File name: Pandora114s1_BuenosAires_20180523_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034753.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v3d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180523_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180523T105209.0Z 6717.452882 474 1 32.00 2 89.76 64.51 152.88 191.72 0.00 1 0.00 1 0 15 7.317e-02 7.174e-02 7.940e-02 7.795e-02 1.051743e+03 4.685082e+03 5.358302e+01 -6.000000e+00 4.020561e+03 284.27 -2.00 20.00 -2.00 505.27 0.00e+00 -8.172031e-04 2.122635e-03 7.700128e-05 -6.000000e+00 2.033916e-03 284.27 -2.00 20.00 -2.00 500.17 0.00e+00 2.311571e+00 1.545064e+00 3.116157e-02 -6.000000e+00 1.417077e+00 224.55 -2.00 3.16 -2.00 501.81 0.00e+00 20.120 0.076 489.00 513.00 1 9.3616e+00 1.1865e-01 3.0960e-02 -6.0000e+00 1.0877e-01 9.4670e-02 3.0285e-02 1.7400e-03 -6.0000e+00 2.8129e-02 8.1023e-06 6.2179e-03 7.4210e-03 2.9583e-05 -6.0000e+00 7.1695e-03 6.4370e-02 1.3899e-04 12 8 8 10 0 0 95.13 20.96 10.34 0.06437 0.10750 8 2 1 4 0 4000.000 25.17 19.77 20.96 -2254 4295 1523 -4849 8406 1888 736 13362 -4273 -433 -5107 15134 -14661 -3037 1018 -1741 7451 -9967 13978 -10638 -5792 -4332 17208 1398 -7891 4816 -1433 2186 5362 -2976 9151 2965 8272 -12244 10697 2190 -247 -6489 248 10356 -4162 8703 845 -2784 -8823 2144 720 97 878 155 8851 -7445 8134 9432 -7882 13973 18734 -1499 2715 -3762 3497 -978 2665 7506 -4105 671 1523 -1424 -5092 -11921 2016 10900 -12320 -6234 7486 -1705 1831 -2060 1447 -9190 1220 -9778 -8461 -6554 5802 14085 3615 9244 8749 1498 14538 -7538 9649 -9374 185 -7585 -903 930 7189 9622 5234 -7997 5719 3180 -12147 -1077 4827 -442 -2916 8693 1765 8356 -11726 15155 -5404 -6105 2749 -3788 10835 -4290 10473 -8973 17049 6532 4235 789 3084 5672 -2350 -2040 1839 3554 -3435 1899 -4949 -9752 -730 4278 1941 -9656 2307 -5512 -10894 7441 2313 -420 6598 9134 -1021 -6086 -3583 10991 -53 -2300 4242 1596 -5558 8625 2102 835 13346 -5037 -485 -5909 14124 -18244 -3348 1012 -1809 7249 -11830 13243 -12950 -6727 -4965 15953 1524 -9446 5053 -1584 2283 5272 -3107 8437 2961 8090 -15156 10680 2376 -271 -7504 265 9970 -4643 8600 913 -3148 -10652 2315 781 104 917 158 8070 -7813 7251 8408 -8592 12598 16414 -1619 2808 -4140 3580 -1051 2770 7417 -4517 694 1536 -1458 -5343 -13238 1931 9550 -12885 -6222 7016 -1637 1670 -1918 1285 -9041 1083 -9759 -8405 -6448 5098 11502 3297 7990 7604 1403 12011 -7847 8571 -10162 182 -7969 -871 861 6111 7811 4374 -7638 4862 2870 -13226 -1070 4518 -430 -2869 7556 1652 7422 -12935 12955 -5729 -6559 2717 -4016 9934 -4548 9452 -9684 14004 5927 3944 764 2931 5255 -2357 -1916 1662 3146 -3227 1664 -4582 -9423 -650 3692 1754 -9982 2147 -5599 -11752 6722 2214 -415 6079 8129 -986 -6045 -3414 9040 -49 SO 20180523T105632.0Z 6717.455926 478 1 32.00 2 88.95 63.88 153.02 189.47 0.00 1 0.00 1 0 22 6.108e-02 6.008e-02 5.440e-02 5.364e-02 8.492336e+03 3.675419e+03 6.708383e+02 -6.000000e+00 3.356080e+03 284.27 -2.00 20.00 -2.00 505.23 0.00e+00 4.214720e-03 1.459588e-03 2.164245e-04 -6.000000e+00 1.699207e-03 284.27 -2.00 20.00 -2.00 500.19 0.00e+00 -5.149686e-01 1.064291e+00 4.561634e-02 -6.000000e+00 1.190614e+00 224.55 -2.00 3.16 -2.00 501.78 0.00e+00 18.517 0.059 489.00 513.00 1 9.3291e+00 8.1297e-02 2.8610e-02 -6.0000e+00 9.1289e-02 1.3434e-01 2.1140e-02 1.8751e-03 -6.0000e+00 2.3788e-02 1.1929e-05 -1.1877e-03 5.0078e-03 1.0774e-04 -6.0000e+00 6.0088e-03 2.3944e-02 -2.0544e-05 12 8 8 10 0 0 66.60 20.95 6.65 0.02394 0.01571 8 2 1 4 0 4000.000 25.17 20.45 20.95 -3304 -558 -1880 -5213 4416 -689 -4402 3848 8142 9958 2231 -5019 -7752 2245 -3975 2650 -443 1850 10750 6461 13174 9516 -1229 7647 -3663 -2779 -9515 942 -2875 -3564 -1186 -12407 7116 -2242 6860 -6060 -3204 -2946 4160 -6730 -19 4034 -14647 -2536 2624 7742 2193 7406 3649 -2537 16630 267 2889 -4562 2172 3390 -3891 3315 8210 936 -714 -114 9417 -10518 3359 -962 -5128 2235 -10230 -671 203 10870 -5651 5812 9333 774 -10994 2551 5366 -1535 1421 -1397 4355 -1358 -10622 5351 2621 2929 -4278 -5368 4497 -5598 2142 -4608 14154 -2123 5010 6635 -864 -2712 -6285 7235 -4658 16399 -5580 3184 -848 -3606 1514 2428 2687 1396 -6223 8071 -7992 18184 -7927 1662 -4968 -7890 2908 6947 2057 -382 -1723 3754 8607 -907 3587 13208 -1348 -4408 -9250 -376 -6730 -6777 882 1273 11371 -996 1496 -4682 -1887 -1618 -2763 5640 -5115 5660 1509 2517 -782 4526 2986 -3400 -572 -2019 -5972 4711 -789 -4953 4006 8654 10247 2276 -5419 -8477 2196 -4111 2573 -451 1881 10212 6477 12376 9273 -1336 7639 -4122 -3108 -11340 1001 -3104 -3761 -1193 -13917 6685 -2389 6878 -7010 -3594 -3264 4244 -7596 -20 4115 -18226 -2836 2823 7979 2390 7607 3837 -2783 14690 270 2795 -4733 2140 3399 -4323 3498 8317 1021 -791 -118 9507 -12201 3388 -1005 -5510 2196 -11229 -661 197 9359 -5739 5310 8343 761 -12103 2414 4849 -1468 1312 -1326 3922 -1303 -11274 4889 2481 2772 -4344 -5486 4152 -5739 2055 -4800 12326 -2163 4659 5909 -806 -2513 -5907 5849 -4240 12341 -5428 2950 -839 -3685 1458 2290 2517 1335 -6524 7453 -8772 15477 -8805 1688 -5117 -8419 2953 6689 2042 -359 -1626 3355 7374 -858 3251 10866 -1280 -4308 -9441 -346 -6494 -6456 775 1122 9214 -931 1384 -4663 -1844 -1586 -2751 5181 -5236 5182 1424 2304 -724 3906 2613 SO 20180523T110037.1Z 6717.458762 482 1 20.15 2 88.20 63.29 153.13 187.35 0.00 1 0.00 1 0 22 6.071e-03 6.018e-03 5.634e-04 5.625e-04 1.096760e+04 3.797744e+01 7.293323e+02 -6.000000e+00 3.335647e+02 284.27 -2.00 20.00 -2.00 505.37 0.00e+00 4.941703e-03 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