File name: Pandora114s1_BuenosAires_20180426_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T032833.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180426_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180426 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180426T103123.0Z 6690.438461 393 1 32.00 2 89.76 73.27 134.31 241.79 0.00 1 0.00 1 0 75 3.473e-01 2.384e-01 3.029e-01 2.449e-01 2.402862e+04 2.039149e+04 2.210695e+03 -6.000000e+00 1.924233e+04 285.97 -2.00 20.00 -2.00 505.27 0.00e+00 1.085380e-03 6.841787e-03 1.570902e-04 -6.000000e+00 9.716607e-03 285.97 -2.00 20.00 -2.00 499.99 0.00e+00 -9.194646e-01 5.027392e+00 4.514413e-02 -6.000000e+00 6.767556e+00 225.69 -2.00 3.16 -2.00 501.65 0.00e+00 20.061 0.076 489.00 513.00 1 1.0677e+01 3.8884e-01 3.1311e-02 -6.0000e+00 5.1931e-01 1.4475e-01 9.6829e-02 2.9314e-03 -6.0000e+00 1.3505e-01 2.3845e-06 -2.3456e-03 2.0415e-02 1.9107e-04 -6.0000e+00 3.4163e-02 -4.1407e-01 3.6304e-03 12 9 8 11 8 0 99.88 22.76 -1.55 -0.41407 -0.43034 8 2 1 4 0 4000.000 26.62 20.00 22.76 32323 16790 -3396 86583 -26822 7945 53437 -8283 -14382 19775 25693 5107 44430 -11653 -26822 25521 11552 4499 249 3690 23192 13086 18332 -29891 22500 1669 -20931 -26147 3590 37682 22319 31595 -11330 -5401 -10051 768 8713 31762 74275 -14695 16031 -213 18055 -4749 -15291 87790 -22746 47461 30793 22572 -17020 2030 82213 3818 3421 48619 -18494 17803 9735 38352 49497 1276 29545 33407 8454 -13640 33760 18955 -158 -47129 29181 -33883 13117 19820 50247 20606 -9304 18815 31098 889 -22085 -5373 -11835 4269 92597 -5255 -6224 -2239 40438 605 -32026 40258 -12162 34347 27845 5108 31967 16811 27310 -6688 -17417 23162 -6853 23042 -30168 47250 -8394 71013 -17161 9841 8685 27626 26405 36534 164636 -9511 22624 -13796 -5519 22998 50707 -1302 -4028 -2978 12769 -20599 -12292 19473 10630 113678 6722 -23617 -31094 -6571 7212 20492 43805 99343 21878 10918 66375 -7031 43867 -25868 19340 22542 16649 -29971 75124 -437 3140 4961 900000 24384 15257 -3901 41565 -40928 8717 37564 -10793 -19726 18986 22906 5516 31994 -14585 -39089 22315 11883 5091 299 4302 22267 13910 18544 -49197 21988 2003 -29140 -37656 3734 29073 19898 26001 -13779 -6396 -12706 872 9063 25921 42024 -18812 15135 -239 17046 -5700 -20553 42144 -32758 33417 25130 19504 -21243 2047 36836 3787 3504 32676 -24859 16808 9970 29458 34058 1429 25058 27263 8794 -17461 26471 16986 -169 -79942 22881 -49883 12174 17444 32966 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3.0536e-01 1.4138e-01 6.0353e-02 2.2216e-03 -6.0000e+00 7.9716e-02 4.0445e-06 -1.1460e-02 1.3172e-02 1.2548e-04 -6.0000e+00 2.0062e-02 -6.3473e-03 4.1774e-05 12 9 8 11 8 0 11.32 22.76 8.74 -0.00635 -0.08584 8 2 1 4 0 4000.000 26.73 20.00 22.76 55835 1965 28242 -11195 4717 8097 10065 13374 -19761 18348 -10206 19748 28944 12533 60426 -19321 3462 -2338 13883 7862 11769 2414 -4576 26053 3007 34031 -6917 -37067 -12009 12790 5737 -2070 -5 -19340 21124 4496 13188 19973 -6623 -11069 -5172 38377 -5496 -1835 5742 -17142 31562 3482 39070 -38114 37977 -233 28687 12562 10248 -133 -11377 -11833 -27805 12949 -8832 -6444 15147 -4757 31591 15771 1340 20842 14911 24827 -2362 30025 -9457 32202 62076 -4080 13094 -31276 5469 652 6455 20425 -5926 -4526 7139 29033 -8526 -9327 5627 -478 12870 -23309 -13550 14851 16938 -10056 -1492 2813 -5048 15599 -7967 -1383 -5451 945 26524 -8102 17562 5838 15034 15523 -1528 -2788 -27084 15046 12797 8083 36500 -10717 -10004 -1911 14328 -785 22610 -18300 39292 -27088 21329 1707 -7966 -27507 4050 14097 5454 37536 15905 5584 -3242 4957 -3640 -3601 41524 -4033 23778 11896 -17766 17483 -12390 -10984 9721 51047 35111 -6466 59075 31980 1944 22058 -13406 4962 8432 10482 13649 -28193 17769 -12966 18303 24114 12138 35868 -25352 3641 -2654 13735 8433 12256 2765 -5623 23604 3445 28706 -8203 -59085 -14707 11934 5576 -2133 -5 -24249 18273 4719 12818 18054 -7725 -13340 -5831 27976 -6250 -2033 5972 -22659 25768 3757 29241 -60755 27684 -242 21749 10989 9163 -134 -13269 -14261 -39998 12460 -10559 -7516 14281 -5502 25485 14868 1446 18232 13624 20270 -2502 22763 -10571 23787 34391 -4442 12091 -44687 5316 653 6023 16478 -6220 -4707 6662 22011 -9530 -10606 5524 -497 11634 -28248 -14940 13280 14982 -10904 -1455 2538 -4738 11513 -7259 -1160 -4719 775 17402 -7899 13922 5373 12740 13013 -1503 -2769 -34551 12750 11195 7439 25277 -11913 -11121 -1985 12794 -815 18336 -21844 25778 -34062 16520 1618 -8348 -35090 3765 11817 4970 24626 12754 4885 -3073 4336 -3515 -3544 26486 -4116 18634 10623 -21531 14975 -14339 -12511 8947 30700 24315 -6658 31221 SO 20180426T103921.0Z 6690.443993 401 1 32.00 2 88.19 72.13 135.67 239.92 0.00 1 0.00 1 0 22 1.150e-01 1.111e-01 1.038e-01 1.003e-01 1.728656e+04 7.792883e+03 1.120401e+03 -6.000000e+00 6.359298e+03 285.97 -2.00 20.00 -2.00 505.44 0.00e+00 3.279831e-03 2.777018e-03 2.433768e-04 -6.000000e+00 3.213520e-03 285.97 -2.00 20.00 -2.00 500.33 0.00e+00 3.949732e+00 1.977558e+00 2.186487e-01 -6.000000e+00 2.248915e+00 225.69 -2.00 3.16 -2.00 501.95 0.00e+00 16.524 0.042 489.00 513.00 1 9.9343e+00 1.5226e-01 3.0463e-02 -6.0000e+00 1.7241e-01 -2.4586e-02 3.7098e-02 4.5880e-03 -6.0000e+00 4.5100e-02 6.1395e-06 3.4552e-02 8.9759e-03 9.6080e-05 -6.0000e+00 1.1327e-02 7.2277e-02 -5.3953e-04 12 8 8 10 0 0 99.32 22.77 2.99 0.07228 0.31194 8 2 1 4 0 4000.000 26.73 20.00 22.77 12539 20065 11646 -20862 -333 13608 7762 -1292 -3354 3963 14534 -4283 -1446 15082 -10877 -19756 2896 -13613 -15255 1923 -2129 -2147 -8992 10613 -2876 8343 -3100 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