File name: Pandora114s1_BuenosAires_20180404_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T031215.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180404_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180404 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180404T101414.0Z 6668.426551 309 1 32.00 2 89.75 82.83 46.71 281.80 0.00 1 0.00 1 0 34 3.153e-01 2.370e-01 2.137e-01 1.807e-01 3.725194e+04 1.670834e+04 2.544916e+03 -6.000000e+00 1.752444e+04 287.25 -2.00 20.00 -2.00 505.43 0.00e+00 6.473963e-03 4.958337e-03 5.510350e-04 -6.000000e+00 8.841969e-03 287.25 -2.00 20.00 -2.00 500.39 0.00e+00 -2.315583e+00 3.673422e+00 1.447476e-01 -6.000000e+00 6.179610e+00 226.88 -2.00 3.16 -2.00 501.98 0.00e+00 20.000 0.075 489.00 513.00 1 1.0392e+01 2.8050e-01 3.5467e-02 -6.0000e+00 4.7379e-01 1.2560e-01 6.8952e-02 4.4579e-03 -6.0000e+00 1.2413e-01 3.2274e-06 7.0305e-03 1.3564e-02 3.1792e-04 -6.0000e+00 3.1068e-02 2.9004e-02 -3.7480e-04 12 8 8 10 0 0 -905.19 22.17 24.71 0.02900 0.07777 8 2 1 4 0 4000.000 26.21 20.00 22.17 59940 1741 15869 12183 22912 16697 22038 25173 -11734 17489 -26127 4036 -5475 -25755 20861 -6750 66358 -41232 39623 -14418 -6256 28273 -6977 48605 -34849 42859 17645 95425 26776 -11720 34116 14428 89987 17154 -7628 22788 -16176 7774 -3247 36271 13939 28489 21659 47342 37672 -11529 60798 2881 55195 -20414 3945 -786 -22558 54188 -21725 76301 3348 14516 -18587 -11381 59888 -12570 48951 -26159 7330 -1680 -25152 45822 3383 51922 -7108 7250 -487 -11694 23260 -1671 44125 -34841 93030 10317 31255 9895 30648 37594 -16504 14314 6834 30327 16941 -6672 25012 -20061 46443 -8597 9802 -13594 -2653 58371 -24633 37699 -6382 58258 36396 46420 -3933 -33729 31997 -11838 60007 6562 12634 -2524 -21332 16991 -15374 89329 -15466 9365 -513 -5932 26765 -5406 46984 3143 25819 12 -24697 22483 -14177 23465 41339 16449 20881 24747 9751 -28717 446 -15626 12200 5361 22515 -1667 12093 14677 -21526 60721 -12896 21061 -14957 -9858 19794 -5144 27381 32609 1740 14255 11715 20292 16055 20354 22612 -15142 16595 -37683 4238 -6234 -35517 17947 -7686 36940 -68858 30078 -18971 -7599 24324 -8562 34437 -53497 32535 17189 42255 23036 -13425 25898 12437 39847 15192 -8918 19912 -20820 7803 -3604 26983 13003 23212 19182 32983 29359 -14839 38050 3197 35847 -27722 4099 -835 -29301 32633 -28475 38742 3637 14398 -25899 -14783 38188 -16625 35260 -40156 8050 -2004 -37423 33006 3675 34335 -8393 7362 -535 -14499 20600 -1914 31784 -54307 39547 9868 23990 9348 23524 27079 -20658 13353 6940 24351 15404 -7564 20379 -23984 30711 -9327 9376 -14899 -2467 29639 -25634 21813 -5299 26829 19743 23639 -3527 -43687 22670 -13367 33215 6175 11189 -2627 -27157 14860 -18551 37578 -18492 8812 -545 -6830 22519 -6224 31208 3132 20008 12 -31715 18169 -16636 18963 27916 14203 17106 19177 8636 -37195 434 -18164 10940 5223 18693 -1790 11513 13811 -29311 36299 -15989 18419 -18545 -11459 16872 -5580 21522 SO 20180404T101814.0Z 6668.429329 313 1 32.00 2 88.93 82.26 47.49 281.09 0.00 1 0.00 1 0 73 1.249e-01 1.158e-01 1.113e-01 1.071e-01 -6.268274e+02 6.410877e+03 5.784371e+02 -6.000000e+00 6.946181e+03 287.25 -2.00 20.00 -2.00 505.28 0.00e+00 1.338241e-03 2.946539e-03 1.021680e-04 -6.000000e+00 3.504044e-03 287.25 -2.00 20.00 -2.00 500.09 0.00e+00 3.882384e+00 2.157283e+00 9.499488e-02 -6.000000e+00 2.446849e+00 226.88 -2.00 3.16 -2.00 501.75 0.00e+00 18.397 0.058 489.00 513.00 1 9.8127e+00 1.6667e-01 2.8535e-02 -6.0000e+00 1.8758e-01 5.9931e-02 4.2398e-02 1.8716e-03 -6.0000e+00 4.9187e-02 5.6471e-06 8.5699e-03 1.0462e-02 1.0366e-04 -6.0000e+00 1.2311e-02 -3.5665e-02 9.0152e-04 12 8 8 10 0 0 49.06 22.17 7.39 -0.03566 0.02378 8 2 1 4 0 4000.000 26.21 20.00 22.17 847 -2294 4354 17648 18937 -19628 -2051 3425 7037 -12657 32996 8869 -4201 11447 17043 2256 -3211 15817 -8562 -1539 -779 -556 13545 -6376 8413 -8582 -3787 -2958 2819 14303 -1755 -1570 10125 -14251 -15429 -12049 -3764 -4976 9501 -10764 -6658 16788 9182 -16103 16362 16789 1788 10354 12522 13576 9228 12028 12600 12747 -4529 8470 -3493 2104 -95 9994 -14739 10520 7100 -3287 -5022 -5988 23218 4397 13004 -19580 2512 -4462 -12624 -2884 -17434 17156 -8291 16969 -13694 -5314 -5070 -3065 -247 -19747 25869 4964 13035 -14867 -3984 3270 2494 20953 1617 18285 -15963 -8587 -3118 -4582 806 3080 23993 16943 -6718 14565 -10085 -2675 -10566 7136 9660 8605 10411 -6465 16429 -1655 26732 -15615 18127 8693 2239 17284 17444 2629 10495 -8300 -3152 -19518 9752 9128 20869 -3420 -705 -8249 -1702 -3981 -8507 44977 -12661 12234 675 5164 2323 -15138 -10652 -8284 6278 16651 19429 7908 -9706 3451 -9524 29659 900000 845 -2444 4474 16282 17613 -27236 -2400 3776 7390 -15949 25986 8781 -4694 10904 15467 2420 -3733 15542 -10130 -1702 -856 -611 13918 -7499 8540 -10274 -4268 -3230 2822 12516 -1806 -1648 9781 -18057 -19982 -15014 -4269 -5644 9245 -12809 -7644 15395 9192 -20968 15463 15749 1928 10075 11659 12165 8398 10441 10850 11154 -4851 8182 -3864 2209 -102 9655 -18263 10163 7107 -3636 -5590 -6623 18854 4248 11379 -23439 2391 -4561 -14140 -2968 -20870 14412 -8822 13780 -14955 -5319 -5075 -3026 -239 -21902 19559 4366 11315 -16001 -3844 2940 2275 16089 1528 14760 -18124 -8960 -3029 -4421 719 2628 16376 12454 -6393 11566 -10524 -2616 -11095 6182 8051 7229 8677 -6492 13370 -1640 20176 -18139 15109 7988 2189 14406 14311 2467 9023 -8606 -3124 -22929 8576 8088 16435 -3434 -689 -8662 -1653 -3893 -8598 26566 -13461 10358 656 4880 2286 -17883 -12094 -8699 6098 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