File name: Pandora114s1_BuenosAires_20180302_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T030901.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180302_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180302 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180302T094737.0Z 6635.408067 281 1 32.01 2 89.75 98.51 86.94 282.31 0.00 1 0.00 1 0 22 3.187e-01 2.380e-01 2.753e-01 2.261e-01 5.712639e+04 2.130761e+04 2.016502e+03 -6.000000e+00 1.779871e+04 288.52 -2.00 20.00 -2.00 505.14 0.00e+00 -1.222795e-02 6.203001e-03 5.633667e-04 -6.000000e+00 8.970167e-03 288.52 -2.00 20.00 -2.00 499.84 0.00e+00 -1.285381e+01 4.585618e+00 3.209153e-01 -6.000000e+00 6.273288e+00 228.74 -2.00 3.16 -2.00 501.48 0.00e+00 19.950 0.074 489.00 513.00 1 1.1677e+01 3.4596e-01 4.2154e-02 -6.0000e+00 4.8072e-01 3.5067e-01 9.3679e-02 6.5559e-03 -6.0000e+00 1.2654e-01 2.5058e-06 -2.8174e-02 1.2247e-02 1.8148e-04 -6.0000e+00 3.1421e-02 1.2876e-01 -1.2527e-03 12 8 8 10 0 0 97.45 22.90 3.62 0.12876 -0.06667 8 2 1 4 0 4000.000 26.83 19.99 22.90 19070 -47585 53889 14059 18409 16047 7480 50803 -12255 18301 43143 38508 713 -1857 20449 981 25366 -29282 6441 -1797 -2819 -12788 -14319 35369 5891 22983 -10828 -14819 30967 24586 58273 -21789 74202 -1516 36326 -10115 24303 19654 -21818 -2224 -1084 34758 16274 -515 25439 -13047 16202 7347 5626 23504 -18535 67704 -22015 -12682 -11228 -15086 13310 16091 -14604 -13473 -1965 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9250 21150 1188 -3198 16653 18329 17631 -27162 14894 10689 17128 7826 -37546 34947 18069 -31305 20007 10553 -252 -63261 41956 10822 28066 39003 4629 -3121 7007 24631 -31443 5584 6165 -1456 5636 14056 22533 -36775 36599 -15720 4780 9849 590 23694 24166 29703 -65277 30343 25760 11103 27933 -9589 2284 -24215 27517 10752 14609 28317 -39673 34398 23342 19316 17754 -10549 5142 10910 9089 -14339 27756 -31773 -25795 26685 -22788 17250 -12502 32394 5587 -30709 4808 14498 21902 -1603 32156 SO 20180302T095143.0Z 6635.410914 285 1 32.00 2 88.92 97.93 87.73 281.73 0.00 1 0.00 1 0 22 2.312e-01 1.956e-01 2.000e-01 1.823e-01 -2.616270e+03 1.024173e+04 4.480291e+02 -6.000000e+00 1.291106e+04 288.52 -2.00 20.00 -2.00 505.15 0.00e+00 6.569555e-03 4.941683e-03 4.960302e-04 -6.000000e+00 6.501522e-03 288.52 -2.00 20.00 -2.00 500.27 0.00e+00 -2.588466e+00 3.586181e+00 7.188934e-02 -6.000000e+00 4.540357e+00 228.74 -2.00 3.16 -2.00 501.83 0.00e+00 18.315 0.057 489.00 513.00 1 1.0767e+01 2.7492e-01 3.0345e-02 -6.0000e+00 3.4813e-01 1.9298e-01 7.2398e-02 1.7234e-03 -6.0000e+00 9.1331e-02 3.1897e-06 1.9702e-02 1.7897e-02 2.2548e-04 -6.0000e+00 2.2775e-02 1.4293e-01 -1.1301e-03 12 8 8 10 0 0 97.89 22.90 26.06 0.14293 0.27959 8 2 1 4 0 4000.000 26.83 20.00 22.90 37839 10069 1827 -6964 -19832 12425 -28559 61208 -1145 24975 20302 10466 17334 -4117 676 -18988 10172 29105 21326 54532 5719 21395 1497 18308 -5247 -8665 -8613 -13796 28364 -8851 1098 -21735 -12584 -3047 -15907 74676 -15014 24404 -8744 6137 20077 -9804 11034 31779 24086 -10461 18414 25401 11527 10465 -3041 11121 -32710 14568 -4832 24895 -3744 19922 34466 -12495 -7253 6307 1255 11621 -25875 1665 -12356 -6611 5742 3421 6122 -5682 21336 -13993 34286 3083 -7102 19336 -10883 -21233 3672 24435 29670 33475 6225 -2430 30495 -4151 65124 -37122 6825 -10493 11263 26155 2759 28748 -8259 43305 -29820 9889 -6363 15693 20593 30115 -11607 -28572 72006 1092 20967 -21673 -2719 39662 -16825 47576 30563 -878 9504 -14422 10500 19130 -4004 2856 504 11569 1290 11148 -14211 21730 37661 7406 25212 -10427 26516 24567 7702 -20032 17841 13379 2550 4025 -19862 45401 -29038 41896 -32202 15676 19450 -20388 3412 13200 46078 16969 33523 26563 9639 1959 -8356 -27590 12686 -44107 38281 -1316 21676 18139 10152 15487 -4519 708 -24478 9997 24147 19326 35497 6058 19388 1662 17292 -5875 -10013 -9850 -16270 21287 -9385 1046 -26410 -14391 -3266 -19708 37362 -18243 19769 -9792 5922 16981 -11328 10516 24986 20659 -12711 16671 21182 10848 9724 -3152 9804 -44421 12495 -5180 20463 -4192 17799 26688 -15480 -8554 6536 1375 11491 -36989 1785 -15014 -7482 5678 3423 5907 -6160 17792 -16836 25732 3159 -7952 16354 -12317 -26559 3587 19502 22620 24724 6081 -2605 23613 -4549 35687 -53066 6749 -11719 11002 22433 2835 22796 -9408 29018 -40630 8835 -6537 12794 16099 21861 -13092 -38610 35383 1074 16625 -26141 -2733 26577 -20294 30817 23893 -951 9340 -18039 10202 16878 -4383 2871 512 10465 1297 10209 -16823 17958 26498 7030 19991 -11762 20433 18931 6881 -23266 14147 11206 2420 3820 -24178 28901 -38915 27606 -44594 13481 16075 -23358 3201 10909 26760 13076 22089 SO 20180302T095545.0Z 6635.413715 289 1 32.00 2 88.09 97.36 88.51 281.16 0.00 1 0.00 1 0 29 1.536e-01 1.414e-01 1.267e-01 1.202e-01 -2.218525e+03 7.442995e+03 3.462530e+02 -6.000000e+00 8.578643e+03 288.52 -2.00 20.00 -2.00 505.42 0.00e+00 5.503908e-03 3.317753e-03 3.267912e-04 -6.000000e+00 4.315339e-03 288.52 -2.00 20.00 -2.00 500.15 0.00e+00 9.524164e+00 2.432730e+00 1.212126e-01 -6.000000e+00 3.003430e+00 228.74 -2.00 3.16 -2.00 501.80 0.00e+00 16.202 0.040 489.00 513.00 1 9.7779e+00 1.8650e-01 2.6601e-02 -6.0000e+00 2.3050e-01 -8.9279e-02 4.7377e-02 2.1040e-03 -6.0000e+00 6.0115e-02 4.9258e-06 2.4065e-05 1.1367e-02 1.4252e-04 -6.0000e+00 1.5112e-02 9.9263e-02 -5.4072e-04 12 8 8 10 0 0 -135.47 22.89 17.64 0.09926 0.09943 8 2 1 4 0 4000.000 26.83 19.99 22.89 -6563 3077 -105 -3925 12837 -4151 -337 -4061 22453 9765 31666 7005 -4434 16446 -10746 13143 -27087 13949 -6948 -9771 16996 -2978 18545 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