File name: Pandora114s1_BuenosAires_20180527_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034814.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180527_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180527 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180527T105453.0Z 6721.454780 384 1 32.00 2 89.76 63.61 115.31 236.30 0.00 1 0.00 1 0 157 7.739e-01 4.378e-01 6.397e-01 4.318e-01 8.376119e+04 4.372783e+04 1.527236e+03 -6.000000e+00 4.273996e+04 284.07 -2.00 20.00 -2.00 505.16 0.00e+00 8.841256e-03 1.125191e-02 5.904002e-04 -6.000000e+00 2.203770e-02 284.07 -2.00 20.00 -2.00 500.10 0.00e+00 -7.678373e+00 8.311312e+00 7.940787e-01 -6.000000e+00 1.599829e+01 224.48 -2.00 3.16 -2.00 501.65 0.00e+00 20.130 0.076 489.00 513.00 1 1.1438e+01 6.1718e-01 6.9928e-02 -6.0000e+00 1.2141e+00 1.6492e-01 1.5993e-01 1.4250e-02 -6.0000e+00 3.3635e-01 1.2040e-06 1.2701e-01 2.8581e-02 4.9425e-04 -6.0000e+00 7.7613e-02 1.2816e-01 -3.2294e-03 12 13 8 11 8 0 81.72 21.81 46.77 0.12816 1.00916 8 2 1 4 0 4000.000 25.90 20.00 21.81 900000 900000 56613 20288 2345 26740 47255 74428 -22921 31510 89990 35774 74343 28806 127262 -6264 159547 1241 18446 47085 40231 26693 56104 173606 -23604 -28509 5748 900000 60472 -437 87651 -21454 7510 81398 -36215 150176 -31724 95129 24673 29741 28360 -59165 115350 -30782 8516 4198 47464 53389 -10461 93765 4824 59460 4208 104961 -32863 -13639 -7335 41386 177891 -47849 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55503 32189 46971 32584 32990 38549 -25623 44859 -15943 56548 35479 -5099 7187 42449 21221 41840 45142 -4295 18263 34683 -84431 155936 -3212 78543 18618 900000 12435 8087 -4656 -72227 11247 22427 45196 29858 40349 33316 -95036 39357 -36230 -7850 45166 -8043 58344 -739 81863 59748 24403 -23932 5170 29811 -66289 900000 15791 39376 16684 -41878 -39845 45844 26218 31124 19916 -5963 41274 36430 4103 21763 32032 40459 -37854 61339 83838 -49660 41158 -34593 9663 7434 900000 41770 900000 27649 13648 -30998 92354 27641 25981 21985 SO 20180527T105900.0Z 6721.457639 388 1 32.00 2 89.01 63.02 115.98 235.51 0.00 1 0.00 1 0 85 4.942e-01 3.062e-01 4.188e-01 2.977e-01 -2.045422e+04 1.517737e+04 6.038282e+01 -6.000000e+00 2.713199e+04 284.07 -2.00 20.00 -2.00 504.93 0.00e+00 1.701931e-04 8.158926e-03 3.817811e-04 -6.000000e+00 1.375535e-02 284.07 -2.00 20.00 -2.00 500.11 0.00e+00 5.601705e-01 5.852256e+00 1.577962e-01 -6.000000e+00 9.673708e+00 224.48 -2.00 3.16 -2.00 501.72 0.00e+00 18.660 0.061 489.00 513.00 1 1.1002e+01 4.5181e-01 3.1844e-02 -6.0000e+00 7.4076e-01 1.9099e-01 1.1954e-01 2.9034e-03 -6.0000e+00 1.9463e-01 1.9322e-06 -3.8103e-02 2.5681e-02 1.3594e-04 -6.0000e+00 4.8700e-02 1.5870e-01 -3.6281e-04 12 9 8 11 8 0 -136.92 21.81 7.02 0.15870 -0.10560 8 2 1 4 0 4000.000 25.90 19.98 21.81 7111 14453 76858 -7802 33394 20249 -9467 111637 -42200 128784 14096 40663 55322 -10985 -15373 -11754 51346 -16923 31015 22431 138 7474 35672 28867 -892 13191 1125 -34754 67534 17968 11258 -9257 8864 47263 -38839 62054 -19698 30349 57485 2728 49142 93161 25962 -19123 94503 -9909 33652 76623 30744 44027 -33559 85606 -3799 12832 15661 25338 109902 4880 133472 -20813 39223 -19546 49621 8369 -2030 41976 -29233 48400 -8724 87289 95094 115008 -18695 16034 14362 -9219 143361 -45208 43719 8445 -7894 35008 -509 4250 5230 -5179 30864 -23008 144589 -35135 44316 -10670 38460 19020 5351 16975 3309 20151 -16989 52029 -27840 5699 65731 -5471 49067 -32124 68289 28158 -26977 3009 36429 32178 -6842 23869 -20150 55088 127386 12143 109371 37199 58948 -22602 93233 36330 21931 65059 -39444 80788 -4462 59749 8943 52967 79700 24785 75225 98753 3747 -2439 23135 75407 226 27465 -11701 24547 -13274 11025 9313 -9398 6871 -37256 45853 -20786 900000 7411 13858 40049 -9757 28538 20259 -13023 46537 -82680 45633 15571 33902 39205 -14882 -21468 -15679 36387 -23985 27797 22441 175 8880 31971 27677 -1153 14847 1431 -58820 43636 18726 11389 -11165 8795 34479 -64223 41389 -28356 26568 40738 3078 34415 44661 22727 -26413 42284 -12723 28150 41737 26316 32547 -52880 39968 -4212 11733 13710 20209 38484 5032 38947 -28747 29758 -26617 33786 8628 -2330 31030 -43789 32955 -10353 39056 38848 38034 -23275 14036 12852 -10582 41833 -75633 29767 8050 -8753 25198 -525 4216 5189 -5742 24016 -30883 42192 -53996 31036 -13077 29179 17760 5830 16842 3621 20385 -23858 39474 -43665 6236 38361 -6385 33111 -49213 38609 23623 -38376 3073 25911 23474 -7362 19154 -25724 34159 39495 12181 41888 29173 36553 -30916 39108 26503 18399 35596 -61866 38308 -4964 34870 8644 32844 37792 20341 37042 37822 3622 -2446 17721 34381 223 21038 -13444 19698 -15494 10053 8662 -10626 6641 -55716 29269 -25020 900000 SO 20180527T110259.0Z 6721.460405 392 1 32.00 2 88.28 62.45 116.62 234.74 0.00 1 0.00 1 0 15 2.805e-01 2.147e-01 2.435e-01 2.128e-01 1.385273e+04 1.494556e+04 8.800133e+02 -6.000000e+00 1.539872e+04 284.07 -2.00 20.00 -2.00 505.22 0.00e+00 -4.258281e-04 5.896681e-03 1.196764e-04 -6.000000e+00 7.796505e-03 284.07 -2.00 20.00 -2.00 500.14 0.00e+00 -1.477971e+00 4.204523e+00 8.167630e-02 -6.000000e+00 5.457729e+00 224.48 -2.00 3.16 -2.00 501.77 0.00e+00 16.786 0.044 489.00 513.00 1 1.1074e+01 3.2446e-01 2.5967e-02 -6.0000e+00 4.1857e-01 1.2000e-01 8.2988e-02 2.3897e-03 -6.0000e+00 1.0884e-01 2.8228e-06 6.3155e-03 1.8955e-02 8.2211e-05 -6.0000e+00 2.7570e-02 -6.3996e-03 2.8069e-04 12 8 8 10 0 0 99.85 21.81 -2.58 -0.00640 0.03741 8 2 1 4 0 4000.000 25.90 19.98 21.81 7945 -15817 15776 4760 12910 16295 5771 -8120 7881 12263 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