File name: Pandora114s1_BuenosAires_20180526_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034859.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180526_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180526 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180526T105406.0Z 6720.454236 400 1 32.00 2 89.79 63.84 125.62 230.10 0.00 1 0.00 1 0 22 1.047e-01 1.005e-01 1.018e-01 9.922e-02 -4.660232e+02 5.699492e+03 5.107068e+02 -6.000000e+00 5.751838e+03 284.12 -2.00 20.00 -2.00 505.22 0.00e+00 -2.818341e-03 2.693621e-03 4.848084e-05 -6.000000e+00 2.912558e-03 284.12 -2.00 20.00 -2.00 500.11 0.00e+00 4.057315e-01 1.959701e+00 9.515162e-02 -6.000000e+00 2.041353e+00 224.50 -2.00 3.16 -2.00 501.76 0.00e+00 20.157 0.077 489.00 513.00 1 9.7737e+00 1.4997e-01 3.1647e-02 -6.0000e+00 1.5652e-01 1.4006e-01 3.9115e-02 2.0085e-03 -6.0000e+00 4.0766e-02 6.3007e-06 2.9525e-03 9.4186e-03 7.1034e-05 -6.0000e+00 1.0298e-02 -7.7827e-02 6.1887e-04 12 9 8 11 8 0 64.60 21.17 11.50 -0.07783 -0.05735 8 2 1 4 0 4000.000 25.39 20.00 21.17 -18349 4986 15736 -7923 14315 7334 17165 -3648 -4563 7990 -6480 3339 3402 -7663 -6812 -4828 7487 -9501 -819 7802 2539 2616 2075 12440 3107 -2952 -1305 -23123 -1908 -489 -4351 8917 -13222 -3627 3354 10748 -8148 13824 10456 15624 9620 -1691 11808 -3684 13513 -4899 8697 3081 7828 373 7532 5351 -2173 -10220 -1500 2107 -2850 -1821 3022 7407 9201 -5277 -2478 -2249 -6681 6719 6621 4387 -2819 -1347 6480 -12376 -54 11785 15586 9804 -15897 -6373 -3587 12424 11507 3924 -18890 7979 6276 -3735 -3298 -2601 -4030 -7368 -3962 -12467 -1458 -3795 -12613 5848 862 -278 -5469 3816 -225 16892 25062 -15766 6202 -5591 6096 3666 -9149 16195 -6216 -817 21861 42769 14271 -2124 -8420 10493 7471 13124 8839 -3239 17493 5175 2811 6380 12220 -307 9987 -29245 9407 -8980 -15660 23001 -3588 -4329 -863 -6865 -2981 16911 10063 14772 7356 -14340 -11133 -17771 12704 5256 12525 6967 -10733 -2059 13655 -21670 4780 13993 -9192 13624 7642 16456 -4333 -5452 8326 -7698 3549 3568 -8890 -7808 -5467 7646 -11027 -892 8455 2716 2799 2233 12099 3324 -3349 -1446 -31485 -2054 -504 -4570 8210 -15517 -3998 3545 10662 -9720 13087 10102 14182 9232 -1820 11178 -4109 12792 -5591 8628 3197 7614 383 6983 4927 -2113 -10735 -1469 2049 -2993 -1924 3056 7155 8710 -5783 -2651 -2406 -7451 6491 6310 4210 -2869 -1336 5882 -13481 -53 10239 13239 8899 -18553 -6653 -3581 10472 9774 3613 -20668 6741 5456 -3632 -3228 -2546 -4018 -7614 -3974 -13716 -1453 -3922 -14338 5510 843 -271 -5485 3410 -205 12835 17671 -17154 5617 -5879 5781 3543 -9899 13388 -6385 -799 17275 27818 12492 -2208 -9366 9695 7130 11807 8220 -3347 14462 4782 2648 5817 10548 -300 8803 -35805 8291 -9498 -17611 17337 -3468 -4157 -798 -6802 -2899 13775 8931 12661 6841 -15670 -11847 -20334 10756 4781 10462 6019 -10807 -1873 10624 SO 20180526T105807.0Z 6720.457025 404 1 32.00 2 89.04 63.27 126.22 229.17 0.00 1 0.00 1 0 22 7.641e-02 7.145e-02 6.579e-02 6.448e-02 3.848620e+03 4.117380e+03 2.465223e+02 -6.000000e+00 4.196930e+03 284.12 -2.00 20.00 -2.00 505.26 0.00e+00 -6.364216e-04 1.747546e-03 1.467153e-05 -6.000000e+00 2.123722e-03 284.12 -2.00 20.00 -2.00 500.19 0.00e+00 1.320628e+00 1.274934e+00 2.368900e-02 -6.000000e+00 1.482481e+00 224.50 -2.00 3.16 -2.00 501.80 0.00e+00 18.747 0.062 489.00 513.00 1 9.4291e+00 9.7136e-02 2.8344e-02 -6.0000e+00 1.1376e-01 1.0065e-01 2.5342e-02 1.6472e-03 -6.0000e+00 2.9467e-02 9.8280e-06 -6.6738e-03 6.0420e-03 2.7630e-05 -6.0000e+00 7.4946e-03 -1.2176e-02 5.1852e-04 12 8 8 10 0 0 -11.01 21.18 4.92 -0.01218 -0.05847 8 2 1 4 0 4000.000 25.39 20.00 21.18 3638 -23 -4949 4997 -7308 6185 -2818 8897 6918 4109 -11292 3446 902 -8593 10964 -454 -3965 2683 -5510 3129 -2308 8964 -12462 543 912 947 441 2866 9054 -7241 5694 22327 9628 5920 -1904 568 -465 4345 1480 -5303 8814 -1183 3193 -5404 -1430 -5756 -5960 3718 -2949 14234 -10039 -9477 -1472 -315 -8774 -6672 9096 -2358 3461 -7157 1085 414 41 11170 926 -10894 -4919 16266 2188 -3967 3350 -49 6237 -5977 13379 6045 3424 6214 -4209 3244 -6608 17046 4616 15508 6487 -8698 -1340 -14243 13506 -666 -5402 5018 -4594 10406 -7227 -3215 1129 4360 -1982 -6456 19838 -10223 13622 -8254 -4048 1741 1381 17330 -1646 -10343 -10263 3854 2227 389 2727 -1703 -444 -2985 6283 -1727 1623 4285 -4529 2772 -5926 2312 1611 16959 -2913 -4610 21032 232 3954 -10728 15184 5080 -895 -8810 9480 -9223 -10011 15225 -2114 6047 -1230 -7596 -6183 -1261 9647 -4652 8896 4793 -206 3433 -23 -5385 5076 -8612 6506 -3295 9318 7371 4452 -14069 3656 969 -9378 10494 -457 -4211 2736 -6245 3296 -2577 8952 -15438 592 996 1033 481 3019 8775 -8024 5423 17969 8965 5912 -2118 625 -515 4540 1572 -5966 8579 -1276 3324 -6194 -1591 -6718 -6957 3901 -3255 12955 -11337 -10342 -1451 -305 -9391 -7197 8624 -2553 3558 -8172 1138 438 44 10684 979 -12853 -5388 14188 2166 -4129 3204 -48 5756 -5903 11782 5782 3138 5449 -4024 2845 -6369 12995 4012 12191 5637 -8899 -1286 -15641 11257 -639 -5441 4579 -4664 9208 -7680 -3264 1079 3944 -1864 -6197 14341 -9854 10385 -8021 -3917 1651 1342 14376 -1632 -11032 -10865 3563 2120 383 2650 -1743 -451 -3125 6031 -1801 1628 4130 -4687 2628 -6086 2192 1546 14001 -2762 -4439 16617 213 3470 -10769 12296 4496 -788 -8483 8239 -9293 -10348 12396 -2068 5485 -1207 -7992 -6437 -1247 8464 -4618 7541 4170 -188 SO 20180526T110158.6Z 6720.459706 408 1 21.28 2 88.34 62.71 126.78 228.27 0.00 1 0.00 1 0 22 6.264e-03 6.205e-03 7.901e-04 7.887e-04 9.091154e+03 5.175771e+01 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