235 1210 5888 -13434 3938 -9357 -965 2040 10547 -246 4006 10443 -5502 17351 -11850 9776 -663 12433 5285 926 -2199 -7746 5706 2557 11694 7701 -5710 15959 2891 -9026 1727 3692 -1772 2933 8770 -7802 14136 -581 9157 -759 2584 6087 -9002 6510 -2200 14146 4826 4098 14216 -18526 7263 -8336 -15779 3831 -3087 4844 7209 7712 -6014 7684 4117 9856 12016 -5128 6878 -637 5005 6054 4831 2630 6769 3592 -6468 -948 -3613 5257 10859 -12231 7766 -6427 19636 -7288 6371 5410 8988 4078 -5002 14178 -2873 19287 9986 -6761 10309 2400 10195 -1185 10231 -15428 -6289 7581 -2150 9337 -24854 -4038 -171 6032 10080 -12214 -5623 -2220 14844 -10356 8144 -4205 3563 1262 -14867 -1923 13660 7039 -1843 551 -10746 -3718 15584 13438 -5240 -7705 -6722 16271 -5270 9476 -6365 1083 -8625 -14212 3032 -3562 9926 -15222 -16868 9853 2767 1840 -4707 7545 3174 2077 683 -1741 4485 -5558 -4183 -17860 1318 6141 -16994 4189 -11402 -1086 2233 10565 -272 4158 9868 -5937 14782 -13705 9388 -729 12197 5567 1008 -2441 -8998 5774 2681 11291 7833 -6722 15244 3149 -10999 1863 3832 -1894 2908 8015 -8339 12262 -600 8841 -827 2749 6255 -10737 6656 -2465 13512 5059 4295 13285 -23626 7050 -9340 -18820 3719 -3204 4677 6886 7406 -6200 6807 3707 8254 9771 -4939 5893 -592 4434 5363 4373 2444 6029 3286 -6512 -904 -3567 4809 9461 -13322 6766 -6253 14258 -6738 5027 4242 6787 3296 -4600 11255 -2795 15218 8604 -6807 8683 2195 8735 -1153 8964 -17550 -6545 6898 -2175 8497 -31881 -4164 -166 5401 8538 -12889 -5580 -2139 12072 -10191 7057 -3869 3208 1148 -14697 -1750 10580 5860 -1704 507 -10575 -3456 12824 10714 -5061 -7652 -6615 12676 -5042 7684 -5915 917 -8016 SO 20171211T084840.0Z 6554.367130 287 1 32.00 2 88.29 117.03 46.92 42.83 0.00 1 0.00 1 0 29 6.641e-02 6.423e-02 6.161e-02 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