File name: Pandora114s1_BuenosAires_20180520_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034728.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180520_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180520T104958.0Z 6714.451366 485 1 32.00 2 89.77 65.26 147.32 110.62 0.00 1 0.00 1 0 36 9.628e-02 9.031e-02 8.494e-02 8.266e-02 7.643989e+03 5.747559e+03 3.229491e+02 -6.000000e+00 5.291786e+03 284.43 -2.00 20.00 -2.00 505.22 0.00e+00 4.141946e-03 2.233321e-03 3.045489e-04 -6.000000e+00 2.678194e-03 284.43 -2.00 20.00 -2.00 500.04 0.00e+00 1.378588e+00 1.647703e+00 7.974300e-02 -6.000000e+00 1.873554e+00 224.61 -2.00 3.16 -2.00 501.66 0.00e+00 20.123 0.076 489.00 513.00 1 9.4089e+00 1.2610e-01 3.2241e-02 -6.0000e+00 1.4369e-01 1.1963e-01 3.1775e-02 2.1616e-03 -6.0000e+00 3.7385e-02 7.5759e-06 2.2577e-02 7.7254e-03 1.0479e-04 -6.0000e+00 9.4630e-03 9.0713e-02 -3.4066e-04 12 8 8 10 0 0 -312.13 20.77 10.94 0.09071 0.24731 8 2 1 4 0 4000.000 24.96 20.15 20.77 -5194 15427 4709 -3464 3906 -2725 -7055 -5736 11451 -2053 -1447 -11679 1754 6147 -5217 -3142 -1281 -3117 -597 -3471 15728 4498 9358 505 -3450 -6959 2128 -88 -3467 -17791 14782 6974 -1293 -1092 3788 -6241 324 12753 4081 2342 -6550 32539 27286 10730 11624 -1494 2700 -8624 -7710 9883 12776 -4785 1132 -14394 2385 4847 2517 3258 -6085 9972 -5650 14726 -12237 -3312 -680 3782 -15513 -3247 6109 12513 -8124 518 3285 7733 11312 4438 -6405 14409 -2702 -3007 -663 10193 6690 -15245 -7708 2638 2055 13170 8522 20984 -17261 -9903 -19075 901 3249 14201 13292 1527 -850 -14772 -741 -2027 3900 -5598 6883 1469 -7223 -152 -8784 -4463 23423 18598 13352 -8763 9276 -2221 3119 36021 44 5906 2703 4652 -7477 -8696 8655 11612 10201 3654 -2706 -9155 5990 6256 -7910 -160 4567 -2871 -13873 10539 8282 -6819 -4243 5105 -4369 -9917 -3115 5314 4615 -44 10093 8673 7898 -1155 -16961 -5681 14196 4960 -4049 4318 -3249 -8778 -6971 11532 -2328 -1607 -14194 1847 6190 -5552 -3344 -1370 -3451 -648 -3882 14528 4664 9301 551 -3914 -8120 2230 -92 -3633 -21238 12855 6743 -1404 -1209 4011 -7248 349 11986 4166 2442 -7536 25662 22993 10780 11616 -1695 2902 -10202 -8829 9235 11317 -4988 1119 -17027 2460 5000 2692 3466 -7099 9911 -6592 14079 -15334 -3774 -745 3902 -19105 -3491 5907 11220 -8908 523 3265 7435 10510 4090 -6455 11602 -2559 -2847 -614 8517 5827 -16675 -7885 2444 1915 10938 7379 16046 -19493 -10531 -22506 872 3027 11578 10635 1338 -745 -14587 -631 -1765 3298 -5415 6065 1383 -7388 -143 -8941 -4362 17555 14881 11427 -9452 8408 -2272 3048 25537 45 5623 2615 4335 -7763 -9116 7670 10056 8989 3442 -2553 -9207 5167 5337 -7653 -141 3809 -2586 -14150 8590 7026 -6825 -4186 4623 -4373 -10540 -3102 4863 4223 -42 8418 7193 6550 -1057 -18512 SO 20180520T105404.0Z 6714.454213 489 1 32.00 2 89.00 64.67 146.56 109.65 0.00 1 0.00 1 0 15 5.613e-02 5.601e-02 5.268e-02 5.193e-02 4.616148e+03 3.395716e+03 3.801537e+02 -6.000000e+00 3.084747e+03 284.43 -2.00 20.00 -2.00 505.25 0.00e+00 1.718444e-03 1.417822e-03 1.056538e-04 -6.000000e+00 1.561217e-03 284.43 -2.00 20.00 -2.00 500.11 0.00e+00 2.472295e+00 1.031457e+00 2.862221e-02 -6.000000e+00 1.091944e+00 224.61 -2.00 3.16 -2.00 501.74 0.00e+00 18.640 0.061 489.00 513.00 1 9.1017e+00 7.8927e-02 2.8287e-02 -6.0000e+00 8.3750e-02 8.2555e-02 2.0413e-02 1.6867e-03 -6.0000e+00 2.1783e-02 1.2317e-05 -1.2595e-03 4.8662e-03 5.2117e-05 -6.0000e+00 5.5158e-03 8.2291e-02 -2.7431e-04 12 8 8 10 0 0 66.97 20.77 5.17 0.08229 0.07355 8 2 1 4 0 4000.000 24.96 19.93 20.77 8143 -3126 6622 1932 -531 -1008 -3603 2133 670 8575 2354 3297 -11502 4452 10559 -2275 -8814 6784 -1378 -315 565 -258 -7700 12426 -916 4724 4867 -12536 1660 -3181 2981 -1597 -4221 13458 1914 5185 -8597 5577 -7500 4872 -6106 -1361 -2767 3032 6642 -3813 -2590 -1533 10593 -421 -2189 -4003 -6584 8538 -7369 1339 7457 -1179 5014 -2938 7980 -502 4972 -5823 -1383 3234 3650 6684 -4870 -2960 4536 4068 700 -5520 3321 -9631 6795 5042 -3917 9738 -3873 -710 -3895 2942 -3345 1280 -6435 -8899 14195 -6137 -3953 -5665 5331 5618 -10683 5312 4920 6418 4229 -712 1845 -2420 -8661 -4313 2853 5662 -905 36 5640 -1404 -483 2032 3920 520 809 8285 6170 2868 392 -1146 4979 -3314 2623 901 -6315 -907 -5885 5110 -8058 4203 -5187 -4293 -2529 -3133 6691 -2992 6009 -871 -11914 263 -7528 167 -1944 7547 -1007 14122 10007 1451 4090 -720 540 -3065 4248 7521 -3319 6597 2079 -560 -1091 -4060 2280 723 8439 2428 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