File name: Pandora114s1_BuenosAires_20180423_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T032828.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180423_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180423 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180423T102903.0Z 6687.436840 447 1 31.99 2 89.75 74.47 163.19 187.76 0.00 1 0.00 1 0 29 5.407e-01 2.876e-01 4.477e-01 3.303e-01 7.659469e+03 2.360172e+04 1.525464e+03 -6.000000e+00 2.993174e+04 286.17 -2.00 20.00 -2.00 505.33 0.00e+00 -5.212230e-04 8.989364e-03 2.387696e-04 -6.000000e+00 1.518858e-02 286.17 -2.00 20.00 -2.00 500.28 0.00e+00 -2.123423e-01 6.430275e+00 2.637277e-01 -6.000000e+00 1.070495e+01 225.84 -2.00 3.16 -2.00 501.92 0.00e+00 20.043 0.075 489.00 513.00 1 1.0956e+01 4.8881e-01 3.6155e-02 -6.0000e+00 8.1802e-01 7.8749e-02 1.2444e-01 3.2284e-03 -6.0000e+00 2.1831e-01 1.7242e-06 5.1722e-02 3.0701e-02 5.7284e-05 -6.0000e+00 5.3284e-02 -3.6251e-02 -7.7571e-04 12 9 8 11 8 0 64.31 22.36 -11.67 -0.03625 0.32251 8 2 1 4 0 4000.000 26.32 20.00 22.36 900000 5716 -2754 58775 -10556 21188 548 -4349 -15205 12857 2308 15541 -5873 -1399 49681 -5845 21647 106486 32168 16986 50806 -33590 33386 -3101 6783 69161 4378 28407 -25261 27734 95475 13779 -11603 43395 -5499 -24779 -24369 9826 -7039 -3018 -9815 -12271 46644 4888 -18432 -25239 28734 91154 19479 11847 30587 8324 119005 -9582 10292 -36509 26033 28858 -20193 21273 -12909 29919 41233 4232 59092 35318 -21596 -22695 37746 22796 22648 -9799 75193 37509 72636 75793 -18440 7789 -9530 165894 -16350 -27210 27118 -18230 81703 -1495 -10471 143595 11351 78802 -7484 25669 82002 -1678 13054 -7682 -721 72394 94832 35807 26643 -20282 88166 -12049 -18520 30934 -3761 4608 -21035 164685 4829 -25988 9374 55861 47041 6989 91853 -14083 17023 152744 12499 98249 -26921 56094 -28151 -24734 -3318 403 12235 -10628 327599 22300 -49718 49766 70645 43382 -2328 9769 -21651 44884 -2592 69439 12183 70792 7421 5585 37528 -10286 -2163 13505 -18046 61898 60251 900000 5551 -2993 35335 -12937 19107 608 -5028 -19338 12189 2401 14015 -6519 -1488 32166 -6758 19521 41859 26777 16496 35244 -54369 27791 -3728 7371 39980 4757 23647 -35047 22445 39738 13382 -15024 33112 -6866 -37243 -36063 10224 -8626 -3559 -12482 -16173 34513 5538 -24662 -35949 25248 42155 18016 11505 24047 8084 38524 -10753 9773 -56730 21912 23666 -27019 18823 -16159 24536 30256 4476 35708 26677 -28430 -29877 26882 18695 18574 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4.8275e-01 3.2304e-02 -6.0000e+00 1.0882e+00 -1.2720e-02 1.2476e-01 4.9063e-03 -6.0000e+00 2.9206e-01 1.7954e-06 4.3568e-03 2.3805e-02 2.5189e-04 -6.0000e+00 7.0733e-02 -6.0041e-02 -9.2093e-04 12 9 8 11 8 0 91.77 22.36 7.27 -0.06004 -0.02982 8 2 1 4 0 4000.000 26.32 20.00 22.36 900000 210187 27287 44611 -13341 -1834 7998 -41500 66126 21415 8606 -13211 41720 68312 11238 81886 -30680 34556 2404 6805 -24175 -7554 39674 -35492 45441 24844 96854 44061 -17838 41973 39383 108463 35158 72702 6078 7600 60977 -25815 190661 -35095 31936 36118 54995 19222 -23518 41889 -15974 302078 -17647 677 94726 -14599 93914 -34030 62007 32571 83198 8775 -12692 38597 -3477 89477 -16367 8278 -13075 26628 56951 -10622 89989 -24451 123047 49210 54051 83055 11737 57603 -92 77172 -13075 35183 85806 -9842 58031 -27880 9156 -31061 327415 47231 47537 48044 -2212 105121 -5197 153755 37785 28408 133102 -38992 900000 31102 115795 20794 61847 59184 -22411 127080 20767 -23660 40939 170532 23890 -10078 19948 -21051 83270 -12274 100320 29908 21338 40566 -49169 132265 9930 50190 -26972 60949 160796 -14218 111635 1969 61927 18582 -8197 32210 -16123 82371 -29601 900000 -21882 3593 21092 -23511 36673 -11385 54904 1861 87667 131512 3433 3616 5346 93946 -14780 900000 62326 21962 31181 -17236 -2175 8809 -76471 42017 21318 9661 -18188 32695 40513 11664 41625 -48087 28545 2801 7783 -38402 -10240 33612 -63898 36574 24732 47183 36396 -27203 34671 32532 43649 29042 41576 6951 8853 42620 -40316 56536 -58970 29086 31365 39604 18620 -35333 35489 -22736 89574 -25467 804 46146 -19336 43761 -51799 38087 25111 42292 9020 -16560 30520 -4193 42452 -22325 8837 -17317 23688 37152 -13438 40916 -34319 38919 32102 33123 37763 10905 34162 -98 38139 -15767 25734 37317 -11090 33268 -38029 8688 -44210 97087 30812 31011 31342 -2405 39483 -5959 45592 29131 24709 42099 -71685 900000 30127 48071 21786 41569 39779 -31567 42707 20116 -32887 30754 50567 19835 -10833 15897 -25750 37038 -14785 40903 25497 20168 31575 -92035 39220 9754 32556 -37989 36146 47680 -18445 41379 2189 37874 17563 -10178 26862 -21813 41218 -44436 900000 -29198 3729 18763 -33550 29225 -14770 36631 2103 42243 41434 3945 4155 5944 41786 -18900 SO 20180423T103701.0Z 6687.442373 455 1 31.99 2 88.18 73.33 163.30 181.53 0.00 1 0.00 1 0 18 2.320e-01 1.872e-01 1.895e-01 1.719e-01 -8.951004e+01 1.260033e+04 8.805635e+02 -6.000000e+00 1.284642e+04 286.17 -2.00 20.00 -2.00 505.17 0.00e+00 -1.934689e-04 4.731210e-03 1.224269e-04 -6.000000e+00 6.483875e-03 286.17 -2.00 20.00 -2.00 500.10 0.00e+00 -1.451356e+00 3.463735e+00 1.719425e-01 -6.000000e+00 4.517465e+00 225.84 -2.00 3.16 -2.00 501.73 0.00e+00 16.474 0.042 489.00 513.00 1 1.0950e+01 2.6497e-01 2.7322e-02 -6.0000e+00 3.4670e-01 1.6689e-01 6.8197e-02 2.3918e-03 -6.0000e+00 9.0091e-02 3.4911e-06 -2.3999e-03 1.6617e-02 1.8242e-04 -6.0000e+00 2.2815e-02 -6.4066e-02 6.4339e-04 12 8 8 10 0 0 36.41 22.36 22.62 -0.06407 -0.08071 8 2 1 4 0 4000.000 26.32 20.00 22.36 -15113 35504 -19392 25045 -19364 25392 42706 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