File name: Pandora114s1_BuenosAires_20171212_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022511.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171212_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171212T084044.0Z 6555.361620 289 1 31.99 2 89.77 118.27 51.96 59.73 0.00 1 0.00 1 0 15 1.346e-01 1.253e-01 1.077e-01 1.032e-01 1.397050e+03 6.393479e+03 1.787012e+02 -6.000000e+00 7.475464e+03 286.75 -2.00 20.00 -2.00 505.20 0.00e+00 7.857725e-03 2.821335e-03 6.084728e-04 -6.000000e+00 3.765928e-03 286.75 -2.00 20.00 -2.00 500.03 0.00e+00 1.651605e-01 2.106905e+00 9.504556e-02 -6.000000e+00 2.633165e+00 229.64 -2.00 3.16 -2.00 501.65 0.00e+00 20.022 0.075 489.00 513.00 1 9.7598e+00 1.6174e-01 3.4400e-02 -6.0000e+00 2.0203e-01 1.6841e-01 4.1968e-02 1.8910e-03 -6.0000e+00 5.2542e-02 5.6714e-06 2.8045e-03 9.7855e-03 2.1628e-04 -6.0000e+00 1.3240e-02 -8.0458e-02 7.3785e-04 12 8 8 10 0 0 -113.58 22.24 9.84 -0.08046 -0.06101 8 2 1 4 0 4000.000 26.21 20.00 22.24 16655 3194 -15151 -658 1643 30707 1898 17535 17992 4258 8509 -8199 -2806 -10 13960 -15092 -9368 1632 -4329 7973 -16438 6521 8843 2124 4764 -3231 -3109 -5710 9462 -10809 7263 -2389 -3414 4549 -3826 20982 -8960 -1636 4521 4758 4488 971 17807 -2136 -3754 -9871 8705 3894 -17762 11728 -17078 8109 8772 18261 12544 -8872 11898 -17656 9262 -8527 -4479 -2290 -4085 10515 -1853 14590 -10827 12121 15852 3221 11099 -12006 -3285 -20463 38398 -7590 35070 1110 -8280 15303 5154 12744 -5872 19134 12530 -8146 -3387 -13840 22671 -12809 5330 17329 -6884 612 -21789 -777 -12665 30713 1935 -7851 14091 -1314 2217 -9803 11949 -3517 3105 17836 4225 11357 -153 32672 -31131 23775 17662 6745 22896 -3903 22998 -10271 -3149 -4147 -4474 18970 -15160 25974 -16167 23592 -8316 -17537 6156 -11073 10220 -13407 18204 18350 8389 9172 133 10245 10776 29979 -1007 12102 18316 8287 19383 -15389 -197 -16849 -5254 -1826 -649 14318 3231 -19045 -737 1839 26176 2180 17228 17417 4645 8729 -9774 -3122 -10 12909 -18753 -11167 1780 -5098 8352 -20505 6926 8586 2220 4882 -3594 -3437 -6391 8868 -12025 6611 -2400 -3545 4509 -4231 18250 -10452 -1754 4511 4716 4478 1015 15969 -2376 -4303 -12113 8863 4123 -22995 11071 -20958 7546 7985 15145 11249 -10170 11391 -23096 9305 -10234 -5165 -2594 -4738 10564 -2099 13871 -13068 11442 14216 3236 10178 -13762 -3455 -25801 27185 -8547 25538 1116 -8988 13001 4830 11085 -5790 15740 11067 -8342 -3319 -15047 17054 -13684 4751 13802 -7093 595 -26858 -776 -14090 21744 1786 -7791 10956 -1171 1906 -9667 9743 -3424 2846 13981 3739 9261 -140 21892 -40342 18185 14626 6310 18381 -4120 18608 -11556 -3265 -4273 -4553 15109 -16962 19374 -18498 18194 -8831 -20397 5643 -12039 8915 -14577 14154 14035 7053 7711 125 8807 9332 21603 -993 10480 14935 7491 15683 -16480 -178 -17542 -4751 -1575 -556 SO 20171212T084449.0Z 6555.364456 293 1 32.00 2 89.03 117.69 51.25 58.84 0.00 1 0.00 1 0 22 7.743e-02 7.626e-02 8.249e-02 8.028e-02 8.294411e+02 4.872694e+03 3.574293e+02 -6.000000e+00 4.299560e+03 286.75 -2.00 20.00 -2.00 505.25 0.00e+00 6.871776e-04 2.196242e-03 5.538316e-05 -6.000000e+00 2.166404e-03 286.75 -2.00 20.00 -2.00 499.83 0.00e+00 5.032971e+00 1.626179e+00 8.685305e-02 -6.000000e+00 1.515696e+00 229.64 -2.00 3.16 -2.00 501.49 0.00e+00 18.617 0.060 489.00 513.00 1 9.4532e+00 1.2448e-01 2.8643e-02 -6.0000e+00 1.1628e-01 6.6071e-02 3.2246e-02 1.9031e-03 -6.0000e+00 3.0269e-02 7.3847e-06 -8.1518e-03 7.4902e-03 7.3839e-05 -6.0000e+00 7.6180e-03 -5.5735e-02 5.3757e-04 12 8 8 10 0 0 -556.51 22.24 10.76 -0.05573 -0.11228 8 2 1 4 0 4000.000 26.21 20.00 22.24 -3748 5158 -9193 -7320 3973 6294 -8115 -162 10455 -2268 5629 6297 -3056 -5649 1524 -7750 -9262 8311 -15182 11107 -47 5370 5978 -2227 2397 9026 4378 -18715 9401 -4567 -1143 -6671 5250 9653 2288 3401 6099 6212 8430 3243 10215 4584 -3875 15058 2813 -1146 -3345 -4064 5345 4379 -10907 4533 -9673 -2737 857 -4533 10389 -1368 -5536 -2769 -12164 11360 11002 6455 3779 1018 1104 -7005 3307 795 8230 3603 6996 -2499 -7472 728 2330 2573 -539 -1120 -2531 -13064 7253 2005 3210 -7783 13064 -4470 14300 -2370 1792 939 6703 -4933 15543 7630 -265 -6533 -10668 -8056 -734 13905 13113 -1258 -1836 -2787 1168 4910 -11154 7466 -7349 -18833 2573 1521 3150 -12541 15561 2681 3732 14620 3696 5288 -4544 10373 7277 6867 1441 -3249 20451 -1915 2768 -3461 23096 -576 7364 -3474 -9940 8929 -5963 3695 -9412 -16756 10207 -4939 -1447 -4101 -1537 -3665 1588 -6724 -2247 5716 6197 -3918 5016 -10644 -8599 4287 6792 -10308 -192 11165 -2728 6169 6760 -3556 -6667 1662 -8660 -10641 8197 -19433 11129 -53 5747 6366 -2582 2666 9423 4777 -25526 9519 -5175 -1217 -7419 5233 9469 2497 3747 6559 6615 8668 3470 10128 4810 -4452 14456 3084 -1316 -3931 -4775 5636 4571 -12931 4471 -10707 -2786 846 -4827 9810 -1485 -6331 -3079 -14804 10906 10619 6535 3925 1079 1152 -7790 3262 793 7512 3402 6350 -2504 -7958 722 2273 2470 -490 -1008 -2290 -13106 5957 1745 2778 -7579 10409 -4265 11323 -2215 1604 850 5769 -4827 12536 6679 -249 -6426 -10703 -7686 -635 10189 9609 -1076 -1625 -2577 1063 4323 -11410 6242 -7048 -20284 2265 1377 2851 -13446 12704 2505 3469 12223 3435 4785 -4470 8672 6227 5910 1318 -3132 15590 -1827 2519 -3353 17152 -538 6266 -3246 -9826 7334 -5777 3325 -9279 -18071 9036 -4824 -1373 -4024 -1479 -3614 1478 -6692 -2090 4816 5163 SO 20171212T084851.0Z 6555.367257 297 1 31.99 2 88.29 117.13 50.55 57.95 0.00 1 0.00 1 0 22 6.573e-02 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