File name: Pandora114s1_BuenosAires_20180109_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T024604.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180109_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180109T085723.0Z 6583.373183 261 1 32.00 2 89.79 116.99 35.34 35.69 0.00 1 0.00 1 0 43 7.269e-01 4.109e-01 6.065e-01 4.156e-01 3.254538e+04 3.049504e+04 4.682129e+02 -6.000000e+00 4.070398e+04 288.17 -2.00 20.00 -2.00 504.91 0.00e+00 -2.349529e-02 1.142955e-02 4.665341e-05 -6.000000e+00 2.081467e-02 288.17 -2.00 20.00 -2.00 500.44 0.00e+00 -8.462292e+00 8.769201e+00 8.755951e-02 -6.000000e+00 1.442865e+01 229.92 -2.00 3.16 -2.00 501.91 0.00e+00 20.005 0.075 489.00 513.00 1 1.2083e+01 6.6829e-01 3.1188e-02 -6.0000e+00 1.1050e+00 2.4410e-01 1.9584e-01 2.0020e-03 -6.0000e+00 2.9408e-01 1.2066e-06 -1.3743e-01 2.4991e-02 9.7300e-05 -6.0000e+00 7.2512e-02 -2.8496e-01 2.4541e-03 12 12 8 10 0 0 39.27 23.23 30.66 -0.28496 -1.23822 8 2 1 4 0 4000.000 27.05 20.00 23.23 92374 76498 35394 900000 -19522 171727 2272 78919 4776 25244 90833 52797 20307 80767 106252 -46642 89501 268337 129110 40057 4476 31779 32032 68026 91164 189240 -27567 -32123 105641 25174 79315 131179 -8466 108135 -14809 11137 30542 -678 -8433 -32017 75637 -19046 7500 82138 5245 -16283 73441 16766 26148 73065 -46599 -24239 32800 104703 166349 -16597 48551 -3691 64742 39190 49883 900000 20951 38265 95711 41897 119232 -31653 -15966 -4296 3756 90582 -21501 33666 -25507 -1765 20470 80104 54119 2628 43379 -29382 -36047 -20053 1657 120376 159291 -14258 16828 -21672 26068 -30362 6559 38619 44607 -14105 -32225 28324 37437 79806 37658 99582 26665 -37567 26819 -5204 43925 -38863 -42177 179915 75288 35544 1011 53404 -3288 39311 900000 215883 -44950 66132 -20595 79150 52227 49727 133276 126089 23666 68816 -6547 80011 63012 63463 70039 20806 -36419 6056 2796 57179 65265 39104 20618 226733 -1942 1066 -20691 -4838 163488 -11630 11543 51660 900000 9872 900000 42975 42262 29845 900000 -27814 69906 2444 39010 5000 22020 42258 36844 20076 44620 46342 -94934 46843 109233 52557 33777 5336 28645 28873 43515 47713 77035 -50499 -62580 52219 27815 50737 53400 -12801 50308 -23252 13277 29306 -868 -11525 -52133 46185 -28945 8955 50155 6406 -24304 46980 17290 24126 44614 -87258 -36179 27594 45666 67717 -22071 32940 -4106 35140 26589 29782 900000 17057 26999 38961 29562 48536 -46386 -19931 -4780 3873 39332 -28592 25581 -34611 -1868 17221 36956 32311 2639 29431 -42261 -56739 -27210 1799 49002 64843 -17412 15070 -28819 21930 -46143 7120 31442 35106 -20288 -55971 26903 32511 45482 32703 45942 24604 -58303 21834 -5164 27417 -51416 -57945 73239 36778 26225 1157 39403 -4517 36006 900000 87880 -91490 43746 -31963 44303 37205 35425 54253 51328 22278 42020 -8494 42749 38476 37136 37421 17998 -55595 6009 2845 33459 34870 26862 16786 92297 -1927 1030 -25269 -5170 66552 -13908 11160 34173 900000 10298 900000 SO 20180109T090122.0Z 6583.375949 265 1 32.00 2 89.05 116.43 34.87 34.20 0.00 1 0.00 1 0 43 5.954e-01 3.358e-01 5.465e-01 4.086e-01 2.979620e+03 2.726391e+04 2.008536e+02 -6.000000e+00 3.346109e+04 288.17 -2.00 20.00 -2.00 505.29 0.00e+00 2.191062e-02 1.198376e-02 1.156322e-03 -6.000000e+00 1.688108e-02 288.17 -2.00 20.00 -2.00 500.41 0.00e+00 4.038073e+00 8.501282e+00 1.708648e-01 -6.000000e+00 1.186676e+01 229.92 -2.00 3.16 -2.00 501.99 0.00e+00 18.644 0.061 489.00 513.00 1 1.0782e+01 6.6095e-01 4.1628e-02 -6.0000e+00 9.0918e-01 5.0098e-02 1.6359e-01 2.1733e-03 -6.0000e+00 2.3806e-01 1.2851e-06 -4.1085e-02 3.3179e-02 2.6268e-04 -6.0000e+00 5.9555e-02 1.2126e-01 -1.1308e-03 12 8 8 10 0 0 97.55 23.22 17.55 0.12126 -0.16373 8 2 1 4 0 4000.000 27.05 19.99 23.22 -21974 23688 48955 29301 -11833 76719 -7048 -36176 73786 -16976 74393 46742 33548 -34644 13231 20791 -22128 -18579 18732 900000 18086 48142 -2606 40203 7617 -30474 42018 -4381 27101 162739 60595 14661 86771 -9791 24602 41406 -14058 -21701 4350 17745 615 2504 25637 -14687 101701 -9880 28137 21763 3292 82846 -32178 900000 -15638 113492 -9730 37206 -10958 20469 10318 82761 -544 7056 56239 97067 115895 21109 24162 44328 3890 -22556 126915 59872 -20497 -20256 16190 -27608 -8077 31004 -33242 8100 49366 36568 22333 100391 12327 40724 52110 26126 900000 160798 54357 14094 9911 -9154 -28285 -30533 120534 5059 1241 25750 24387 -38877 146499 -3172 199230 21458 48808 -25843 38841 -10139 46820 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30560 -22711 26765 -68742 -21808 18788 17994 13855 38157 44909 17024 40118 -33376 37714 33662 39887 25310 5146 38140 -7895 -27795 -35566 30238 15287 16106 10068 -32975 37647 754 916 -33090 31115 -28843 SO 20180109T090505.0Z 6583.378530 269 1 32.00 2 88.37 115.91 34.45 32.79 0.00 1 0.00 1 0 29 4.809e-01 3.088e-01 4.435e-01 3.222e-01 1.242987e+04 2.248040e+04 2.076637e+02 -6.000000e+00 2.696913e+04 288.17 -2.00 20.00 -2.00 504.86 0.00e+00 1.551982e-03 9.366413e-03 3.916906e-04 -6.000000e+00 1.354822e-02 288.17 -2.00 20.00 -2.00 499.96 0.00e+00 -8.473418e+00 6.817915e+00 2.548459e-01 -6.000000e+00 9.534254e+00 229.92 -2.00 3.16 -2.00 501.52 0.00e+00 16.930 0.045 489.00 513.00 1 1.1978e+01 5.2988e-01 3.2984e-02 -6.0000e+00 7.2850e-01 3.0686e-01 1.3614e-01 4.1962e-03 -6.0000e+00 1.9178e-01 1.6616e-06 -6.5079e-03 3.0430e-02 2.1034e-04 -6.0000e+00 4.7588e-02 7.2210e-02 -7.9285e-04 12 9 8 11 8 0 -137.00 23.21 10.04 0.07221 0.02707 8 2 1 4 0 4000.000 27.05 20.00 23.21 7311 19245 16796 66367 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