File name: Pandora114s1_BuenosAires_20171215_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T022541.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171215_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171215T084134.0Z 6558.362199 321 1 32.00 2 89.77 118.49 70.77 92.60 0.00 1 0.00 1 0 15 1.436e-01 1.288e-01 9.815e-02 9.347e-02 1.391214e+03 5.756217e+03 2.886393e+02 -6.000000e+00 7.975569e+03 286.90 -2.00 20.00 -2.00 505.19 0.00e+00 6.757356e-03 2.544301e-03 3.893730e-04 -6.000000e+00 4.017213e-03 286.90 -2.00 20.00 -2.00 499.99 0.00e+00 2.101121e+00 1.895859e+00 6.837284e-02 -6.000000e+00 2.806597e+00 229.71 -2.00 3.16 -2.00 501.60 0.00e+00 20.010 0.075 489.00 513.00 1 9.5317e+00 1.4527e-01 3.2261e-02 -6.0000e+00 2.1536e-01 1.2954e-01 3.7674e-02 1.8423e-03 -6.0000e+00 5.5991e-02 6.2715e-06 1.9059e-03 8.9154e-03 1.3750e-04 -6.0000e+00 1.4114e-02 4.7268e-03 2.4062e-04 12 8 8 10 0 0 -296.00 22.85 3.30 0.00473 0.01795 8 2 1 4 0 4000.000 26.73 20.00 22.85 15006 2073 4230 9064 12678 -2742 -11082 12407 -2625 9105 -13981 13532 2471 2635 2848 2887 23724 -2612 9217 2038 -3564 15025 1238 14677 -12294 2708 -69 45397 -4084 -14676 14165 -11387 28073 -7822 -3174 15345 -12918 6067 -20832 -3531 -11186 5340 7978 -9742 946 -2239 26146 -13991 19383 12578 -9905 12683 -8574 1587 -18882 13120 2271 -11614 7133 -12274 22314 5006 15822 -14693 -7301 -5353 5326 12346 6451 12201 -7327 30752 -10228 -8211 10245 -15706 30578 -12897 35420 -10120 -453 18749 -16551 8167 -14037 12655 -13673 15044 18329 4206 3583 -21893 15784 -11644 22845 2145 -3167 10447 -12417 11130 1852 9201 -15072 -2446 19919 -7480 2758 -20564 27723 -3135 5997 32482 -13172 -3263 -11906 2701 -5545 1816 -687 7330 10722 -2307 34770 -4222 28776 -2492 29327 1527 2282 8447 -17927 -831 -20565 10156 21151 3095 23308 4973 14187 -2473 2485 16976 -12129 28683 -6261 23455 -14013 14701 -6767 -1239 18841 -6581 -1882 13159 2130 4401 9253 12777 -3284 -14577 12909 -3144 9534 -18115 13106 2636 2776 2982 3041 20649 -3025 9651 2153 -3983 14945 1324 13805 -15243 2894 -75 31055 -4466 -17300 12285 -12797 21776 -8981 -3567 14433 -16016 6151 -27356 -3882 -13322 5447 8040 -11900 1051 -2585 22677 -17945 17521 11908 -11434 11387 -9374 1571 -23411 12181 2414 -14400 7363 -15368 19762 5289 15075 -19025 -8740 -6212 5466 11613 6344 11178 -8055 22915 -11494 -9128 9574 -19090 23158 -14809 24663 -10315 -446 15230 -18007 6968 -15031 10434 -14719 12146 14273 3757 3221 -25574 12834 -12668 17790 2051 -3155 8913 -13011 8986 1601 7270 -15190 -2213 14827 -7495 2511 -23432 19208 -2926 5117 21575 -14104 -3232 -13089 2599 -5842 1788 -697 6841 9577 -2312 23692 -4207 20597 -2454 21159 1460 2169 7545 -20838 -813 -22941 8723 15987 2764 16950 4385 11617 -2436 2362 14095 -12746 21351 -6242 18534 -15179 11884 -6674 -1129 13708 -6100 -1673 SO 20171215T084538.0Z 6558.365023 325 1 32.00 2 89.03 117.92 69.95 92.06 0.00 1 0.00 1 0 15 7.745e-02 7.849e-02 7.219e-02 7.000e-02 -2.434816e+03 4.136762e+03 7.217674e+01 -6.000000e+00 4.300187e+03 286.90 -2.00 20.00 -2.00 505.13 0.00e+00 -1.279297e-03 1.939842e-03 8.366612e-05 -6.000000e+00 2.168896e-03 286.90 -2.00 20.00 -2.00 499.69 0.00e+00 3.471629e+00 1.419567e+00 7.209054e-02 -6.000000e+00 1.523757e+00 229.71 -2.00 3.16 -2.00 501.35 0.00e+00 18.612 0.060 489.00 513.00 1 9.4645e+00 1.0917e-01 2.8473e-02 -6.0000e+00 1.1676e-01 1.1572e-01 2.8522e-02 1.8875e-03 -6.0000e+00 3.0631e-02 8.4922e-06 2.9325e-03 6.5303e-03 3.4389e-05 -6.0000e+00 7.6302e-03 1.0921e-01 -8.8368e-04 12 8 8 10 0 0 74.55 22.86 3.93 0.10921 0.12955 8 2 1 4 0 4000.000 26.73 20.00 22.86 -6630 -3587 -839 55 -7247 6918 16810 1701 713 -351 -5746 3118 -1165 -13346 8668 1396 3468 2988 7149 14354 6898 1235 7027 -65 -551 10555 5361 -27140 -637 3565 1082 4482 -3027 -10472 -941 9229 6503 5411 -3263 1158 20603 -1491 -6824 -6723 3252 -7316 -1029 5799 -1674 -3840 -4552 -755 16776 10966 7878 -12849 1140 -8157 -2667 -5712 9888 -3002 5847 12045 5315 1310 6554 5730 -4837 4206 9298 3282 2542 6681 1699 -6246 -3031 -978 -5179 -5225 -6695 17748 -1438 -2568 1506 -6737 13839 -12887 3621 -14487 1098 6338 -679 6109 765 -3710 7810 6971 11055 -3243 -31 -11041 -9695 616 -763 -32 12137 2263 -4167 9637 6515 13421 2571 -6543 -2787 203 3233 -5791 -6395 6488 -9399 -260 -6981 -13503 11824 -2820 6568 11331 18184 10176 -5018 -608 -2153 17263 7239 2149 2174 -6006 1710 2536 -5386 12362 -13573 -1179 1945 4409 -6538 3836 10541 -10565 -2090 2292 3130 -7408 -3973 -933 63 -9092 7695 17217 1906 805 -396 -6755 3309 -1274 -16299 8445 1469 3633 3225 7586 14378 7477 1418 7618 -76 -647 11104 5910 -40966 -723 3766 1143 4551 -3364 -12933 -1089 9794 7079 5891 -3821 1282 18659 -1684 -8178 -8118 3585 -9001 -1186 6180 -1892 -4338 -5038 -780 14196 9730 7279 -14986 1188 -9515 -2964 -6531 9634 -3323 5938 11514 5082 1292 6446 5582 -4832 3787 7854 2913 2267 5758 1559 -6267 -2937 -915 -4953 -4929 -6374 13242 -1307 -2379 1350 -6615 11157 -13650 3261 -15655 1017 5598 -649 5528 738 -3755 7000 6218 9291 -3073 -28 -10842 -9354 544 -704 -30 10304 2115 -4092 8100 5587 10762 2326 -6593 -2749 196 3064 -6035 -6719 5982 -10076 -251 -7094 -13624 9785 -2550 5434 8963 13430 8132 -4658 -540 -1937 12680 5784 1778 1781 -5357 1436 2159 -5065 9879 -14187 -1094 1758 3915 -6518 3452 8806 -10702 -1898 1952 2628 SO 20171215T084947.0Z 6558.367905 329 1 32.00 2 88.27 117.34 69.11 91.51 0.00 1 0.00 1 0 15 6.815e-02 6.578e-02 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