File name: Pandora114s1_BuenosAires_20180518_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034711.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180518_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180518 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180518T104831.0Z 6712.450359 479 1 32.01 2 89.76 65.79 125.64 87.57 0.00 1 0.00 1 0 22 1.248e-01 1.167e-01 1.212e-01 1.163e-01 -2.898480e+03 6.982704e+03 4.045398e+02 -6.000000e+00 6.863983e+03 284.53 -2.00 20.00 -2.00 505.23 0.00e+00 -6.129689e-04 3.225125e-03 2.206048e-05 -6.000000e+00 3.478255e-03 284.53 -2.00 20.00 -2.00 499.90 0.00e+00 3.358699e+00 2.364947e+00 2.123505e-02 -6.000000e+00 2.444266e+00 224.65 -2.00 3.16 -2.00 501.59 0.00e+00 20.114 0.076 489.00 513.00 1 9.7006e+00 1.8263e-01 3.0841e-02 -6.0000e+00 1.8718e-01 1.0872e-01 4.6745e-02 1.7566e-03 -6.0000e+00 4.9199e-02 5.3049e-06 6.8503e-03 1.1153e-02 4.4428e-05 -6.0000e+00 1.2298e-02 6.7185e-02 1.7126e-04 12 9 8 11 8 0 -808.52 20.76 12.68 0.06719 0.11470 8 2 1 4 0 4000.000 24.96 20.38 20.76 4443 22874 14141 13290 -16211 5994 -1181 -10654 18635 -4088 15859 -6019 102 -336 3288 -17963 -9750 -1467 -2897 5023 7280 -2336 3429 -8702 11014 -11698 31985 28824 -9863 14761 -6851 1476 3271 -13527 11796 -10889 -3823 11257 5660 2332 21513 -5648 11734 7346 624 14245 -2822 -1098 -20515 -9549 3487 20309 20656 6933 -1217 9210 -1846 5190 2718 29211 -6048 13574 -748 7035 42 -22364 -14843 -1029 -1564 5882 15425 3338 1064 22373 -7270 13411 -8116 -7758 7001 -4751 -15416 -709 43 -13880 3352 -9406 13933 2504 -10626 5305 457 12861 -10611 239 -7345 -10702 13479 26305 6744 -7344 23069 -13966 -9235 16456 -19571 34833 9896 290 4154 1058 -2927 13129 10679 9874 -6723 -5259 11510 -3309 -14211 16944 10430 14931 -4978 20966 5886 7228 7441 -8897 21124 -9149 -2767 2159 -12614 6530 9256 18581 -12947 -10311 2943 5577 15860 -18361 19666 12604 4749 -16712 18803 -8457 534 9764 -17285 24214 900000 4376 19364 13468 13090 -21905 6587 -1403 -13876 17900 -4858 15233 -7105 112 -370 3506 -24127 -12382 -1755 -3324 5724 8119 -2680 3725 -10710 11129 -14753 25758 23432 -11465 13121 -7548 1525 3429 -17265 11829 -13650 -4415 11033 5805 2462 18796 -6522 11500 7590 692 13744 -3195 -1201 -26652 -10810 3365 16201 16321 6374 -1248 8747 -1992 5245 2808 23080 -6801 12582 -802 6949 44 -28885 -17479 -1040 -1569 5407 12774 3119 1027 17678 -7788 11616 -8571 -8016 6170 -4692 -16983 -678 41 -14433 2961 -9514 11214 2265 -10974 4686 426 10718 -11337 232 -7691 -11510 11233 18923 5764 -7062 16103 -14125 -9078 12893 -22582 23570 8528 270 3668 957 -2772 10754 9127 8650 -7039 -5469 10165 -3394 -16195 13999 9064 12230 -4928 15979 5240 6383 6572 -9252 16250 -9515 -2700 1999 -13387 5628 7647 13896 -13372 -10576 2704 5085 13217 -21709 15968 11042 4532 -18709 15670 -8617 487 7920 -18076 16719 900000 SO 20180518T105230.0Z 6712.453125 483 1 32.00 2 89.02 65.22 124.86 87.05 0.00 1 0.00 1 0 22 6.205e-02 6.237e-02 7.047e-02 6.926e-02 6.919433e+03 4.759825e+03 4.913147e+01 -6.000000e+00 3.413100e+03 284.53 -2.00 20.00 -2.00 505.28 0.00e+00 1.607462e-03 1.898522e-03 1.250935e-04 -6.000000e+00 1.726278e-03 284.53 -2.00 20.00 -2.00 500.19 0.00e+00 2.865377e+00 1.381631e+00 1.380339e-01 -6.000000e+00 1.204447e+00 224.65 -2.00 3.16 -2.00 501.80 0.00e+00 18.670 0.061 489.00 513.00 1 9.3670e+00 1.0588e-01 3.0109e-02 -6.0000e+00 9.2425e-02 6.0793e-02 2.6961e-02 2.6392e-03 -6.0000e+00 2.3961e-02 9.1029e-06 -8.8045e-03 6.3982e-03 5.0225e-05 -6.0000e+00 6.0893e-03 4.5458e-02 1.1739e-04 12 9 8 11 8 0 28.77 20.77 4.79 0.04546 -0.01561 8 2 1 4 0 4000.000 24.96 19.49 20.77 10448 -16877 -1235 8261 -8464 2755 2209 -10134 2367 -4668 -198 -6268 6761 5224 -5332 6530 4327 13083 -4701 10658 1748 4909 3360 -1249 534 2045 6899 8654 4423 2917 -3912 465 -17174 10904 -6251 -6203 -1151 -1300 2952 298 2578 -2945 6091 -1640 4521 -3385 -2994 9216 -415 -3644 -2480 4473 7015 -4457 10922 -8511 3808 1041 2273 -2360 -518 14845 -6862 7201 3997 -2304 7540 1380 -8933 -509 -6900 3226 4003 8156 5141 6572 -9024 3739 -7972 15509 -7891 3981 4391 -3807 -717 7376 7765 -5462 -696 -3215 107 -14297 -5647 4917 -5668 -686 1922 -11073 2209 -1308 6063 -2083 5567 -573 718 3338 4616 2081 4026 -2182 -5872 4558 6443 3815 11616 -2872 10086 7470 -4915 2386 1029 -2966 -7467 -3332 -374 2456 9184 -1997 -5091 1359 6227 -1736 10699 5880 2506 -1382 -8168 -387 -9855 2374 3763 -4725 8670 -307 -837 583 5532 -10574 -5847 3315 -1733 3996 -3001 9119 -19805 -1281 8052 -10014 2979 2442 -12776 2629 -5500 -220 -7295 6819 5294 -5575 6088 4191 11901 -5234 10322 1859 5066 3528 -1379 582 2203 7056 8617 4504 2930 -4108 465 -20831 10314 -7243 -7299 -1286 -1442 3099 318 2684 -3252 6203 -1826 4788 -3907 -3442 9301 -454 -4041 -2649 4332 6477 -4579 9738 -9476 3860 1107 2407 -2617 -563 13840 -7981 7300 4179 -2544 7439 1424 -10067 -521 -7433 3110 3822 7530 4646 5911 -9458 3395 -7982 12108 -7734 3463 3820 -3619 -666 6384 6754 -5447 -662 -3124 100 -15529 -5679 4506 -5820 -666 1786 -11417 1940 -1160 4888 -1794 4440 -496 637 3002 4211 1960 3690 -2102 -5830 4100 5768 3561 10153 -2924 9072 6941 -5214 2369 1035 -3071 -7952 -3350 -362 2314 8144 -1991 -4940 1237 5396 -1629 8844 5048 2191 -1242 -7829 -346 -9878 2152 3426 -4755 7721 -302 -832 575 5214 -11696 -6117 3111 -1674 3590 -2888 SO 20180518T105634.0Z 6712.455949 487 1 32.00 2 88.26 64.64 124.07 86.53 0.00 1 0.00 1 0 15 4.942e-02 4.752e-02 5.094e-02 5.043e-02 4.278871e+03 3.221094e+03 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