File name: Pandora114s1_BuenosAires_20180331_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T030839.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180331_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180331 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180331T101109.0Z 6664.424410 303 1 32.00 2 89.74 84.70 93.29 268.59 0.00 1 0.00 1 0 43 1.933e-01 1.640e-01 1.808e-01 1.677e-01 1.872968e+04 1.364536e+04 1.639427e+03 -6.000000e+00 1.076528e+04 287.44 -2.00 20.00 -2.00 505.39 0.00e+00 4.432549e-03 4.632552e-03 3.773614e-04 -6.000000e+00 5.420598e-03 287.44 -2.00 20.00 -2.00 500.26 0.00e+00 3.456396e+00 3.419078e+00 7.726006e-02 -6.000000e+00 3.760193e+00 227.11 -2.00 3.16 -2.00 501.87 0.00e+00 19.988 0.075 489.00 513.00 1 9.9834e+00 2.6237e-01 3.2511e-02 -6.0000e+00 2.8882e-01 3.1847e-02 6.4955e-02 2.7685e-03 -6.0000e+00 7.4793e-02 3.5391e-06 -1.1121e-02 1.4811e-02 1.8764e-04 -6.0000e+00 1.8995e-02 -1.8450e-01 1.5499e-03 12 8 8 10 0 0 -577.38 22.58 17.72 -0.18450 -0.26164 8 2 1 4 0 4000.000 26.51 20.00 22.58 -23243 20492 3534 -4480 1789 18684 28728 29817 -11099 7561 -7704 160 -8496 4444 -24488 295 29869 7109 27375 3543 25719 -21926 1442 -8914 17229 213 261 -11766 4361 27306 33251 33621 7832 -27016 1985 -15587 30650 -2160 1773 -4155 -15573 42620 -2921 53225 9151 1972 19608 18014 -220 2041 2815 3302 -168 -11556 -10826 19508 -6147 1200 -16827 -1355 -2459 7709 42010 1422 4505 -15529 -7128 -3100 -6654 46994 -10225 -15091 2481 2936 22078 8454 6165 3631 6048 -1329 26344 -11314 30202 -2626 -815 -19677 42 6002 -17773 12005 -35445 21207 12658 25755 30728 -530 19660 -11660 25003 13015 6665 16764 -25572 6827 -21497 21831 17802 8638 6478 -17968 1782 33754 18242 14662 723 -4058 -744 -82 -17642 9408 -9717 28134 6012 11755 28078 5140 4743 -20596 43532 10060 -24444 6861 -27764 3527 30812 27014 9027 -2024 23295 2050 57683 1359 -7513 -8009 11331 -11673 1046 75024 -7223 23479 -3896 -15929 -444 -27841 16123 3403 -4840 1870 16895 23953 24861 -13946 7813 -9137 173 -9877 4488 -32784 309 23501 7179 23146 3869 22652 -31156 1626 -11201 16793 231 284 -14315 4446 21549 24053 23953 7296 -36717 2089 -19988 24860 -2415 1885 -4645 -19458 29897 -3265 34419 9328 2184 18268 16980 -246 2192 2931 3330 -171 -13046 -12222 16678 -7007 1302 -22131 -1530 -2803 7942 30850 1575 4839 -20254 -8437 -3466 -7585 30905 -11768 -18030 2474 2929 18391 8154 6081 3621 5767 -1340 19924 -12401 21848 -2647 -813 -23939 42 5723 -20089 10658 -46984 16968 11099 20043 22902 -501 15730 -11502 16443 9362 4999 11197 -26014 5121 -22311 15478 13719 7456 5725 -20125 1629 22545 14433 12203 698 -4128 -734 -81 -21028 8701 -10983 21682 5683 10267 20485 4700 4386 -24762 27734 8993 -30894 6345 -36232 3334 21846 19708 7885 -1996 18192 2022 33193 1396 -8569 -9300 10945 -14273 1128 38546 -8386 19783 -3994 -18178 -434 SO 20180331T101509.0Z 6664.427188 307 1 32.00 2 88.93 84.13 94.08 268.03 0.00 1 0.00 1 0 29 1.166e-01 1.082e-01 9.180e-02 8.883e-02 1.644309e+04 6.827717e+03 1.207453e+03 -6.000000e+00 6.488293e+03 287.44 -2.00 20.00 -2.00 505.32 0.00e+00 1.902850e-03 2.434346e-03 1.182752e-04 -6.000000e+00 3.269364e-03 287.44 -2.00 20.00 -2.00 500.26 0.00e+00 6.142010e-01 1.780150e+00 7.998477e-02 -6.000000e+00 2.275444e+00 227.11 -2.00 3.16 -2.00 501.85 0.00e+00 18.374 0.058 489.00 513.00 1 9.8273e+00 1.3562e-01 2.8604e-02 -6.0000e+00 1.7464e-01 7.7355e-02 3.5043e-02 2.6824e-03 -6.0000e+00 4.5471e-02 6.8595e-06 -2.5264e-03 7.8886e-03 9.5112e-05 -6.0000e+00 1.1475e-02 7.6660e-02 -3.1639e-04 12 9 8 11 8 0 -53.05 22.57 7.64 0.07666 0.05914 8 2 1 4 0 4000.000 26.51 20.00 22.57 27808 -7699 25422 -1755 9955 10217 -1657 -997 -2955 24252 -2379 1945 -7260 -11513 5802 -9380 13822 -1350 -138 -503 -3342 10884 -13505 17804 3402 14162 -11 -1559 23881 -12742 9977 497 -1673 3348 5264 -5569 -7230 5584 -9335 13769 -19307 -3142 10280 -3421 -5247 8248 12912 -8268 -10176 13604 -15188 15446 -16044 8278 -2301 -2698 1402 -6116 11711 -6800 18436 -13408 10616 -4222 8625 5565 -2334 12012 -2662 13873 -4382 -6274 13928 -10566 -662 -9238 19486 -6053 -15646 21541 16578 -1918 -7711 17539 -16249 11826 -14453 12002 12419 2104 -694 17359 -10844 -6106 5192 1917 -4044 21889 -5548 -7617 5937 -1240 6709 1353 28516 -20327 16813 -10840 -4477 12469 -10079 -442 5973 17617 1548 636 -4496 2526 4391 -9622 -4347 5151 28142 6090 -2650 -2267 -5379 16738 -19076 3792 -3465 1284 16425 -17262 25299 -10933 9522 9454 -5136 -6256 -4627 11137 -7192 19001 -15039 10716 6360 2800 10043 -5816 12451 -2882 27469 20235 -8188 20080 -1877 9720 10167 -1886 -1134 -3418 21116 -2663 2056 -8308 -13605 5738 -10127 12894 -1402 -145 -537 -3686 10425 -16541 16018 3554 13317 -12 -1692 19684 -14719 8976 490 -1719 3381 5378 -6433 -8477 5705 -10945 12708 -24768 -3447 9965 -3852 -6091 8426 12592 -9886 -12227 12635 -18337 13359 -18626 7496 -2351 -2851 1465 -7029 11353 -7934 16694 -16733 10475 -4853 8711 5749 -2574 11295 -2859 12482 -4680 -6774 12289 -11269 -692 -9953 16740 -6192 -17284 17255 12991 -1806 -7721 13744 -18039 10039 -16124 10319 10611 1981 -668 13981 -11684 -6347 4832 1815 -3939 15843 -5102 -6964 4652 -1032 5185 1134 19087 -23340 13815 -11916 -4605 10721 -10805 -433 5559 14764 1533 636 -4747 2501 4325 -11049 -4755 5073 21593 5700 -2668 -2270 -5591 14027 -21592 3632 -3354 1184 13765 -18832 18861 -10919 8239 8283 -4998 -6280 -4645 9697 -7625 15668 -17562 9715 6026 2739 9053 -6047 10586 -2820 19837 SO 20180331T101912.0Z 6664.430000 311 1 32.00 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