File name: Pandora114s1_BuenosAires_20180525_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034741.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180525_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180525T105330.0Z 6719.453819 439 1 32.00 2 89.77 64.05 135.72 221.97 0.00 1 0.00 1 0 22 8.227e-02 7.947e-02 9.085e-02 8.912e-02 7.469209e+03 6.029277e+03 4.712430e+02 -6.000000e+00 4.518960e+03 284.17 -2.00 20.00 -2.00 505.29 0.00e+00 1.871469e-03 2.407433e-03 1.369827e-04 -6.000000e+00 2.287177e-03 284.17 -2.00 20.00 -2.00 500.19 0.00e+00 8.175428e-01 1.755470e+00 3.794384e-02 -6.000000e+00 1.599329e+00 224.52 -2.00 3.16 -2.00 501.81 0.00e+00 20.134 0.076 489.00 513.00 1 9.5593e+00 1.3403e-01 3.1186e-02 -6.0000e+00 1.2268e-01 1.1914e-01 3.4433e-02 1.9146e-03 -6.0000e+00 3.1863e-02 7.0295e-06 1.3110e-02 8.3750e-03 5.9341e-05 -6.0000e+00 8.0812e-03 2.7004e-02 1.3767e-04 12 8 8 10 0 0 -200.97 21.00 3.82 0.02700 0.11794 8 2 1 4 0 4000.000 25.17 19.62 21.00 5015 -455 245 -1839 1376 4563 -9373 14406 1699 719 -143 2032 12958 1047 -3686 895 -6639 -12530 3330 2502 -7514 -5310 956 15508 506 9114 -6821 19067 -2326 45 -12286 -4449 7502 2347 1437 5591 -9725 16714 -3017 -6348 2301 4456 1230 9749 4645 6227 9959 -2209 -11454 -6901 1593 -4503 -256 -3928 9821 -10851 3806 -1048 4996 -11455 -7279 -5770 335 -7644 10707 9878 16519 11221 -4190 -4226 8079 -400 -4559 9214 -4539 -1172 -7783 1173 -636 -1129 2578 20590 4455 9177 -755 -4408 -1233 -1301 10436 -9421 2723 -1942 5711 1105 9785 -3997 -14152 4751 13728 -7169 -9679 -2076 5461 7408 10714 -12900 8431 -1317 -11657 -163 -5602 -277 19754 12981 19453 5649 6268 -6907 -1204 -16256 391 10151 -877 -1166 -8027 -922 8219 19284 -4854 -109 7960 -5114 8023 8251 -7613 -10026 -680 5372 -19568 -6162 10333 2627 4425 -9636 16087 2297 -716 5292 7996 8829 -4187 -8409 11309 4757 -472 260 -2042 1511 4925 -11697 14113 1866 785 -156 2130 12048 1091 -4048 955 -7307 -14959 3433 2608 -8664 -5999 1019 14360 545 8970 -7786 16435 -2412 45 -13738 -4689 7252 2460 1540 5731 -11497 14990 -3268 -7098 2372 4542 1311 9652 4870 6418 9801 -2418 -13475 -7555 1559 -4589 -249 -4026 9036 -12638 3901 -1135 5091 -13743 -8393 -6586 361 -8903 10288 9434 14526 10259 -4417 -4406 7387 -398 -4779 8532 -4864 -1208 -8430 1141 -622 -1105 2432 16308 3916 7767 -713 -4356 -1185 -1250 8889 -9773 2513 -1898 5238 1068 8601 -3950 -15067 4072 10493 -6615 -9036 -1802 4502 6229 9067 -14156 7503 -1280 -12411 -154 -5628 -268 15855 11269 15932 5336 5920 -7504 -1242 -19437 391 9034 -857 -1133 -8371 -901 7360 15477 -4955 -106 7127 -5193 7053 7118 -7606 -10236 -639 4839 -21720 -6460 9308 2582 4301 -10200 14053 2172 -695 4786 6903 7395 -3937 -8253 9240 SO 20180525T105731.0Z 6719.456609 443 1 32.00 2 89.03 63.47 136.23 220.80 0.00 1 0.00 1 0 15 7.210e-02 6.902e-02 6.425e-02 6.306e-02 7.137378e+03 4.218760e+03 4.465107e+02 -6.000000e+00 3.958131e+03 284.17 -2.00 20.00 -2.00 505.22 0.00e+00 -8.306093e-04 1.718948e-03 8.219808e-05 -6.000000e+00 2.004574e-03 284.17 -2.00 20.00 -2.00 500.11 0.00e+00 4.153790e-01 1.241799e+00 5.745309e-02 -6.000000e+00 1.404905e+00 224.52 -2.00 3.16 -2.00 501.73 0.00e+00 18.707 0.061 489.00 513.00 1 9.4738e+00 9.4896e-02 2.8651e-02 -6.0000e+00 1.0771e-01 1.2134e-01 2.4690e-02 1.9855e-03 -6.0000e+00 2.8076e-02 1.0079e-05 1.0190e-03 5.8213e-03 4.7396e-05 -6.0000e+00 7.0910e-03 1.1304e-01 -5.7270e-04 12 8 8 10 0 0 -292.39 21.00 -1.54 0.11304 0.12011 8 2 1 4 0 4000.000 25.17 20.44 21.00 -6498 2930 645 2333 -3916 -1121 -484 -2590 6578 -3946 21069 -6001 1665 -2131 -7484 -906 8922 537 -3967 5004 5282 2275 10273 -6325 10500 1813 -4265 -12071 5767 2856 -311 -2537 -11119 4177 1141 -1152 5520 3608 -316 -1997 -1521 -7007 1569 717 -581 13995 -525 2529 -646 7051 -8592 -9551 16760 -6422 1408 -911 12307 -2991 -2125 1908 -9321 -8770 -4037 10309 1591 9091 -1984 7731 11207 -5667 9884 6531 -3279 12872 -3828 -1071 -6673 12827 -9774 9016 278 -11047 -84 -9091 7491 673 5396 4633 -7071 -2313 3301 -4859 -7153 24957 8394 1994 -4156 -3030 12049 -3297 -3959 -6270 -4687 6918 2325 1859 5026 4922 -10410 6296 8692 -8539 -8394 7446 -2356 -5233 6546 -3290 6644 -210 -8135 8986 -8944 10532 7506 8928 6022 -3683 -5565 -6493 2922 1524 4235 4564 -3609 7005 -10647 3166 -4149 9774 733 -1726 12968 13 7617 -14531 -7686 -5584 10549 -6498 11171 6302 1383 -6971 2936 683 2503 -4582 -1215 -529 -2903 6695 -4407 19348 -6651 1688 -2222 -8204 -937 8529 573 -4528 5279 5572 2474 10329 -7532 10600 1995 -4956 -14972 5846 2895 -319 -2666 -13013 4337 1256 -1310 5845 3851 -347 -2205 -1668 -8142 1687 786 -651 13610 -588 2719 -706 6973 -9666 -10547 13950 -6722 1386 -946 11512 -3316 -2347 2020 -10335 -9690 -4273 9478 1591 8359 -2008 6988 9655 -5714 8439 5727 -3180 10741 -3830 -1051 -6883 10703 -10043 7593 255 -11352 -78 -9307 6569 640 4940 4296 -7375 -2296 3099 -4974 -7571 19379 7717 1933 -4190 -2938 9774 -3044 -3610 -5789 -4291 5799 2128 1781 4777 4696 -11462 5788 7757 -9104 -9047 6932 -2439 -5600 6247 -3483 6417 -218 -8577 8366 -9203 9317 6386 7499 5233 -3536 -5443 -6397 2614 1380 3711 3933 -3320 5731 -10375 2717 -3907 8173 682 -1670 10938 12 6868 -16431 -8132 -5766 9167 -6568 9261 5408 1247 SO 20180525T110118.0Z 6719.459236 447 1 8.00 2 88.33 62.93 136.70 219.68 0.00 1 0.00 1 0 22 8.171e-03 8.102e-03 3.645e-03 3.639e-03 1.019716e+04 2.427754e+02 6.815931e+02 -6.000000e+00 4.488184e+02 284.17 -2.00 20.00 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