File name: Pandora114s1_BuenosAires_20180120_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T024552.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180120_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180120T090756.0Z 6594.380509 351 1 32.00 2 89.76 114.47 122.01 133.42 0.00 1 0.00 1 0 71 8.042e-01 4.174e-01 5.642e-01 3.833e-01 5.337322e+04 3.373498e+04 2.913431e+03 -6.000000e+00 4.568249e+04 288.57 -2.00 20.00 -2.00 505.24 0.00e+00 -1.971580e-02 1.095459e-02 2.237049e-04 -6.000000e+00 2.317192e-02 288.57 -2.00 20.00 -2.00 500.61 0.00e+00 -1.078989e+01 8.214197e+00 1.331395e-01 -6.000000e+00 1.619206e+01 229.92 -2.00 3.16 -2.00 502.18 0.00e+00 19.963 0.074 489.00 513.00 1 1.2101e+01 6.2538e-01 3.2238e-02 -6.0000e+00 1.2393e+00 2.2236e-01 1.7314e-01 1.9259e-03 -6.0000e+00 3.2469e-01 1.2867e-06 -1.2778e-01 2.0925e-02 4.3334e-04 -6.0000e+00 8.2708e-02 5.7697e-02 1.0849e-03 12 13 8 11 8 0 89.35 22.98 -14.08 0.05770 -0.82863 8 2 1 4 0 4000.000 26.83 20.00 22.98 55721 7211 115178 -24818 255268 -199 69730 36751 -17950 77389 10475 146273 2304 108825 -29434 61820 12588 9232 82705 7488 900000 -28406 54531 22737 40290 33113 4385 900000 -56204 3753 9673 69318 27648 15749 49298 39888 17369 23379 -13826 -234 -38614 105514 17165 104060 765 176142 -2344 -1145 48093 -34563 59557 -23113 75977 49512 51488 213976 8159 69247 -4730 36712 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14760 29690 -11142 3755 14097 54394 -29882 9835 5038 36673 6688 26665 900000 23031 29696 41186 900000 -23614 -46236 100145 -46940 900000 -68006 40212 -3352 8383 69247 17060 31391 11955 12022 45119 -5606 75284 -10624 900000 -79748 13951 55676 -23529 34353 25004 82943 -17800 124574 53098 52439 110941 -7658 48376 -98496 46257 7833 37991 30290 -17618 34342 -33251 46491 -32501 -32780 40132 25904 35982 13153 900000 29832 14321 -4283 38569 30999 34745 -16078 10623 -8330 10466 28441 28285 37513 7974 22413 -6 -44004 900000 900000 SO 20180120T091206.0Z 6594.383403 355 1 32.00 2 88.98 113.89 121.41 132.50 0.00 1 0.00 1 0 79 6.354e-01 3.447e-01 5.239e-01 3.614e-01 5.150666e+03 2.677805e+04 2.063486e+02 -6.000000e+00 3.554715e+04 288.57 -2.00 20.00 -2.00 505.40 0.00e+00 -3.031805e-03 1.009312e-02 1.337002e-04 -6.000000e+00 1.788377e-02 288.57 -2.00 20.00 -2.00 499.87 0.00e+00 -4.563934e+00 7.593215e+00 1.785841e-01 -6.000000e+00 1.239152e+01 229.92 -2.00 3.16 -2.00 501.64 0.00e+00 18.467 0.059 489.00 513.00 1 1.1649e+01 5.8088e-01 3.0962e-02 -6.0000e+00 9.5212e-01 2.6800e-01 1.4819e-01 3.0791e-03 -6.0000e+00 2.4678e-01 1.4665e-06 -1.9305e-02 3.3803e-02 7.2509e-05 -6.0000e+00 6.2682e-02 -1.7586e-01 1.5185e-03 12 9 8 11 8 0 -171.61 22.98 31.09 -0.17586 -0.30976 8 2 1 4 0 4000.000 26.83 19.99 22.98 12553 104487 106688 -28937 80591 6921 94251 -9169 106553 18963 -40624 -28296 900000 -25146 38284 -3874 4964 28472 82955 1049 -7251 -3449 26448 -22239 4026 62021 -227 -6665 18888 60647 40622 -15708 48209 25816 -28855 5690 47245 14890 58857 -8228 11107 140510 15333 40051 60966 15210 -16164 47775 43454 -24391 33431 53673 22027 38231 14271 -5257 -17986 32900 2214 157469 23816 104077 -31350 58507 79296 -40846 57730 24843 154200 -7963 -20311 -15755 -8419 51620 27017 58374 4450 3930 16651 -11799 54660 80738 58889 -7480 19076 20395 96531 386750 116651 116968 -47815 83666 111521 -41882 22066 2042 72354 66174 76366 118974 91512 281 -33247 15101 38451 -1051 -19557 -1355 2543 43818 89264 16696 83950 -20082 81146 61203 29854 24655 12822 6599 -3531 91114 -20524 -10238 114128 37362 22718 5457 28105 43059 4127 -30804 -7837 -6768 -30850 2855 6311 61246 -4979 11078 101903 -32213 25944 32430 -4699 2034 -6290 -14278 -38443 2028 121587 49809 154327 12704 42298 43189 -46856 44859 8230 47693 -13223 48526 20631 -79142 -47967 900000 -40083 31965 -4901 5777 26653 46175 1353 -10274 -4712 26766 -36574 5093 43937 -298 -9274 20071 41429 32889 -21859 35372 24167 -44972 6910 38251 16576 41696 -10493 12365 49771 15207 31210 38871 15445 -22520 34973 32836 -35711 26841 34221 18726 27084 12806 -5835 -23360 26415 2457 55778 21371 41781 -48860 37303 41195 -70413 36808 21706 54620 -9402 -26859 -19718 -9742 32912 22329 35840 4729 4176 15335 -14210 33559 38131 34766 -8655 17117 18301 41031 136992 41319 41432 -88072 41490 42136 -74176 20843 2363 41006 39066 39673 42142 38898 292 -44898 12704 28148 -1117 -25978 -1530 2759 31042 42158 15154 39029 -26675 39522 36583 24454 21287 12490 6866 -4065 40342 -27262 -12013 40426 26468 18609 5316 21777 28598 4020 -42281 -8501 -7192 -40978 2655 5589 31185 -4961 9565 36095 -44215 20103 23692 -4993 2027 -6824 -16753 -57021 1976 43068 28670 54665 SO 20180120T091614.0Z 6594.386273 359 1 32.00 2 88.20 113.31 120.81 131.60 0.00 1 0.00 1 0 57 3.623e-01 2.400e-01 3.273e-01 2.600e-01 -2.327782e+04 1.529587e+04 8.073224e+02 -6.000000e+00 2.025226e+04 288.57 -2.00 20.00 -2.00 505.10 0.00e+00 -2.067771e-03 7.166713e-03 1.244482e-04 -6.000000e+00 1.018842e-02 288.57 -2.00 20.00 -2.00 500.08 0.00e+00 9.307819e+00 5.238441e+00 1.326717e-01 -6.000000e+00 7.097034e+00 229.92 -2.00 3.16 -2.00 501.70 0.00e+00 16.488 0.042 489.00 513.00 1 1.0669e+01 3.9902e-01 2.6635e-02 -6.0000e+00 5.4446e-01 -4.8545e-02 1.0533e-01 3.1338e-03 -6.0000e+00 1.4234e-01 2.1370e-06 -4.9758e-02 2.2199e-02 6.7555e-05 -6.0000e+00 3.5718e-02 1.2779e-01 7.1949e-05 12 9 8 11 8 0 97.03 22.98 -24.56 0.12779 -0.21735 8 2 1 4 0 4000.000 26.83 20.00 22.98 -5326 -3638 56300 -3665 8798 72261 2209 20752 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