File name: Pandora114s1_BuenosAires_20180103_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T023915.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180103_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180103T085226.0Z 6577.369745 241 1 32.00 2 89.77 117.90 75.37 306.57 0.00 1 0.00 1 0 113 7.838e-01 4.295e-01 6.256e-01 4.225e-01 2.228546e+04 3.126143e+04 2.739416e+02 -6.000000e+00 4.395825e+04 287.87 -2.00 20.00 -2.00 505.05 0.00e+00 -7.968163e-03 1.149483e-02 4.277767e-04 -6.000000e+00 2.241421e-02 287.87 -2.00 20.00 -2.00 500.06 0.00e+00 -2.001746e+00 8.026290e+00 3.413013e-01 -6.000000e+00 1.585160e+01 229.87 -2.00 3.16 -2.00 501.74 0.00e+00 19.986 0.075 489.00 513.00 1 1.1407e+01 6.0298e-01 4.1001e-02 -6.0000e+00 1.2065e+00 1.7666e-01 1.5398e-01 5.9161e-03 -6.0000e+00 3.2716e-01 1.1646e-06 1.1461e-01 3.4069e-02 2.6325e-04 -6.0000e+00 7.7412e-02 3.9113e-02 -1.1960e-03 12 13 8 11 8 0 29.33 22.33 6.49 0.03911 0.83408 8 2 1 4 0 4000.000 26.32 20.00 22.33 900000 131149 -13060 108886 2506 -965 -26272 900000 125861 21772 11985 -36058 141389 -7818 79939 23592 -10424 95611 -28062 144697 -55530 900000 20294 122365 50347 34737 53768 129847 44954 25636 80073 84212 8693 34443 -9339 122724 95830 46316 149869 76107 131951 -11551 83771 99004 33589 24076 15127 -25207 -32736 -24872 -31235 27159 85921 28493 22076 85444 103892 111188 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17268 61264 -13149 33461 26546 34225 -46989 -17986 37519 20532 37671 -9037 -5704 -58175 30811 37342 -22477 900000 97597 24608 10777 34465 -36805 -16342 43007 29001 22105 -13831 -7030 -33646 24185 3444 6475 118907 22185 19454 11464 7998 -43023 -44115 27301 -4564 43160 65074 36491 110030 -33601 775 31893 12934 29570 -8340 32690 -19646 900000 26203 53514 10246 14720 -7684 -85607 35551 -60993 18691 -6684 12064 7265 12641 900000 -93707 44114 26604 63794 30581 -7368 98796 -26634 41081 29927 52562 63829 -4069 26171 10344 900000 24987 64498 -35482 -39546 SO 20180103T085636.0Z 6577.372639 245 1 32.00 2 89.01 117.31 76.03 305.86 0.00 1 0.00 1 0 43 8.718e-01 4.260e-01 5.997e-01 3.878e-01 -2.130180e+04 2.294171e+04 2.501425e+02 -6.000000e+00 4.863531e+04 287.87 -2.00 20.00 -2.00 505.42 0.00e+00 4.480970e-03 1.097196e-02 1.015436e-04 -6.000000e+00 2.460911e-02 287.87 -2.00 20.00 -2.00 500.43 0.00e+00 7.962657e+00 7.579566e+00 1.891202e-01 -6.000000e+00 1.701807e+01 229.87 -2.00 3.16 -2.00 502.07 0.00e+00 18.542 0.060 489.00 513.00 1 1.0708e+01 5.8168e-01 3.1412e-02 -6.0000e+00 1.3061e+00 -2.0857e-02 1.4364e-01 3.5607e-03 -6.0000e+00 3.3943e-01 1.3058e-06 3.3596e-02 3.2826e-02 4.2206e-05 -6.0000e+00 8.8234e-02 -7.8076e-02 8.7484e-04 12 8 8 10 0 0 -31.98 22.34 -4.73 -0.07808 0.15496 8 2 1 4 0 4000.000 26.32 20.00 22.34 -18475 900000 -20585 17472 16193 19287 16038 -34266 36843 9279 -16746 4709 23734 13153 58405 101500 -4166 -1033 29479 105071 163012 69886 54557 -14513 -3125 -28313 54596 77918 900000 46415 31794 98455 -40407 85762 -32639 163961 56773 -18773 15752 -2096 384154 -9620 -39634 6447 -2372 76613 189442 29149 -14141 2576 154845 34384 43158 18216 87448 -27737 46939 19674 355 126878 50454 79246 -24616 10542 21865 20124 27293 -28792 143840 -21963 95930 -6591 135379 9177 13486 78372 -27602 150906 -28202 57705 5551 83220 25883 14323 142695 73708 125287 -3991 196200 266731 41631 11898 -45346 115821 -46 7652 100969 11503 127996 -5119 103818 2900 173779 124490 29013 17197 -53426 371336 15950 29876 -4435 33328 -1386 -26164 7503 -37987 130467 11098 56946 -22792 44774 105151 -18713 51877 -1319 46023 28062 -41026 57532 4779 88019 -42493 245967 125991 81800 98700 1306 28351 79440 -23381 45966 -20132 26147 -64 152423 25863 196043 61972 -13930 -3477 15527 10435 -20718 -24571 900000 -29611 17546 16701 19369 16541 -57662 29999 9822 -22726 5112 21258 13209 38045 44078 -5315 -1290 27204 45629 61941 43627 39981 -21271 -4071 -46875 38527 42296 900000 34014 27614 45428 -76770 46554 -57582 62302 40063 -28024 16673 -2674 145971 -13577 -71284 7349 -2944 45746 71984 26899 -18270 2937 58838 27997 32799 17073 45096 -42860 34483 18939 414 48211 35787 42157 -36791 10949 19940 18352 22816 -41574 54656 -28931 38882 -7514 51441 9066 12640 37721 -37758 57341 -38579 33621 5484 37946 20981 13062 54221 37344 47607 -4448 74552 101353 30584 12056 -83855 44010 -57 8916 46040 12530 48636 -6224 42079 3233 66033 47304 24253 15683 -90085 141101 14142 23461 -4740 27017 -1547 -38524 8019 -64053 49575 11070 35162 -30853 30837 39956 -24888 34496 -1503 32790 23992 -70151 36891 5221 41807 -73669 93463 47874 38853 39848 1426 24239 41505 -34426 33841 -28686 23597 -75 57918 23954 74493 38266 -17864 -3963 14750 10656 -29522 SO 20180103T090044.0Z 6577.375509 249 1 32.01 2 88.25 116.73 76.70 305.17 0.00 1 0.00 1 0 156 7.378e-01 3.835e-01 5.093e-01 3.174e-01 3.299708e+04 2.814037e+04 8.950193e+02 -6.000000e+00 4.124735e+04 287.87 -2.00 20.00 -2.00 505.20 0.00e+00 -1.379577e-02 9.078980e-03 9.367942e-04 -6.000000e+00 2.096942e-02 287.87 -2.00 20.00 -2.00 500.05 0.00e+00 -1.685492e+00 6.352632e+00 5.445205e-01 -6.000000e+00 1.450440e+01 229.87 -2.00 3.16 -2.00 501.72 0.00e+00 16.622 0.043 489.00 513.00 1 1.1644e+01 4.9177e-01 5.3291e-02 -6.0000e+00 1.1162e+00 6.2119e-02 1.2158e-01 9.1572e-03 -6.0000e+00 2.9140e-01 1.6104e-06 -1.3009e-02 2.3036e-02 2.6701e-04 -6.0000e+00 7.3787e-02 1.5001e-01 6.8133e-04 12 9 8 11 8 0 99.51 22.34 -29.90 0.15001 0.05977 8 2 1 4 0 4000.000 26.32 19.99 22.34 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