File name: Pandora114s1_BuenosAires_20180112_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T024028.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180112_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180112T094513.0Z 6586.406400 3 1 32.00 2 81.27 110.29 41.69 72.77 0.00 1 0.00 1 0 36 7.152e-02 7.024e-02 5.581e-02 5.477e-02 3.663030e+03 3.552988e+03 7.643712e+01 -6.000000e+00 3.993660e+03 288.32 -2.00 20.00 -2.00 505.21 0.00e+00 4.828894e-03 1.503652e-03 2.829917e-04 -6.000000e+00 2.009508e-03 288.32 -2.00 20.00 -2.00 500.00 0.00e+00 1.876004e+00 1.093061e+00 1.075914e-01 -6.000000e+00 1.403901e+00 229.94 -2.00 3.16 -2.00 501.64 0.00e+00 6.215 0.002 489.00 513.00 1 1.0986e+01 8.3886e-02 1.3747e-02 -6.0000e+00 1.0768e-01 1.0625e-02 2.1521e-02 1.7093e-03 -6.0000e+00 2.8159e-02 1.0999e-05 1.4042e-02 5.1309e-03 9.5525e-05 -6.0000e+00 7.0445e-03 6.1986e-02 -4.4709e-04 12 8 8 10 0 0 -747.63 23.88 8.68 0.06199 0.15939 8 2 1 4 0 4000.000 27.56 20.00 23.88 -10205 5449 -3728 8427 1124 1771 2870 4992 -206 1760 1497 -7278 -4639 12285 -5832 -2349 -13553 -313 -7424 2540 2555 3317 2699 5681 -1120 -3154 12247 -4831 3975 -4662 804 -2953 -42 -5250 3788 8407 3079 -4276 -3008 -7099 2087 4150 10048 11413 3824 3766 -4030 21363 -11583 4828 -1039 7738 11698 -14658 12291 -12640 12361 -3765 -3623 2299 -901 16921 -7761 12146 -1066 2176 -5640 -1088 -1768 -2710 -3859 -5333 8308 3184 10488 -1020 -10506 11474 -7822 1172 1336 1960 7371 -590 -1974 -4701 -1268 -7390 13702 -221 -7841 8955 -4155 4058 -6012 8187 -12898 2512 -3573 -1288 15324 -9687 5593 8288 6924 3683 645 19106 -6761 2989 -10760 2022 6130 -264 -293 -3028 -2338 2608 1716 3860 -3177 8621 -8534 10267 2586 2898 2446 2726 1427 -10685 4796 3560 8887 -14281 4934 2140 -560 -1968 -11412 5663 441 7683 -303 -8702 8786 4978 -361 -3986 9221 -2244 7401 -11450 -1674 -11701 5517 -4275 8790 1202 1914 3091 5253 -226 1859 1559 -8153 -4998 11080 -6303 -2480 -16347 -338 -8742 2718 2734 3526 2897 5957 -1262 -3624 11966 -5498 4026 -5005 809 -3118 -44 -6031 4053 8605 3295 -4866 -3348 -8207 2211 4351 10069 11437 4175 4124 -4745 19267 -14260 4925 -1093 7283 10467 -17207 11305 -15381 11989 -4339 -4175 2493 -947 15928 -8801 11289 -1123 2190 -6037 -1095 -1767 -2700 -3846 -5368 7331 2992 9255 -1010 -11280 9702 -7899 1073 1219 1782 6381 -556 -1901 -4685 -1225 -7587 11356 -210 -8050 7842 -4210 3840 -6313 7390 -14108 2301 -3392 -1167 11518 -9263 4635 6869 6017 3386 615 15001 -6783 2698 -11192 1879 5574 -261 -293 -3139 -2424 2590 1626 3571 -3120 7867 -8570 8991 2303 2590 2209 2462 1307 -11034 4241 3182 7465 -14883 4176 1845 -497 -1796 -11676 4971 413 6769 -291 -9123 7769 4590 -351 -3990 7950 -2119 6217 -11535 -1544 SO 20180112T095255.0Z 6586.411748 5 1 32.00 2 79.78 109.29 40.20 71.17 0.00 1 0.00 1 0 15 3.259e-02 3.212e-02 2.825e-02 2.801e-02 4.615826e+03 1.820507e+03 4.327433e+02 -6.000000e+00 1.819992e+03 288.32 -2.00 20.00 -2.00 505.27 0.00e+00 2.294336e-03 7.777721e-04 9.193926e-05 -6.000000e+00 9.152233e-04 288.32 -2.00 20.00 -2.00 500.22 0.00e+00 1.375362e+00 5.579859e-01 1.491327e-02 -6.000000e+00 6.375568e-01 229.94 -2.00 3.16 -2.00 501.86 0.00e+00 5.397 0.001 489.00 513.00 1 1.0484e+01 4.3093e-02 8.1518e-03 -6.0000e+00 4.8936e-02 -1.1331e-02 1.0924e-02 6.3366e-04 -6.0000e+00 1.2739e-02 2.2062e-05 9.3305e-04 2.6670e-03 6.1045e-05 -6.0000e+00 3.2063e-03 1.3842e-02 9.4481e-05 12 8 8 10 0 0 -65.43 23.89 5.79 0.01384 0.02031 8 2 1 4 0 4000.000 27.67 20.00 23.89 -424 1823 3090 -2739 -1490 -2159 1551 -34 -1593 4399 -2526 2825 -2733 -1321 -1920 1046 2124 909 3206 -5033 2908 -3944 2490 -48 -2150 2199 -5235 317 -2841 523 1884 3239 1924 2105 3865 -2643 4342 552 -2102 -4827 3145 -514 -3682 -805 -4599 8640 1333 3692 1108 -856 4691 -3170 7074 -4233 -2289 895 -2082 4053 2217 1115 -3428 2251 -1564 3007 4272 -3653 962 372 725 2005 309 2072 757 3047 -4005 -1589 2825 -3445 -4172 -2982 1536 -4611 -2991 -3671 211 -2685 -1566 -2105 -4694 2360 -2036 5494 2352 4995 5007 3716 3608 1462 52 -3976 3883 14 -4499 -2541 -4739 6410 -3069 4978 1315 -2867 7240 834 4 -3065 2422 3280 -1435 -2248 1180 1117 709 1812 1831 -4890 -2790 -2069 -2915 -5792 4388 1024 3494 6454 -6723 -87 -2241 3479 5640 5357 2939 2854 -1735 -4131 -2291 -899 601 -490 -4747 4017 4505 -2508 733 -2478 -232 -401 1732 2997 -2902 -1597 -2379 1669 -37 -1766 4533 -2746 2870 -2896 -1366 -1989 1059 2165 962 3386 -5831 3118 -4533 2689 -53 -2456 2407 -6141 347 -3141 543 1890 3207 1972 2227 4131 -3048 4649 607 -2346 -5495 3304 -528 -3948 -849 -5097 8434 1398 3743 1135 -875 4418 -3144 6214 -4155 -2242 875 -2158 4020 2252 1144 -3676 2286 -1658 3055 4273 -3917 970 371 711 1919 298 1944 720 2865 -4095 -1597 2700 -3446 -4130 -2886 1415 -4525 -2904 -3615 202 -2667 -1550 -2102 -4807 2247 -2026 5099 2280 4782 4828 3609 3448 1394 49 -3813 3371 13 -4207 -2385 -4438 5559 -2978 4453 1206 -2708 6161 763 3 -3014 2284 3093 -1428 -2269 1158 1100 697 1738 1727 -4864 -2703 -1998 -2857 -5864 4017 969 3221 5774 -6828 -82 -2113 3061 4845 4662 2672 2650 -1715 -4236 -2327 -906 600 -497 -5036 3892 4292 -2511 695 -2393 -220 SO 20180112T095930.0Z 6586.416319 8 1 32.00 2 78.49 108.44 38.94 69.74 0.00 1 0.00 1 0 22 4.141e-03 4.102e-03 1.397e-03 1.393e-03 9.462781e+03 9.494606e+01 6.414716e+02 -6.000000e+00 2.312855e+02 288.32 -2.00 20.00 -2.00 505.28 0.00e+00 1.023915e-03 3.839846e-05 7.199203e-05 -6.000000e+00 1.163474e-04 288.32 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