File name: Pandora114s1_BuenosAires_20180121_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T024558.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180121_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180121T090851.0Z 6595.381146 356 1 32.00 2 89.78 114.21 131.05 141.57 0.00 1 0.00 1 0 134 8.917e-01 5.233e-01 6.998e-01 5.004e-01 -2.669797e+02 3.049697e+04 1.194846e+03 -6.000000e+00 5.347059e+04 288.58 -2.00 20.00 -2.00 505.27 0.00e+00 4.708410e-03 1.581027e-02 6.853820e-04 -6.000000e+00 2.659928e-02 288.58 -2.00 20.00 -2.00 500.29 0.00e+00 4.091590e+00 1.048279e+01 1.321589e-01 -6.000000e+00 1.848678e+01 229.91 -2.00 3.16 -2.00 501.97 0.00e+00 19.982 0.075 489.00 513.00 1 1.1012e+01 8.2397e-01 3.6544e-02 -6.0000e+00 1.4098e+00 6.4012e-02 2.0526e-01 2.3904e-03 -6.0000e+00 3.6592e-01 8.6389e-07 -3.8643e-02 5.0700e-02 4.1061e-04 -6.0000e+00 9.2121e-02 1.6976e-01 -1.4692e-03 12 9 8 11 8 0 -48.91 23.37 37.30 0.16976 -0.09828 8 2 1 4 0 4000.000 27.15 20.00 23.37 53005 6839 272649 65803 75168 19867 12363 106449 -54150 150247 69445 86959 -10061 45603 82471 -37185 29152 -4808 900000 -7750 -33406 163166 36750 64379 33134 900000 -11467 -22329 -358 -11055 900000 19933 284384 33954 26159 900000 -3511 65843 -31927 31187 -25334 -22082 48843 101586 249025 42333 67090 16173 143622 -3173 900000 -26474 -49239 33974 48734 102866 111382 6370 900000 75355 120565 31287 24023 140878 96909 39356 -54442 66648 60462 49362 900000 245404 -12421 -2916 143735 25823 19249 105154 900000 -15385 900000 60882 900000 128618 -9932 109047 12596 16666 -57222 -27380 29311 -10013 350830 73586 143476 -25749 -17053 -18208 61338 65928 3765 21772 900000 -22378 1270 -21981 20104 8587 62291 112632 26009 900000 141109 -6787 -30850 18530 83108 900000 149390 63900 70002 -41253 45885 3150 900000 72628 14844 5108 41822 900000 10129 7324 196143 900000 20531 27459 -51764 83570 27141 30438 -5355 36992 -32251 -26307 199075 199893 24581 -16628 67972 7393 224252 -31307 -6515 35199 6932 133410 36798 39408 18748 12963 52087 -115447 73518 43689 45589 -13714 35065 43236 -63682 25472 -5881 900000 -10022 -57210 79839 32111 42752 30109 900000 -16432 -33506 -432 -14786 900000 20203 139152 28481 22186 900000 -4238 43724 -53116 27469 -38841 -32415 35053 49707 121851 33143 41582 16882 70276 -4037 900000 -41453 -94766 27706 33385 50334 54500 6649 900000 41788 58994 27556 22726 68933 47419 32096 -113660 41308 39446 35425 900000 120079 -15802 -3329 70331 21902 17581 51453 900000 -20075 900000 35748 900000 62934 -11664 53358 11916 15223 -110131 -39298 23904 -12086 171665 38407 70204 -36957 -22807 -23388 38017 38711 3800 17977 900000 -27375 1204 -26216 15985 7878 34290 55112 20681 900000 69046 -7265 -42456 15867 40666 900000 73098 37129 38535 -69388 32275 3371 900000 37759 13619 5155 29417 900000 9912 7392 95975 900000 18208 22673 -93400 40892 21581 23271 -5896 27151 -48329 -37812 97410 97810 21800 -22375 39496 7913 109729 -48828 -7770 SO 20180121T091245.0Z 6595.383854 360 1 31.99 2 89.04 113.66 130.58 140.52 0.00 1 0.00 1 0 42 8.294e-01 4.405e-01 6.148e-01 3.918e-01 9.185742e+04 4.571311e+04 6.129468e+03 -6.000000e+00 4.636567e+04 288.58 -2.00 20.00 -2.00 505.34 0.00e+00 -2.166783e-02 1.123684e-02 1.299536e-03 -6.000000e+00 2.365925e-02 288.58 -2.00 20.00 -2.00 499.35 0.00e+00 -1.383586e+00 8.562308e+00 1.467025e-01 -6.000000e+00 1.637727e+01 229.91 -2.00 3.16 -2.00 501.09 0.00e+00 18.613 0.060 489.00 513.00 1 1.1565e+01 6.5750e-01 4.2315e-02 -6.0000e+00 1.2585e+00 3.5498e-02 1.6797e-01 6.2755e-03 -6.0000e+00 3.3022e-01 1.2645e-06 1.0646e-02 1.6270e-02 4.3410e-04 -6.0000e+00 8.1951e-02 1.1664e-01 -9.6185e-04 12 8 8 10 0 0 -0.83 23.36 25.72 0.11664 0.19048 8 2 1 4 0 4000.000 27.15 20.00 23.36 -6368 211313 11565 52383 201703 46745 -20396 -4073 93332 44325 69594 -33568 53034 27511 225340 180152 32941 69346 84868 900000 181613 -17324 92398 22730 22135 -14655 -231 -55871 10344 71146 18033 26185 16749 -24681 -18961 -1760 -12174 -16540 49538 -24596 131845 81037 -4944 64148 84480 16949 -3094 90850 -858 7176 -28861 139016 26700 39074 27808 -22225 24478 58328 106935 900000 61127 119038 -3865 -33933 106031 -16552 58944 61426 -17099 146975 72243 -8325 -30169 35932 31649 60436 7721 -10062 54347 -21395 50031 -41641 -19591 -6774 100208 31767 70673 63216 44040 162243 3653 74022 83065 3642 -18415 87000 8037 263643 3915 -1976 25377 -38542 223977 7617 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-112402 40428 -3978 38476 20747 36647 81899 29504 36986 4238 34685 29936 28125 35209 -32333 31756 -28318 28121 22508 -97597 -3366 19074 -54209 26826 33176 -40682 900000 29691 39603 -25862 -38510 48850 44504 57063 46630 50570 -13195 45116 32289 110166 68265 32811 SO 20180121T091628.0Z 6595.386435 364 1 32.01 2 88.34 113.14 130.11 139.53 0.00 1 0.00 1 0 77 5.186e-01 2.903e-01 4.425e-01 3.260e-01 -2.000660e+04 1.830651e+04 3.588090e+03 -6.000000e+00 2.899586e+04 288.58 -2.00 20.00 -2.00 505.34 0.00e+00 4.977739e-03 9.138064e-03 4.144845e-04 -6.000000e+00 1.456930e-02 288.58 -2.00 20.00 -2.00 500.25 0.00e+00 1.370442e+01 6.557228e+00 6.859648e-01 -6.000000e+00 1.011285e+01 229.91 -2.00 3.16 -2.00 501.92 0.00e+00 16.858 0.045 489.00 513.00 1 1.0385e+01 5.1184e-01 5.5770e-02 -6.0000e+00 7.7674e-01 -1.5157e-01 1.2222e-01 8.0514e-03 -6.0000e+00 2.0139e-01 1.6720e-06 2.8918e-02 2.8288e-02 7.2714e-04 -6.0000e+00 5.0927e-02 -1.6693e-02 4.8835e-04 12 9 8 11 8 0 97.79 23.35 -6.60 -0.01669 0.18390 8 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