File name: Pandora114s1_BuenosAires_20180107_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T024540.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180107_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180107T085545.0Z 6581.372049 244 1 32.00 2 89.77 117.32 39.23 355.91 0.00 1 0.00 1 0 72 1.031e+00 5.849e-01 7.176e-01 4.886e-01 -2.920070e+04 3.209538e+04 3.526311e+02 -6.000000e+00 6.132416e+04 288.07 -2.00 20.00 -2.00 504.92 0.00e+00 2.349250e-02 1.381424e-02 1.146091e-03 -6.000000e+00 3.019477e-02 288.07 -2.00 20.00 -2.00 499.99 0.00e+00 -1.495243e-01 1.122709e+01 2.084811e-01 -6.000000e+00 2.203488e+01 229.90 -2.00 3.16 -2.00 501.49 0.00e+00 19.978 0.075 489.00 513.00 1 1.1087e+01 8.6173e-01 4.0671e-02 -6.0000e+00 1.6767e+00 2.6475e-01 2.2484e-01 3.2563e-03 -6.0000e+00 4.6311e-01 8.4344e-07 7.4993e-02 3.2744e-02 4.8294e-04 -6.0000e+00 1.0785e-01 8.4207e-02 -2.4317e-03 12 13 8 11 8 0 80.94 22.30 5.32 0.08421 0.60439 8 2 1 4 0 4000.000 26.32 20.00 22.30 900000 900000 94363 37046 172582 -2304 75791 84910 82091 79651 98340 48687 2278 47064 -32986 214534 -19664 -61759 10122 -7981 133648 -11995 91796 162076 67659 72265 -38180 280183 63299 137989 70226 870 -15596 7870 244151 -8128 112321 74831 64185 -8454 87092 46985 1779 75441 -23985 900000 64306 -26903 165609 -59386 287280 92640 900000 47849 38730 17103 68269 900000 -7606 5323 -13037 -1071 44324 10872 173161 -54426 900000 33343 39418 -29338 -19256 33568 -1040 42653 -1238 179193 -14462 34254 148131 116529 116745 -4834 900000 7937 284327 -25463 -21231 900000 3305 354146 161712 16332 115867 -55207 900000 84340 900000 26441 900000 52791 16980 14084 -39457 900000 59369 39696 149990 -4322 122518 -24435 118054 -45514 25827 27482 78659 2542 -41759 900000 291834 900000 247702 -13039 103462 6162 252917 16637 900000 -37206 92815 -12224 17226 29530 23654 162302 10031 190312 156390 -21695 96742 16656 26569 13968 -9010 900000 900000 45121 11310 900000 -62271 -9822 64783 157676 108941 900000 900000 48287 34122 82425 -3145 46540 46346 44808 43476 46967 34880 2564 33717 -52889 102462 -28175 -134840 10704 -10074 63831 -15959 43842 77408 41547 41910 -65124 133816 36710 65904 38332 979 -21282 8591 116607 -10260 53645 40845 39413 -10229 44566 36866 2096 46325 -37420 900000 40950 -41974 79095 -122906 137205 44245 900000 35041 32062 17971 43474 900000 -10413 6440 -19095 -1398 36694 12462 82702 -116107 900000 28665 31377 -45773 -26977 27789 -1225 32594 -1458 85583 -18879 27266 70748 55654 55758 -5695 900000 8087 135795 -35673 -28391 900000 3473 169141 77234 16121 55339 -123047 900000 51023 900000 28624 900000 40341 17841 14799 -64778 900000 35916 26069 71635 -4129 58515 -29176 56383 -73364 21586 23790 42264 2959 -74791 900000 139380 900000 118303 -15958 49414 6438 120794 15892 900000 -61083 44329 -15691 16455 24681 20476 77516 9282 90893 74692 -27199 46204 14419 20620 12091 -9682 900000 900000 28284 9790 900000 -104093 -9382 30941 75306 52031 SO 20180107T085955.0Z 6581.374942 248 1 32.00 2 89.00 116.73 39.29 354.30 0.00 1 0.00 1 0 57 6.947e-01 3.908e-01 5.840e-01 4.139e-01 2.881296e+04 3.505052e+04 8.198896e+02 -6.000000e+00 3.890634e+04 288.07 -2.00 20.00 -2.00 505.26 0.00e+00 -7.445917e-03 1.099006e-02 5.950573e-04 -6.000000e+00 1.967358e-02 288.07 -2.00 20.00 -2.00 500.27 0.00e+00 4.989674e-01 8.244255e+00 7.319304e-01 -6.000000e+00 1.367390e+01 229.90 -2.00 3.16 -2.00 501.91 0.00e+00 18.524 0.059 489.00 513.00 1 1.1426e+01 6.2548e-01 6.2475e-02 -6.0000e+00 1.0492e+00 4.1154e-02 1.5574e-01 1.1032e-02 -6.0000e+00 2.7147e-01 1.2435e-06 -7.5770e-03 3.0700e-02 2.1339e-04 -6.0000e+00 6.8557e-02 -1.6636e-01 1.4610e-03 12 9 8 11 8 0 99.06 22.28 -1.34 -0.16636 -0.21892 8 2 1 4 0 4000.000 26.32 19.99 22.28 60404 -12034 140287 -23913 4865 -28650 70845 45889 8320 28164 17962 11254 -7528 49908 -23878 27819 121377 68357 57975 -2912 -49041 -35348 15355 5518 36060 310048 15071 -33186 39388 125030 18620 4469 29072 29156 20662 19732 51346 1624 38627 88444 15549 900000 18277 40527 217029 -86 17001 55247 42362 -46972 71214 90494 -8504 225616 6962 12522 -29701 59538 24232 -23251 26888 -29070 -19321 24600 -4161 -179 262440 48862 105496 900000 -17571 110324 14376 -5602 40271 82120 87734 -17604 127677 13188 -41104 -47969 15621 -4902 18528 30119 -8619 78600 109264 78224 42474 -4162 900000 -31508 22172 -2784 16904 -40969 76085 211890 35741 -483 1261 -11006 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39492 10249 17781 -1415 63056 33777 5941 24136 25382 15573 3507 38381 -13121 619 44015 38513 30951 -36035 37504 20433 19392 28570 21872 34763 -12977 58397 -56857 43641 -47362 -22394 6628 41280 41642 40781 30296 -30581 33562 -70510 23726 41489 SO 20180107T090357.0Z 6581.377743 252 1 32.00 2 88.26 116.17 39.37 352.75 0.00 1 0.00 1 0 135 7.605e-01 3.968e-01 5.765e-01 3.648e-01 -5.222089e+03 1.983942e+04 3.656039e+02 -6.000000e+00 4.281521e+04 288.07 -2.00 20.00 -2.00 505.06 0.00e+00 -5.948294e-03 1.027594e-02 6.576477e-04 -6.000000e+00 2.155450e-02 288.07 -2.00 20.00 -2.00 499.63 0.00e+00 -3.003631e+00 7.445908e+00 1.087128e-01 -6.000000e+00 1.520805e+01 229.90 -2.00 3.16 -2.00 501.39 0.00e+00 16.643 0.043 489.00 513.00 1 1.1833e+01 5.7580e-01 3.0067e-02 -6.0000e+00 1.1671e+00 2.2035e-01 1.5373e-01 1.6958e-03 -6.0000e+00 3.0516e-01 1.3879e-06 -1.9715e-02 3.3101e-02 2.5962e-04 -6.0000e+00 7.4974e-02 -5.2513e-02 -2.6864e-04 12 9 8 11 8 0 -44.57 22.28 9.87 -0.05251 -0.18926 8 2 1 4 0 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